协效阻燃聚丙烯的阻燃性能

doi:10.11944/j.issn.1000-0518.2019.10.190184

摘要/Abstract

摘要：

本文研究了以聚磷酸铵(APP)为主阻燃剂,次磷酸铝(AHP)和三聚氰胺氰尿酸盐(MCA)为辅阻燃剂的协效阻燃体系对聚丙烯(PP)阻燃性能的影响。采用垂直燃烧测试、极限氧指数(LOI)测试、热重分析、锥形量热仪测试、扫描电子显微镜分析等技术手段对所制备的阻燃样品进行了阻燃性能分析。结果表明:单独添加任一质量分数30%阻燃剂,均不能使PP获得良好的阻燃性能;当阻燃剂总质量分数保持在30%,m(APP)：m(AHP)：m(MCA)=4：1：1时获得理想阻燃效果,此时阻燃PP的LOI为33%,垂直燃烧测试达到V-0级,热释放速率峰值(PHRR)从765.7 kW/m²降为122.7 kW/m²。

关键词: 聚丙烯, 协效体系, 锥形量热法, 阻燃

Abstract:

In this paper, the synergistic flame retardant system with ammonium polyphosphate (APP) as the main flame retardant, aluminum hypophosphite (AHP) and melamine cyanurate (MCA) as auxiliary flame retardants was investigated for the flame retardant performance of polypropylene (PP). The flame retardant properties of the prepared flame retardant samples were analyzed by vertical burning test, limiting oxygen index (LOI) test, thermogravimetric analysis, cone calorimeter test and scanning electron microscopy. The results show that the addition of 30% mass fraction of any flame retardant alone can not achieve good flame retardant properties of PP. When the total mass fraction of additives is kept at 30%, mass ratio APP：AHP：MCA=4：1：1, the ideal flame retardancy is obtained, LOI of the flame retardant PP is 33%, the vertical burning test reaches V-0 level, and the peak heat release rate (PHRR) is reduced from 765.7 kW/m² to 122.7 kW/m².

Key words: polypropylene, synergistic system, cone calorimetry, flame retardancy

刘懿德, 陈嘉炼, 李红周, 杨松伟, 罗富彬, 陈庆华. 协效阻燃聚丙烯的阻燃性能[J]. 应用化学, 2019, 36(10): 1165-1171.

LIU Yide, CHEN Jialian, LI Hongzhou, YANG Songwei, LUO Fubin, CHEN Qinghua. Flame Retardant Properties of Synergistic Flame Retardant Polypropylene[J]. Chinese Journal of Applied Chemistry, 2019, 36(10): 1165-1171.

参考文献

[1]	AN Fangcheng.Development Status and Market Analysis of Polypropylene Industry[J]. Chem Ind Chem Eng Prog,2012,31(1):246-251(in Chinese). 安芳成. 聚丙烯行业发展现状及市场分析[J]. 化工进展,2012,31(1):246-251.
[2]	LIAO Kairong,LU Zejian,WANG Jian.Modification of Ammonium Polyphosphate and Flame Retardant Effect on Polypropylene[J]. Polym Mater Sci Eng,1998,14(4):88-93(in Chinese). 廖凯荣,卢泽俭,王坚. 聚磷酸铵的改性及其对聚丙烯的阻燃作用[J]. 高分子材料科学与工程,1998,14(4):88-93.
[3]	GUAN Yahui,WANG Xiuli,DENG Cong.Research of Flame Retardant Modification of Polypropylene Wood-Plastic Composites Based on Aluminum Phosphate[J]. Chem Res Appl,2019,31(1):88-89(in Chinese). 关雅慧,汪秀丽,邓聪. 基于次磷酸铝的聚丙烯木塑复合材料的阻燃改性研究[J]. 化学研究与应用,2019,31(1):88-89.
[4]	HUANG Weiguang. Application Status and Prospects of Flame Retardants[N]. Sichuan Economic Daily,2017 -12-06(006)(in Chinese). 黄维光. 阻燃剂的应用现状及前景展望[N]. 四川经济日报,2017-12-06(006.
[5]	ZHANG Yue.Market Analysis of Flame Retardants at Domestic and Foreign[J]. Fine Spec Chem,2014,22(8):20-24(in Chinese). 张月. 国内外阻燃剂市场分析[J]. 精细与专用化学品,2014,22(8):20-24.
[6]	Liang J Z,Zhang Y J.A Study of the Flame-Retardant Properties of Polypropylene/Al(OH)3/Mg(OH)2, Composites[J]. Polym Int,2010,59(4):539-542.
[7]	Xu M J,Wang J,Ding Y H,et al. Synergistic Effects of Aluminum Hypophosphite on Intumescent Flame Retardant Polypropylene System[J]. Chinese J Polym Sci,2015,33(2):318-328.
[8]	YUAN Yizhong.Synthesis of New Halogen-Free Flame Retardant of Melamine Cyanurate(MCA) Containing Silicone and Application in Polypropylene[J]. Zhejiang Chem Ind,2013,44(9):27-29(in Chinese). 袁益中. 含有机硅的三聚氰胺氰尿酸盐(MCA)新型无卤阻燃剂的合成及在聚丙烯中的应用研究[J]. 浙江化工,2013,44(9):27-29.
[9]	Horst B,Wolfram S.Reactions of Methyl(phenyl)silylene with CO and PH3-the Formation of Acid-Base Complexes[J]. J Organomet Chem,2002,641:156-164.
[10]	WANG Jing.Effect of Aluminum Hypophosphite on Expanded Flame Retardant Polypropylene System[D]. Northeast Forest University,2012(in Chinese). 王静. 次磷酸铝对膨胀阻燃聚丙烯体系的影响[D]. 东北林业大学,2012.
[11]	HE Xiaofang,ZHANG Cong,DAI Xin,et al. Research Progress in Application of Ammonium Polyphosphate Intumescent Flame Retardants for Polymer[J]. Plast Add,2011,(2):14-17(in Chinese). 何小芳,张崇,代鑫,等. 聚磷酸铵膨胀型阻燃剂在聚合物中应用的研究进展[J]. 塑料助剂,2011,(2):14-17.
[12]	Du B X,Guo Z H,Fang Z P.Effects of Organo-Clay and Sodium Dodecyl Sulfonate Intercalated Layered Double Hydroxide on Thermal and Flame Behavior of Intumescent Flame Retarded Polypropylene[J]. Polym Degrad Stab,2009,94:1979-1985.

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