应用化学 ›› 1998, Vol. 0 ›› Issue (1): 77-79.

• 研究论文 • 上一篇    下一篇

氢化钛的制备及其分解

李光明1, 甘礼华1, 陈龙武1, 蒋凯雁2   

  1. 1. 同济大学化学系 上海 200092;
    2. 同济大学材料科学与工程学院 上海
  • 收稿日期:1997-05-05 修回日期:1997-09-10 出版日期:1998-02-10 发布日期:1998-02-10

The Formation and Decomposition of Titanium Hydride

Li Guangming1, Gan Lihua1, Chen Longwu1, Jiang Kaiyan2   

  1. 1. Department Of Chemistry, Tongji University, Shanghai 200092;
    2. Institute of Materials Science and Engineering, Tongji University, Shanghai
  • Received:1997-05-05 Revised:1997-09-10 Published:1998-02-10 Online:1998-02-10

摘要: 钛是其有吸氢作用的金属元素之一,用于制备超纯氢气[1,2].但纯金属钛作为储氢材料却一直认为没有实用价值[2].近年来对钛与氢作用引起的微观缺陷及钛的氢化物结构和形成机制等方面进行了一些研究[4,5].但并未娜决性与里作用的实用性问题.

关键词: 氢化钛, 制备, 分解

Abstract: The titanium hydride was prepared in quartz tube reactor.Its formation and de-composition were examined by SEM, XRD and DTA.The results show that in about 350C, hydrogen and titanium can be fast combined into titanium hydride which mainly in irreg-ular polyhedron particles of 1~40 μm size, and in 680℃ the titanium hydride can be decom-posed producing hydrogen.The relationship between the partial pressure of hydrogen andtemperature was researched through thermodynamic discussion.

Key words: titanium hydride, formation, decomposition