Au Nanoparticles Confined in N-Doped Porous Carbon for Detection of Chlorine Dioxide in Liquid Phase

doi:10.19894/j.issn.1000-0518.230198

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (11): 1572-1580.DOI: 10.19894/j.issn.1000-0518.230198

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Au Nanoparticles Confined in N-Doped Porous Carbon for Detection of Chlorine Dioxide in Liquid Phase

Ding ZHANG, Wei-Wei YANG, Song-Song MIAO, Yi SU()

CAS Key Laboratory of High-performance Synthetic Rubber and Its Composite Materials，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China

Received:2023-07-23 Accepted:2023-09-23 Published:2023-11-01 Online:2023-12-01
Contact: Yi SU
About author:suyi@ciac.ac.cn
Supported by:
High Tech Industrialization Special Fund Project of Science and Technology Cooperation Between Jilin Province and Chinese Academy of Sciences(2023SYHZ0025)

1. .pdf(695KB)

Abstract

Abstract:

At present， chlorine dioxide （ClO₂） has become one of the most popular green disinfectants. Although ClO₂ disinfectant has been widely used in various domains， there are few survey reports on the detection of ClO₂ concentration. Therefore， it becomes an urgent demand to develop new catalyst materials for detection of ClO₂ in liquid phase. Using polypyrrole as the nitrogen source， the N-doped porous carbon （NPC） is obtained by mixing and annealing with KOH as the substrate. After the loading of gold nanoparticles， the surface active agent is removed by high-temperature pyrolysis， and the Au nanoparticles embedded in N-doped porous carbon catalyst （NPC-Au-P） are obtained. Compared with the N-doped carbon supported Au nanoparticles prepared by traditional methods， the porous structure of NPC-Au-P can limit the domain of Au nanoparticles， which can maintain a smaller size after high temperature pyrolysis， so it has higher catalytic activity. For electrochemical detection of ClO₂ in the liquid phase， NPC-Au-P has a high sensitivity of 29.77 L·mA/mol and a low detection limit of 0.12 μmol/L.

Key words: N-doped porous carbon, Au nanoparticles, Limit the domain, Electrochemistry, Chlorine dioxide

CLC Number:

O646.5

Ding ZHANG, Wei-Wei YANG, Song-Song MIAO, Yi SU. Au Nanoparticles Confined in N-Doped Porous Carbon for Detection of Chlorine Dioxide in Liquid Phase[J]. Chinese Journal of Applied Chemistry, 2023, 40(11): 1572-1580.

Figures/Tables 8

Fig.1 Schematic illustration of preparation of different catalysts

Fig.2 XRD patterns （A）， Au4f XPS spectra （B） and N1s XPS spectra （C） of different catalysts

Fig.3 N2 adsorption-desorption isotherm （A） and pore-size distribution （B） of NPC and NPC-Au-P

Fig.4 TEM images of NC-Au （A）， NC-Au-P （B）， NPC-Au （C） and NPC-Au-P （D）

Fig.5 CV of Au electrode （A） and different catalysts （B） with ClO2， current density difference plotted against scan rate （C）， hereby calculated Cdl values （D） and EIS of different supports （E）Note： 0.5 mol/L H2SO4 as background and in the presence of 1 mmol/L ClO2， scan rate： 50 mV/s（A， B）， current value at 0.3 V（C， D） and 10 mmol/L ［Fe（CN）6］3-/4-， 0.1 mol/L KCl （E）

Fig.6 DPV test of NPC-Au-P with different concentration of ClO2 （A）， linear regression equation of current-concentration （B）， sensitivity and detection limit of different catalysts （C）Note： 0.5 mol/L H2SO4 as background with different concentration of ClO2 （A）， amplitude： 50 mV

Fig.7 i-t curve （A）， linear regression equation of current-concentration （B）， anti-interference test （C） of ClO2 detected by NPC-Au-P， DPV test of the interference and ClO2 （D） 0.5 mol/L H2SO4 as background， applied potential 0.78 V （A， C）

Table 1 Detection of ClO2 in tap-water （n=3）

Analyte	Added/（μmol·L^-1）	Found/（μmol·L^-1）	Recovery/%
ClO₂	0	0	/
	5.0	5.132 0	102.64
	300.0	306.305 4	102.10
	900.0	901.282 7	100.14

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Au Nanoparticles Confined in N-Doped Porous Carbon for Detection of Chlorine Dioxide in Liquid Phase

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