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聚(苯乙烯-马来酸酐)/Fe3O4纳米杂化材料的制备与表征

王云普,马红斌,李宏军,常玥*,祁彩菊,应婵娟   

  1. (西北师范大学化学化工学院，生态环境相关高分子材料教育部重点实验室，甘肃省高分子材料重点实验室 兰州 730070)
  • 收稿日期:2011-08-10 修回日期:2011-09-27 出版日期:2012-07-10 发布日期:2012-07-10
  • 通讯作者: 常玥，教授; Tel:0931-7971533; Fax:0931-7971989; E-mail:cy1126@nwnu.edu.cn; 研究方向：功能材料的制备及应用

Preparation and Characterization of Poly[styrene-co-(maleic anhydride)]/Fe3O4 Hybrid Materials

WANG Yunpu, MA Hongbin, LI Hongjun, CHANG Yue*, QI Caiju, YING Chanjuan   

  1. (Key Laboratory of Eco-Environment-Related Polymer Materials Ministry of Education,
    Key Laboratory of Polymer Materials of Gansu Province,College of Chemistry and
    Chemical Engineering,Northwest Normal University,Lanzhou 730070,China)
  • Received:2011-08-10 Revised:2011-09-27 Published:2012-07-10 Online:2012-07-10
  • Contact: Chang Yue

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摘要： 采用2,2,6,6-四甲基-1-哌啶氧化物(TEMPO)的溴盐对化学共沉淀法制备的Fe3O4纳米粒子进行表面修饰，以该粒子为过氧引发剂，苯乙烯(St)、马来酸酐(MA)为单体，采用“活性”/可控自由基聚合技术在粒子表面原位引发聚合,制备了聚(苯乙烯-马来酸酐)/Fe3O4纳米杂化材料，并对纳米Fe3O4及杂化材料进行了FT-IR、XRD、TGA、TEM和GPC表征。 结果表明，所制备的纳米杂化材料的平均粒径约为70 nm，磁性粒子表面的聚合物分子链随着聚合时间的增长而增长。 振动样品磁强计测试结果显示，在室温、外加磁场下，该纳米杂化材料呈现超顺磁性，饱和磁化强度随着包覆聚合物量的增加而降低。

关键词: Fe3O4纳米粒子, 纳米杂化材料, &, ldquo, 活性&, rdquo, /可控自由基聚合

Abstract: Fe3O4 nanoparticles, which were prepared by chemical coprecipitation, were modified by 2,2,6,6-tetramethylpiperidinyl-1-oxy bromic salt to form peroxide initiators. The poly[styrene-co-(maleic anhydride)]/Fe3O4 hybrid materials were prepared by “living”/controllable free radical polymerization of styrene(St) and maleic anhydride(MA) in the presence of modified Fe3O4. Nano-Fe3O4 and the hybrid materials were characterized by FT-IR, XRD, TGA, TEM, GPC. The results indicate that its average diameter is about 70 nm. The polymer chains increase with the polymerization time. The results of magnetic performance by vibrating sample magnetometer indicate that the hybrid materials exhibit superparamagnetic properties at room temperature under applied magnetic field. Saturation magnetization decreases with the increasing amount of encapsulated polymers.

Key words: Fe3O4 nanoparticles, hybrid materials, &, ldquo, living&, rdquo, /controlled free radical polymerization

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