应用化学 ›› 1990, Vol. 0 ›› Issue (2): 40-44.

• 研究论文 • 上一篇    下一篇

聚氨酯基AB交联聚合物的动态力学性质

刘文忠, 林合, 刘景江, 韩孝族   

  1. 中国科学院长春应用化学研究所 长春 130022
  • 收稿日期:1989-05-06 修回日期:1989-08-21 出版日期:1990-04-10 发布日期:1990-04-10
  • 基金资助:
    国家自然科学基金

DYNAMIC MECHANICAL PROPERTIES OF AB CROSSLINKED POLYMERS BASED ON POLYURETHANE AND MMA

Liu Wengzhong, Lin He, Liu Jingjiang, Han Xiaozu   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022
  • Received:1989-05-06 Revised:1989-08-21 Published:1990-04-10 Online:1990-04-10

摘要: 用紫外光聚合方法制备出一系列不同组成的聚己二酸己二醇酯聚氨酯(PHAPU)和甲基丙烯酸甲醇(MMA)AB交联聚合物(ABCP)。用溶胀法和橡胶平台模量法测定了它们的交联密度,两种方法所得结果具有非常好的一致性。本文研究的ABCP半高宽大于60℃,属于半相容体系。改变PHAPU和MMA的组成可以得到阻尼性能以及其他力学性能比PHAPU和PMMA更好的ABCP。

关键词: AB交联聚合物, 聚氨酯, 动态力学性能, 聚合物的平衡溶胀

Abstract: A series of AB crosslinked polymers(ABCPs)based on poly(hexamethylene adipate)-polyurethane(PHAPU)and methyl methacrylate(MMA)with various compositions were prepared by means of ultra-violet initiation polymerization. The values of crosslink density weredetermined by swelling equilibrum approach and rubberlike elasticity. The both results werein good agreement. The width of tangent δ peak at the half height was more than 60℃,andthe system was considered to be mechanically compatible.By simply varing the concentrationof the constituents, a series of damping materials, With a unique set of properties, could beobtained.

Key words: AB crosslinked polymers, polyurethanes, dynamic mechanical property, swelling equilibrium of polymer