富勒烯硫化反应进展

doi:10.11944/j.issn.1000-0518.2019.04.180369

摘要/Abstract

摘要：

富勒烯官能化研究是富勒烯化学的重要组成部分。近年来,随着富勒烯化学研究的深入发展,许多新颖富勒烯衍生物被陆续合成出来,并在生物医学和有机太阳能电池方面显示出良好的应用潜力。与快速发展的富勒烯化学相比,富勒烯硫化反应研究进展较慢,近年来逐步引起广泛兴趣。在此,我们结合本课题组开展的工作,对富勒烯硫化反应的最新进展进行总结。

关键词: 富勒烯, 硫化反应, 富勒烯硫化物, 反应机理

Abstract:

Functionalization of fullerenes is an important part of fullerene chemistry. Many novel fullerene derivatives have been synthesized during recent years, and the compounds have exhibited promising potentials in biomedical chemistry and organic solar cells. Compared with the rapid development of fullerene chemistry, progress on the fullerene thiolation is slow, which has attracted more attention recently. Herein, the latest progress on the thiolation reactions of fullerenes is reviewed, which includes the recent result from our group.

Key words: fullerenes, thiolation reactions, thiolated fullerene derivatives, reaction mechanism

吴胜莉,李宗军,高翔. 富勒烯硫化反应进展[J]. 应用化学, 2019, 36(4): 392-401.

WU Shengli,LI Zongjun,GAO Xiang. Progress on Thiolation Reactions of Fullerenes[J]. Chinese Journal of Applied Chemistry, 2019, 36(4): 392-401.

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