应用化学 ›› 1990, Vol. 0 ›› Issue (2): 57-59.

• 研究简报 • 上一篇    下一篇

消旋反式菊酸α-氰基-4-氟-3-苯氧基苄酯的合成

邹新琢, 顾可权   

  1. 华东师范大学化学系 上海 200062
  • 收稿日期:1989-05-29 修回日期:1989-08-10 出版日期:1990-04-10 发布日期:1990-04-10

SYNTHESIS OF α-CYANO-3-PHENOXY-4-FLUOROBENZYL(±)-TRANS-2,2-DIMETHYL-3-ISOBUTENYLCYCLOPROPANE-1-CARBOXYLATE

Zou Xinzhuo, Gu Kequan   

  1. Department of Chemistry, East China Normal University, Shanghai 200062
  • Received:1989-05-29 Revised:1989-08-10 Published:1990-04-10 Online:1990-04-10

摘要: 含氟拟除虫菊酯的合成是近年来新型高效拟除虫菊酯研究工作的方向之一[1]。该类化合物由于具有高效、低毒、广谱、低残留、无致癌、致畸作用,有的还具有低鱼毒,杀螨的特性,因此倍受注目[2]。西德拜尔公司开发的百治菊酯(Baythroid)(1)便是其中一种高效杀虫剂。

关键词: 农药, 含氟拟除虫菊醋, 有机合成

Abstract: The synthesis of title compound(2)is reported. The keystep is the synthesis of 3-phen-oxy-4-fluorotenzaldehyde(3). p-Toluidine has been used as starting material. The biologicaltests indicated that the title compound has a higher insecticidal activity to mosquitoes(larvae), houseflies and German cockroaches.

Key words: pesticide, fluorine containing pyrethroid, organic synthesis