Preparation of Uniformly Loaded Cu3P Nanoparticles in Porous Carbon Based on Copper Foam and Their Photocatalytic Performance for Dye Degradation

doi:10.19894/j.issn.1000-0518.210273

Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (7): 1090-1097.DOI: 10.19894/j.issn.1000-0518.210273

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Preparation of Uniformly Loaded Cu₃P Nanoparticles in Porous Carbon Based on Copper Foam and Their Photocatalytic Performance for Dye Degradation

Sheng-Jie LIU, Yong-Jie YE, Yin-Yi LIU, Shu-Man LIN, Hao-Yuan XIE, Wen-Ting LIU, Wei-Qin XU()

Engineering Technology Development Center of Advanced Materials & Energy Saving and Emission Reduction in Guangdong Colleges and Universities，Department of Chemistry and Materials Science，Guangdong University of Education，Guangzhou 510303，China

Received:2021-06-07 Accepted:2021-08-31 Published:2022-07-01 Online:2022-07-11
Contact: Wei-Qin XU
About author:xuweiqin@gdei.edu.cn
Supported by:
the Basic and Applied Basic Research Project Guangzhou Basic Research Program(202102020537);the College Students′ Innovation and Entrepreneurship Programs(S202014278020)

1. Preparation of Uniformly Loaded Cu 3 P Nanoparticles in Porous Carbo n Based on Copper Foam and T heir Photocatalytic Performance for Dye Degradation.pdf(849KB)

Abstract

Abstract:

To develop the photocatalyst with high activity and easy recyclability， uniformly loaded Cu₃P NPs in N-doped porous carbon （NPC） supported by foamy copper （FC） was synthesized through a multi-step calcination method. FC was modified by in-situ growth of copper-based metal-organic framework （Cu-MOF） crystals， which was further calcinated to obtain Cu₂O/Cu NPs loaded NPC on the surface of FC （Cu₂O/Cu@NPC@FC-400）. The desired photocatalyst Cu₃P@NPC@FC-400 can be achieved after phosphate treatment. The composition and morphology of the obtained material were characterized by X-ray powder diffraction （PXRD）， infrared spectroscopy （IR）， ultraviolet-visible diffuse reflectance spectroscopy （UV-Vis DRS）， X-ray photoelectron spectroscopy （XPS） and scanning electron microscopy （SEM）. The photocatalytic performance of Cu₃P@NPC@FC-400 was studied in the simulated dye wastewater of Rhodamine B （Rh B）， and the degradation mechanism was explored as well. It is found that the catalyst exhibits good photocatalytic activity for Rh B with a high dye removal up to 94% within 3 h. The photocatalyst is convenient for recovery， and its activity remains after 10 runs. Moreover， Cu₃P@NPC@FC-400 shows excellent photodegradation performance for multi-component wastewater containing 7 dyes. The photocatalyst has the advantage of good stability and easy recovery， which can be used for treating wastewater of various dyes.

Key words: Metal-organic framework, Foamy copper, Phosphate treatment, Dye, Photocatalytic degradation

CLC Number:

O643.3

Sheng-Jie LIU, Yong-Jie YE, Yin-Yi LIU, Shu-Man LIN, Hao-Yuan XIE, Wen-Ting LIU, Wei-Qin XU. Preparation of Uniformly Loaded Cu₃P Nanoparticles in Porous Carbon Based on Copper Foam and Their Photocatalytic Performance for Dye Degradation[J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1090-1097.

Figures/Tables 6

Fig.1 PXRD patterns of Cu3P@NPC@FC-400， Cu2O/Cu@FC-400 and FC

Fig.2 SEM images of Cu-MOF@FC （A， D）， Cu2O/Cu@NPC@FC-400 （B， E）， and Cu3P@NPC@FC-400 （C， F）

Fig.3 Photocatalytic degradation of Rh B by （a） dark，（b） catalyst-free，（c） FC-400，（d） Cu2O/Cu@NPC-400，（e） Cu2O/Cu@NPC@FC-400，（f） P@FC-400，（g） Cu3P@NPC-400 and （h） Cu3P@NPC@FC-400

Fig.4 Color change of Rh B during the photocatalytic degradation by Cu3P@NPC@FC-400

Fig.5 Recycling experiment of Cu3P@NPC@FC-400

Fig.6 Degradation process monitored by UV-Vis spectroscopy of mixed dyesA. three kinds of dyes， B. five kinds of dyes， C. seven kinds of dyes

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Preparation of Uniformly Loaded Cu₃P Nanoparticles in Porous Carbon Based on Copper Foam and Their Photocatalytic Performance for Dye Degradation

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