Manganese Dioxide Nanorods-Doped Cellulose Composite Film for Piezoelectric Nanogenerators

doi:10.19894/j.issn.1000-0518.240054

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (6): 851-860.DOI: 10.19894/j.issn.1000-0518.240054

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Manganese Dioxide Nanorods-Doped Cellulose Composite Film for Piezoelectric Nanogenerators

Ze-Hao JIN, Li-Li WANG(), Rui HOU, Shou-Kang HU

College of Chemistry，Chemical Engineering and Resource Utilization，Northeast Forestry University，Harbin 150000，China

Received:2024-02-21 Accepted:2024-04-29 Published:2024-06-01 Online:2024-07-09
Contact: Li-Li WANG
About author:wang13624516352@163.com
Supported by:
the National Natural Science Foundation of China(52375088)

Abstract

Abstract:

Cellulose is the most abundant natural polymer resource on the earth. It has the advantages of renewable， low cost， and good biocompatibility. At the same time， cellulose has many dipoles and strong electron donating ability due to its high crystallinity and rich polar hydroxyl group. It has the good piezoelectric effect and can be used as raw material of green electronic products. In this paper， manganese dioxide nanorods （MnO₂） with high purity， small particle size and good dispersion were prepared by a hydrothermal method， which doped into type I cellulose to prepare a MnO₂/cellulose composite film. The effects of different contents of MnO₂ on the current output performance of the MnO₂/cellulose composite film piezoelectric nanogenerator were investigated. With the increase of manganese dioxide content， the output current shows a trend of first increasing and then decreasing. When the doping quality of MnO₂ is 30%， the maximum thermal weight loss rate of the composite film is 325 ℃， which is 44 ℃ higher than that of pure cellulose. The O1s binding energy values of the composite film were different from pure cellulose and manganese dioxide， which proves the existence of chemical bonding between cellulose and manganese dioxide. The piezoelectric nanogenerator with microampere-level current was fabricated by using the MnO₂/cellulose composite film. The maximum output current is 80.75 μA， and the output voltage is 1.10 V. With the press of finger， the piezoelectric nanogenerator can drive a variety of electronic products such as light-emitting diode （LED） lights， calculators and electronic watches. This new type of green piezoelectric nanogenerator is based on cellulose， and MnO₂ doping also improves the energy collection efficiency， which provides a new idea for promoting the development of nanogenerator technology.

Key words: Cellulose, Manganese dioxide, Piezoelectric nanogenerator, Composite film

CLC Number:

O636.9

Ze-Hao JIN, Li-Li WANG, Rui HOU, Shou-Kang HU. Manganese Dioxide Nanorods-Doped Cellulose Composite Film for Piezoelectric Nanogenerators[J]. Chinese Journal of Applied Chemistry, 2024, 41(6): 851-860.

Figures/Tables 12

Fig.1 Preparation process of MnO2/cellulose composite film and PENG

Fig.2 SEM image （A） and FT-IR spectrum （B） of MnO2； FT-IR spectra （C） and XRD pattern （D） of cellulose films， MnO2 and composite films

Fig.3 SEM images of MnO2/cellulose composite films doped with different mass fractions of MnO2 at a magnification of 500 times

Fig.4 SEM images of MnO2/cellulose composite films doped with different mass fraction of MnO2 at a magnification of 10000 times

Fig.5 TGA （A） and DTG （B） curves of cellulose film， MnO2 and composite films doped with different mass fractions of MnO2

Fig.6 EDS spectrum of cellulose （A） and MnO2/cellulose （B）

Fig.7 XPS spectra of MnO2， pure cellulose and piezoelectric composite films

Table 1 C1s data for XPS analyses of cellulose and MnO2/cellulose

Samples	Peak position/eV			Relative mole fraction/%
Combined form	C1	C2	C3	C1	C2	C3
Cellulose	284.8	286.3	287.9	45.7	40.4	13.9
MnO₂/cellulose	284.8	286.3	287.9	18.2	66.2	15.6

Fig.8 Effect of pressure on the output current of composite films with different doping mass fraction of MnO2

Fig.9 Schematic diagram of piezoelectric mechanism

Fig.10 Diagrams of the working mode （A） and principle （B） of PENG

Fig.11 PENG drives electronics

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Manganese Dioxide Nanorods-Doped Cellulose Composite Film for Piezoelectric Nanogenerators

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