应用化学 ›› 2009, Vol. 26 ›› Issue (11): 1349-1352.

• 研究论文 • 上一篇    下一篇

可视化测定痕量甲醛的研究

龙云飞*,周立萍,韩明   

  1. (湖南科技大学化学化工学院 湘潭 411201)
  • 收稿日期:2008-11-06 修回日期:2009-01-13 出版日期:2009-11-10 发布日期:2009-11-10
  • 通讯作者: 龙云飞,男,副教授; E-mail:L_yunfei927@163.com; 研究方向:光散射分析
  • 基金资助:
    湖南自然科学基金(09JJ6021)湖南科技大学博士科研启动基金资助项目

Visual Determination of Trace of Formaldehyde

LONG Yun-Fei*, ZHOU Li-Ping, HAN Ming   

  1. (Hunan University of Science and Technology,Xiangtan,411201)
  • Received:2008-11-06 Revised:2009-01-13 Published:2009-11-10 Online:2009-11-10

摘要:

摘 要:共振光散射(RLS)法是近年发展起来的新的分析测试技术,它具有简便快速,灵敏度高的特点,已用于痕量元素或物质的分析。本文基于一定条件下,在碱性溶液中甲醛能还原Ag+ 得到黄色银胶,使体系的RLS增强,从而建立起测量环境中痕量甲醛的RLS新方法。结果表明,新建方法测定甲醛的浓度线性范围为1.0?10-6?2.0?10-5 mol/L,检出限为1.0?10-7 mol/L,样品加标测定的回收率为96.26%? 103.32%。并且不同浓度的甲醛还原Ag+ 得到黄色银纳米粒子的颜色明显不同,基于此建立了一种可视化半定量测定痕量甲醛的新方法,新建方法简便快速,灵敏度高。用于环境水样、室内空气中甲醛的测定,结果满意。

关键词: 可视化测定, RLS法, 甲醛, 银纳米粒子

Abstract:

Abstract: Resonance light scattering (RLS) is a new analytical techniques developed in recent years,it has simple,fast, and high sensitivity characteristics, and has been used to trace element or material analysis. Under alkaline solution, formaldehyde can be reduced by Ag+, as a result of forming silver yellow plastic, leading to the RLS intensities of the system enhanced. Base on these phenomena, a new RLS method for trace formaldehyde determination in environment water sample was established. Under the optimizing reaction conditions,the enhanced RLS intensities of the system has good relationship with the concentration of formaldehyde in the range of 1.0×10-6 ?2.0×10-5 mol/L with the detection limit of 1.0×10-7 mol/L. The recovery is in the range of 96.26% to 103.32% for formaldehyde detection in environmental water sample and in the indoor air. According to the phenomenon that the resultant from the reaction of Ag+ and formaldehyde has different color at the present of different concentration of formaldehyde, a visual semi-quantificational method for detection of formaldehyde could be achieved.

Key words: Visual Determination, Resonance Light Scattering, Formaldehyde, Silver Nanoparticles

中图分类号: