应用化学 ›› 2015, Vol. 32 ›› Issue (7): 825-830.DOI: 10.11944/j.issn.1000-0518.2015.07.140392

• 研究论文 • 上一篇    下一篇

生物吸附剂菹草干粉对Cr(Ⅵ)的吸附性能

任一丹,王爱丽()   

  1.  德州学院 山东省功能材料与配位化学高校重点实验室 山东 德州 253023
  • 收稿日期:2014-11-14 接受日期:2015-03-25 出版日期:2015-06-30 发布日期:2015-06-30
  • 通讯作者: 王爱丽
  • 基金资助:
    山东省自然科学基金高校科研单位联合专项基金(ZR2013BL001); 德州学院人才引进课题(2003kjrc06);国家级大学生创新创业训练计划项目(201410448030)

Adsorption of Cr(Ⅵ) by Dry Powder of Potamogeton crispus

REN Yidan, WANG Aili*   

  1. Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong,Dezhou University,Dezhou,Shangdong 253023,China
  • Received:2014-11-14 Accepted:2015-03-25 Published:2015-06-30 Online:2015-06-30
  • Contact: Aili WANG
  • Supported by:
    Supported by the Natural Science Foundation of Shandong Province (Combination Research Projects)(No.ZR2013BL001), Talent Introduction Subject of Dezhou University (No.2003kjrc06), National Project of Training Programs of Innovation and Entrepreneurship for Undergraduates (No.201410448030)

摘要:

开发了高效去除重金属Cr(Ⅵ)污染的生物吸附剂,菹草(Potamogeton crispus)干粉吸附剂,通过单因素分析考察了吸附时间、吸附剂颗粒大小、溶液初始pH值、吸附剂用量、Cr(Ⅵ)初始浓度以及离子强度等对重金属离子Cr(Ⅵ)的吸附性能。 结果表明,对吸附效果影响显著的因素有Cr(Ⅵ)初始浓度、吸附剂颗粒大小、溶液初始pH值和离子强度;其吸附行为符合准二级动力学方程,相关系数为0.9998;菹草对Cr(Ⅵ)的吸附等温线符合Langmuir方程。

 

关键词: 菹草, 生物吸附剂, 重金属, 吸附动力学

Abstract:

The dry powder of Potamogeton crispus was developed as an efficient biosorbent material for the removal Cr(Ⅵ) from wastewater. The effects of adsorption equilibrium time, grain size of adsorbent particles, initial pH, the dosage of adsorbent, initial concentration of Cr(Ⅵ), and ionic strength on the adsorption performance were investigated by single-factor experiments. The adsorption process follows the pseudo second-order kinetic with a correlation coefficient (R2) of 0.9998. The experimental data fit with Langmuir isotherm model. The maximum adsorption capacity of Cr(Ⅵ) by Potamogeton crispus is 35.0 mg/g.

Key words: Potamogeton crispus, biosorbent, heavy metal, adsorption kinetics

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