Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (9): 1322-1329.DOI: 10.19894/j.issn.1000-0518.230019
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Da-Wei TONG1, Ming KONG1(), Yu-Bin XIANG2
Received:
2023-02-09
Accepted:
2023-05-24
Published:
2023-09-01
Online:
2023-09-14
Contact:
Ming KONG
About author:
mingkong@smail.nju.edu.cnSupported by:
CLC Number:
Da-Wei TONG, Ming KONG, Yu-Bin XIANG. Synthesis, Photophysical Properties, Theoretical Calculation and Cell Imaging of a Tetraphenylethene Imidazole Compound with Methoxy Group[J]. Chinese Journal of Applied Chemistry, 2023, 40(9): 1322-1329.
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URL: http://yyhx.ciac.jl.cn/EN/10.19894/j.issn.1000-0518.230019
Fig.2 The crystal structure of BTI (Thermal ellipsoids shown at the 30% probability level and the hydrogen atoms has been omitted for clarity); (B) The hydrogen bonding interactions between adjacent molecules
Fig.5 The fluorescence emission spectra of BTI in different volume fraction of ethanol and water mixed solution (A) and the variation of fluorescence intensity according to the water volume fraction (B) (concentration: 1×10-5 mol/L, slit width: 5 nm)
Compound | OI a | ΔE/eV b | Cal.λmax/nm c | Obs.λmax/nm d | f e | Character |
---|---|---|---|---|---|---|
BTI | HOMO→LUMO | 4.176 9 | 335 | 344 | 0.5457 | ICT/π→π* |
HOMO→LUMO+1 | 4.639 8 | 302 | 299 | 0.1578 | π→π* |
Table 1 The major electronic energy level of electron transitions and attributions for compound by TD-DFT calculations
Compound | OI a | ΔE/eV b | Cal.λmax/nm c | Obs.λmax/nm d | f e | Character |
---|---|---|---|---|---|---|
BTI | HOMO→LUMO | 4.176 9 | 335 | 344 | 0.5457 | ICT/π→π* |
HOMO→LUMO+1 | 4.639 8 | 302 | 299 | 0.1578 | π→π* |
Fig.7 The cytotoxic diagram in HepG2 cells of BTI (A) and the one- and two-photon confocal fluorescence images of BTI in HepG2 cells at different time (B) (incubated with the concentrations 10 μmol/L, two-photon excited wavelength at 700 nm, confocal fluorescence images were received by collecting the emissions at 450~600 nm)
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