纳米孔道动电效应能量转换系统的前沿研究进展

doi:10.11944/j.issn.1000-0518.2018.06.170385

摘要/Abstract

摘要：

可再生清洁能源的开发和利用对人类社会的可持续发展具有重要意义。基于动电效应的纳米孔道能量转换系统将流体机械能转化为电能,有望应用于微型电源部件、自驱动纳米机器、微机电体系等领域,为清洁能源发电系统的开发提供了全新的选择。纳米孔道中的机械能-电能转换过程涉及固体孔道与流体界面间的相互作用,合理设计孔道界面的微观结构,对其进行化学修饰及探讨界面间的相互作用,是提高能量转换效率和输出功率的关键。近年来,随着纳米技术的迅猛发展及人们对界面物理化学的深入研究,纳米孔道结构和纳流体发电体系能被更精准地设计和集成。本文主要介绍了基于动电效应的纳米孔道能量转换系统的基本概念,重点关注了纳米孔道中动电效应的最新研究进展,并对该领域进行了展望,为纳米孔道动电效应能量转换系统、纳米发电机、自驱动纳米机器、可穿戴器件等领域的进一步发展和应用提供参考。

关键词: 动电效应, 纳米孔道, 清洁能源, 能量转换

Abstract:

The development of renewable clean energy is of great importance for human sustainable development. Nanopores and nanochannels based electrokinetical energy conversion systems provide us new choices for future clean energy resource development. Because these systems can transfer fluidic mechanical energy to electrical energy, they could be applied in the fields such as marine energy, self-driving nano-machines and micro-electrical mechanical systems. The interplay between solid pores and liquid interface is crucial for the energy conversion process inside nanopores and nanochannels. Artificial design, chemical modification and optimization for the interfacial structure of the energy conversion systems are key factors to improve the energy conversion efficiency. With rapid development of nanotechnology and the further study of the physical chemistry of surfaces, we can effectively and precisely prepare nanofluid power generation systems. This review mainly introduced basic concepts and advance progress of nanopores and nanochannels based electrokinetical energy conversion systems. We hope this review will be inspiring for scientists in the area of developing and applying of electrokinetic energy conversion systems, nano-generators, self-actuated nano-machines and wearable devices, etc.

Key words: electrokinetics, nanopores and nanochannels, clean energy, energy conversion

杨仙, 闵伶俐, 朱颖琳, 曹留烜, 谢彦博, 侯旭. 纳米孔道动电效应能量转换系统的前沿研究进展[J]. 应用化学, 2018, 35(6): 613-624.

YANG Xian, MIN Lingli, ZHU Yinglin, CAO Liuxuan, XIE Yanbo, HOU Xu. Recent Research Progress on Nanopores and Nanochannels Based Electrokinetical Energy Conversion Systems[J]. Chinese Journal of Applied Chemistry, 2018, 35(6): 613-624.

参考文献

[1]	Lindley D.The Energy Should Always Work Twice[J]. Nature,2009,458(7235):138-141.
[2]	GUO Wei,JIANG Lei.Energy Harvesting with Bio-Inspired Synthetic Nanochannels[J]. Sci China(Chem),2011,(8):1257-1270(in Chinese). 郭维,江雷. 基于仿生智能纳米孔道的先进能源转换体系[J]. 中国科学:化学,2011,(8):1257-1270.
[3]	Loeb S,Norman R S.Osmotic Power Plants[J]. Science,1975,189(4203):654-655.
[4]	Van Der Heyden F H J,Stein D,Dekker C. Streaming Currents in a Single Nanofluidic Channel[J]. Phys Rev Lett,2005,95(11):116104-116107.
[5]	Daiguji H,Yang P D,Szeri A J,et al. Electrochemomechanical Energy Conversion in Nanofluidic Channels[J]. Nano Lett,2004,4(12):2315-2321.
[6]	Sheng Z Z,Liu X,Min L L,et al. Bioinspired Approaches for Medical Devices[J]. Chinese Chem Lett,2017,28(6):1131-1134.
[7]	Catania K.The Shocking Predatory Strike of the Electric Eel[J]. Science,2014,346(6214):1231-1234.
[8]	Traeger L L,Sabat G,Barrett-Wilt G A,et al. A Tail of Two Voltages:Proteomic Comparison of the Three Electric Organs of the Electric Eel[J]. Sci Adv,2017,3:e1700523.
[9]	Hou X.Smart Gating Multi-Scale Pore/Channel-Based Membranes[J]. Adv Mater,2016,28(33):7049-7064.
[10]	Hou X,Guo W,Jiang L.Biomimetic Smart Nanopores and Nanochannels[J]. Chem Soc Rev,2011,40(5):2385-2401.
[11]	Zaino L P,Contento N M,Branagan S P,et al. Coupled Electrokinetic Transport and Electron Transfer at Annular Nanoband Electrodes Embedded in Cylindrical Nanopores[J]. ChemElectroChem,2014,1(9):1570-1576.
[12]	Yeh H C,Wang M,Chang C C,et al. Fundamentals and Modeling of Electrokinetic Transport in Nanochannels[J]. Isr J Chem,2014,54(11/12):1533-1555.
[13]	Xie Y B,Wang X,Xue J,et al. Electric Energy Generation in Single Track-etched Nanopores[J]. Appl Phys Lett,2008,93(16):163116.
[14]	Jia Z,Wang B,Song S,et al. Blue Energy: Current Technologies for Sustainable Power Generation from Water Salinity Gradient[J]. Renew Sustain Energy Rev,2014,31:91-100.
[15]	HOU Xu,JIANG Lei.Recent Studies of Biomimetic Smart Single Nanochannels[J]. Physics,2011,40(5):304-310(in Chinese). 侯旭,江雷. 仿生智能单纳米通道的研究进展[J]. 物理,2011,40(5):304-310.
[16]	Jung W,Kim J,Kim S,et al. A Novel Fabrication of 3.6 nm High Graphene Nanochannels for Ultrafast Ion Transport[J]. Adv Mater,2017,29(17):1605854.
[17]	Ying C F,Zhang Y C,Feng Y X,et al. 3D Nanopore Shape Control by Current-stimulus Dielectric Breakdown[J]. Appl Phys Lett,2016,109(6):063105.
[18]	Xiao K,Wen L,Jiang L.Biomimetic Solid-State Nanochannels:From Fundamental Research to Practical Applications[J]. Small,2016,12(21):2810-2831.
[19]	Suk M E,Aluru N R.Ion Transport in Sub-5-nm Graphene Nanopores[J]. J Chem Phys,2014,140(8):084707.
[20]	Lv W,Liu S,Li X,et al. Spatial Blockage of Ionic Current for Electrophoretic Translocation of DNA Through a Graphene Nanopore[J]. Electrophoresis,2014,35(8):1144-1151.
[21]	Qiu W Z,Lv Y,Du Y,et al .Composite Nanofiltration Membranes via the Co-deposition and Cross-linking of Catechol/Polyethylenimine[J]. RSC Adv,2016,6:34096-341020.
[22]	Zhuang T,Tamm L K.Control of the Conductance of Engineered Protein Nanopores Through Concerted Loop Motions[J]. Angew Chem,2014,126(23):6007-6012.
[23]	Bell N A W,Keyser U F. Nanopores Formed by DNA Origami:A Review[J]. FEBS Lett,2014,588(19):3564-3570.
[24]	Kowalczyk S W,Blosser T R,Dekker C.Biomimetic Nanopores:Learning from and about Nature[J]. Trends Biotechnol,2011,29(12):607-614.
[25]	Li J,Stein D,Mcmullan C,et al. Ion Beam Sculpting on the Nanoscale[J]. Nature,2001,412:166-169.
[26]	Fox D S,Maguire P,Zhou Y,et al. Sub-5 nm Graphene Nanopore Fabrication by Nitrogen Ion Etching Induced by a Low-energy Electron Beam[J]. Nanotechnology,2016,27(19):195302.
[27]	Goyal G,Lee Y B,Darvish A,et al. Hydrophilic and Size-controlled Graphene Nanopores for Protein Detection[J]. Nanotechnology,2016,27(49):495301.
[28]	Choi S S,Park M J,Yamaguchi T,et al. Fabrication of Nanopore on Electron Beam Induced Membrane for Single Molecule Analysis[J]. ECS Trans,2016,75(16):281-287.
[29]	Liebes-Peer Y,Bandalo V,Sökmen Ü,et al. Fabrication of Nanopores in Multi-layered Silicon-based Membranes Using Focused Electron Beam Induced Etching with XeF2 Gas[J]. Microchim Acta,2016,183(3):987-994.
[30]	Yuan J H,He F Y,And D C S,et al. A Simple Method for Preparation of Through-Hole Porous Anodic Alumina Membrane[J]. Chem Mater,2004,16(10):1841-1844.
[31]	Burham N,Hamzah A A,Yunas J,et al. Electrochemically Etched Nanoporous Silicon Membrane for Separation of Biological Molecules in Mixture[J]. J Micromech Microeng,2017,27(7):075021.
[32]	Huh D,Mills K L,Zhu X,et al. Tuneable Elastomeric Nanochannels for Nanofluidic Manipulation[J]. Nat Mater,2007,6(6):424-428.
[33]	Liu L,Yang C,Zhao K,et al. Ultrashort Single-walled Carbon Nanotubes in a Lipid Bilayer as a New Nanopore Sensor[J]. Nat Commun,2013,4:2989.
[34]	Branton D,Deamer D W,Marziali A,et al. The Potential and Challenges of Nanopore Sequencing[J]. Nat Biotech,2008,26(10):1146-1153.
[35]	Kang X F,Cheley S,Rice-Ficht A C,et al. A Storable Encapsulated Bilayer Chip Containing a Single Protein Nanopore[J]. J Am Chem Soc,2007,129(15):4701-4705.
[36]	Burns J R,Stulz E,Howorka S.Self-Assembled DNA Nanopores that Span Lipid Bilayers[J]. Nano Lett,2013,13(6):2351-2356.
[37]	Chen Q,Wang Y F,Deng T,et al. SEM-induced Shrinkage and Site-selective Modification of Single-Crystal Silicon Nanopores[J]. Nanotechnology,2017,28(30):305301.
[38]	Zhang B,Zhang A,White H S.The Nanopore Electrode[J]. Anal Chem,2004,76(21):6229-6238.
[39]	Apel P.Track Etching Technique in Membrane Technology[J]. Radiat Meas,2001,34(1):559-566.
[40]	Hou X,Dong H,Zhu D,et al. Fabrication of Stable Single Nanochannels with Controllable Ionic Rectification[J]. Small,2010,6(3):361-365.
[41]	Xia F,Guo W,Mao Y,et al. Gating of Single Synthetic Nanopores by Proton-Driven DNA Molecular Motors[J]. J Am Chem Soc,2008,130(26):8345-8350.
[42]	Vlassiouk I,Siwy Z S.Nanofluidic Diode[J]. Nano Lett,2007,7(3):552-556.
[43]	Cai S L,Zhang L X,Zhang K,et al. A Single Glass Conical Nanopore Channel Modified with 6-Carboxymethyl-chitosan to Study the Binding of Bovine Serum Albumin due to Hydrophobic and Hydrophilic Interactions[J]. Microchim Acta,2016,183(3):981-986.
[44]	Ali M,Yameen B,Neumann R,et al. Biosensing and Supramolecular Bioconjugation in Single Conical Polymer Nanochannels. Facile Incorporation of Biorecognition Elements into Nanoconfined Geometries[J]. J Am Chem Soc,2008,130(48):16351-16357.
[45]	Pérez-Mitta G,Burr L,Tuninetti J S,et al. Noncovalent Functionalization of Solid-state Nanopores via Self-assembly of Amphipols[J]. Nanoscale,2016,8(3):1470-1478.
[46]	Ali M,Yameen B,Cervera J,et al. Layer-by-layer Assembly of Polyelectrolytes into Ionic Current Rectifying Solid-state Nanopores:Insights from Theory and Experiment[J]. J Am Chem Soc,2010,132(24):8338-8348.
[47]	Hou X,Liu Y,Dong H,et al. A pH-gating Ionic Transport Nanodevice:Asymmetric Chemical Modification of Single Nanochannels[J]. Adv Mater,2010,22(22):2440-2443.
[48]	Chen Y C,Xie R,Yang M,et al. Gating Characteristics of Thermo-Responsive Membranes with Grafted Linear and Crosslinked Poly(N-isopropylacrylamide) Gates[J]. Chem Eng Technol,2010,32(4):622-631.
[49]	Tero R,Yamashita R,Hashizume H,et al. Nanopore Formation Process in Artificial Cell Membrane Induced by Plasma-generated Reactive Oxygen Species[J]. Arch Biochem Biophys,2016,605:26-33.
[50]	Guo W,Xia H,Xia F,et al. Current Rectification in Temperature-Responsive Single Nanopores[J]. Chem Phys Chem,2010,11(4):859-864.
[51]	Kalman E B,Sudre O,Vlassiouk I,et al. Control of Ionic Transport Through Gated Single Conical Nanopores[J]. Anal Bioanal Chem,2009,394(2):413-419.
[52]	Siwy Z S.Ion-Current Rectification in Nanopores and Nanotubes with Broken Symmetry[J]. Adv Funct Mater,2006,16(6):735-746.
[53]	Dekker C.Solid-state Nanopores[J]. Nat Nanotechnol,2007,2(4):209-215.
[54]	Vlassiouk I,Smirnov S,Siwy Z.Ionic Selectivity of Single Nanochannels[J]. Nano Lett,2008,8(7):1978-1985.
[55]	Levine S,Marriott J R,Neale G,et al. Theory of Electrokinetic Flow in Fine Cylindrical Capillaries at High Zeta-potentials[J]. J Colloid Interface Sci,1975,52(1):136-149.
[56]	Ai Y,Qian S.Direct Numerical Simulation of Electrokinetic Translocation of a Cylindrical Particle Through a Nanopore Using a Poisson Boltzmann Approach[J]. Electrophoresis,2011,32(9):996-1005.
[57]	Yang J,Lu F,Kostiuk L W,et al. Electrokinetic Microchannel Battery by Means of Electrokinetic and Microfluidic Phenomena[J]. J Micromech Microeng,2003,13(6):963-970.
[58]	Olthuis W,Schippers B,Eijkel J,et al. Energy from Streaming Current and Potential[J]. Sens Actuators B,2005,111:385-389.
[59]	Fievet P,Sbaï M,Szymczyk A,et al. Determining the ζ-Potential of Plane Membranes from Tangential Streaming Potential Measurements:Effect of the Membrane Body Conductance[J]. J Membr Sci,2003,226(1):227-236.
[60]	Yaroshchuk A,Ribitsch V.Role of Channel Wall Conductance in the Determination of ζ-Potential from Electrokinetic Measurements[J]. Langmuir,2002,18(6):2036-2038.
[61]	Werner C,Zimmermann R,Kratzmüller T.Streaming Potential and Streaming Current Measurements at Planar Solid/Liquid Interfaces for Simultaneous Determination of Zeta Potential and Surface Conductivity[J]. Colloids Surf A,2001,192(1/2/3):205-213.
[62]	Xuan X,Li D.Analysis of Electrokinetic Flow in Microfluidic Networks[J]. J Micromech Microeng,2003,14(2):290-298.
[63]	Heyden F H J V D,Bonthuis D J,Stein D,et al. Electrokinetic Energy Conversion Efficiency in Nanofluidic Channels[J]. Nano Lett,2006,6(10):2232-2237.
[64]	Heyden F H J V D,Bonthuis D J,Stein D,et al. Power Generation by Pressure-Driven Transport of Ions in Nanofluidic Channels[J]. Nano Lett,2007,7(4):1022-1025.
[65]	Osterle J F.Electrokinetic Energy Conversion[J]. J Appl Mech,1964,31(2):161-164.
[66]	Burgreen D,Nakache F R.Efficiency of Pumping and Power Generation in Ultrafine Electrokinetic Systems[J]. J Appl Mech,1965,32(3):675-679.
[67]	Morrison Jr F A,Osterle J F. Electrokinetic Energy Conversion in Ultrafine Capillaries[J]. J Chem Phys,1965,43(6):2111-2115.
[68]	Daiguji H,Oka Y,Adachi T,et al. Theoretical Study on the Efficiency of Nanofluidic Batteries[J]. Electrochem Commun,2006,8(11):1796-1800.
[69]	Lu M C,Satyanarayana S,Karnik R,et al. A Mechanical-electrokinetic Battery Using a Nano-porous Membrane[J]. J Micromech Microeng,2006,16(4):667-675.
[70]	Chang C C,Yang R J.Electrokinetic Energy Conversion in Micrometer-length Nanofluidic Channels[J]. Microfluidics Nanofluidics,2009,9(2/3):225-241.
[71]	Wang M,Kang Q.Electrochemomechanical Energy Conversion Efficiency in Silica Nanochannels[J]. Microfluidics Nanofluidics,2010,9(2/3):181-190.
[72]	Chein R,Tsai K,Yeh L.Analysis of Effect of Electrolyte Types on Electrokinetic Energy Conversion in Nanoscale Capillaries[J]. Electrophoresis,2010,31(3):535-545.
[73]	Xie Y B,Sherwood J D,Shui L,et al. Strong Enhancement of Streaming Current Power by Application of Two Phase Flow[J]. Lab Chip,2011,11(23):4006-4011.
[74]	Gillespie D.High Energy Conversion Efficiency in Nanofluidic Channels[J]. Nano Lett,2012,12(3):1410-1416.
[75]	Chanda S,Sinha S,Das S.Streaming Potential and Electroviscous Effects in Soft Nanochannels:Towards Designing More Efficient Nanofluidic Electrochemomechanical Energy Converters[J]. Soft Matter,2014,10(38):7558-7568.
[76]	Haldrup S,Catalano J,Hansen M R,et al. High Electrokinetic Energy Conversion Efficiency in Charged Nanoporous Nitrocellulose/Sulfonated Polystyrene Membranes[J]. Nano Lett,2015,15(2):1158-1165.
[77]	Bakli C,Chakraborty S.Electrokinetic Energy Conversion in Nanofluidic Channels:Addressing the Loose Ends in Nanodevice Efficiency[J]. Electrophoresis,2015,36(5):675-681.
[78]	Haldrup S,Catalano J,Hinge M,et al. Tailoring Membrane Nano-Structure and Charge Density for High Electrokinetic Energy Conversion Efficiency[J]. ACS Nano,2016,10(2):2415-2423.
[79]	Arki P,Hecker C,Güth F,et al. Nano- and Microfluidic Channels as Electrokinetic Sensors and Energy Harvesting Devices-Importance of Surface Charge on Solid-Liquid Interfaces[J]. Procedia Eng,2016,168:1374-1377.
[80]	Yan Z,He Y,Tsutsui M,et al. Short Channel Effects on Electrokinetic Energy Conversion in Solid-State Nanopores[J]. Sci Rep,2017,7:46661.
[81]	Mei L,Yeh L H,Qian S.Buffer Anions can Enormously Enhance the Electrokinetic Energy Conversion in Nanofluidics with Highly Overlapped Double Layers[J]. Nano Energy,2016,32:374-381.
[82]	Ren Y,Stein D.Slip-enhanced Electrokinetic Energy Conversion in Nanofluidic Channels[J]. Nanotechnology,2008,19(19):195707.
[83]	Pennathur S,Eijkel J C,Van d B A. Energy Conversion in Microsystems:Is There a Role for Micro/nanofluidics[J]. Lab on A Chip,2007,7(10):1234-1237.
[84]	Davidson C,Xuan X.Electrokinetic Energy Conversion in Slip Nanochannels[J]. J Power Sources,2008,179(1):297-300.
[85]	Chang C C,Yang R J.Electrokinetic Energy Conversion Efficiency in Ion-selective Nanopores[J]. Appl Phys Lett,2011,99(8):083102.
[86]	Yan Y,Sheng Q,Wang C,et al. Energy Conversion Efficiency of Nanofluidic Batteries:Hydrodynamic Slip and Access Resistance[J]. J Phys Chem C,2013,117(16):8050-8061.