Fabrication and Piezoelectric Properties of Polyvinylidene Fluoride Composites with High β Phase

doi:10.11944/j.issn.1000-0518.2020.12.200133

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (12): 1411-1419.DOI: 10.11944/j.issn.1000-0518.2020.12.200133

• Full Papers • Previous Articles Next Articles

Fabrication and Piezoelectric Properties of Polyvinylidene Fluoride Composites with High β Phase

MA Antong^a,b, FU Chao^a, CHU Huiying^a,b, RAN Xianghai^a,b*, NIE Wei^a,b*

^aLaboratory of Polymer Composites Engineering,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;
^bUniversity of Science and Technology of China,Hefei 230026,China

Received:2020-05-08 Revised:2020-06-04 Accepted:2020-06-16 Published:2020-12-01 Online:2020-12-07
Contact: RAN Xianghai,professor; Tel/Fax:0431-85262677; E-mail:ranxh@ciac.ac.cn; Research interests:fluoropolymer functional materials
Co-corresponding author:NIE Wei,professor; Tel/Fax:0431-85262232; E-mail:wnie@ciac.ac.cn; Research interests:special seal protection materials

Abstract

Abstract: A high content of the electroactive β phase in polyvinylidene fluoride (PVDF) is one of the prerequisites for achieving excellent piezoresponse and sensing in flexible sensors and wearable electronic devices. Herein, three types of nanoparticles of ZnO, Ag, and their composite (Ag-ZnO) were successfully synthesized by hydrothermal method and compounded with PVDF. The morphological, crystallization and piezoelectric properties of PVDF composites were systematically characterized. The synergistic effect of Ag-ZnO nanoparticles promotes crystallization and piezoelectric properties of PVDF. What's more, after stretching, the amount of β phase of all the PVDF films is further improved, the highest β phase content is 70.0% for stretched PVDF/Ag-ZnO nanoparticles, and the best piezoelectric coefficient (d₃₃) is 31.0 pC/N.

Key words: polyvinylidene fluoride, β phase, nanoparticles, stretching, piezoelectric coefficient

CLC Number:

O631

MA Antong, FU Chao, CHU Huiying, RAN Xianghai, NIE Wei. Fabrication and Piezoelectric Properties of Polyvinylidene Fluoride Composites with High β Phase[J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1411-1419.

References

[1] Nakajima T,Okaya K,Ohta K,et al. Performance of Piezoelectric Power Generation of Multilayered Poly(vinylidene fluoride) under High Mechanical Strain[J]. Jpn J Appl Phys,2011,50(9S2):09ND14.
[2] Anton S R,Sodano H A. A Review of Power Harvesting Using Piezoelectric Materials (2003-2006)[J]. Smart Mater Struct,2007,16(3):R1.
[3] Liu X,Ma J,Wu X,et al. Polymeric Nanofibers with Ultrahigh Piezoelectricity via Self-orientation of Nanocrystals[J]. ACS Nano,2017,11(2):1901-1910.
[4] Ye H J,Yang L,Shao W Z,et al. Effect of Electroactive Phase Transformation on Electron Structure and Dielectric Properties of Uniaxial Stretching Poly(Vinylidene Fluoride) Films[J]. RSC Adv,2013,3(45):23730-23736.
[5] Martins P,Lopes A C,Lanceros-Mendez S. Electroactive Phases of Poly(vinylidene fluoride):Determination, Processing and Applications[J]. Prog Polym Sci,2014,39(4):683-706.
[6] Ruan L,Yao X,Chang Y,et al. Properties and Applications of the β Phase Poly(vinylidene fluoride)[J]. Polymers,2018,10(3):228.
[7] Zhou T,Zha J W,Cui R Y,et al. Improving Dielectric Properties of BaTiO₃/Ferroelectric Polymer Composites by Employing Surface Hydroxylated BaTiO₃ Nanoparticles[J]. ACS Appl Mater Interface,2011,3(7):2184-2188.
[8] Si S K,Karan S K,Paria S,et al. A Strategy to Develop an Efficient Piezoelectric Nanogenerator Through ZTO Assisted γ-Phase Nucleation of PVDF in ZTO/PVDF Nanocomposite for Harvesting Bio-mechanical Energy and Energy Storage Application[J]. Mater Chem Phys,2018,213:525-537.
[9] Chang J,Shen Y,Chu X,et al. Large d₃₃ and Enhanced Ferroelectric/Dielectric Properties of Poly(vinylidene fluoride)-Based Composites Filled with Pb(Zr_0.52Ti_0.48)O₃ Nanofibers[J]. RSC Adv,2015,5(63):51302-51307.
[10] Manna S,Batabyal S K,Nandi A K. Preparation and Characterization of Silver-Poly(vinylidene fluoride) Nanocomposites: Formation of Piezoelectric Polymorph of Poly(vinylidene fluoride)[J]. J Phys Chem B,2006,110(25):12318-12326.
[11] Li Q,Chen L,Gadinski M R,et al. Flexible High-Temperature Dielectric Materials from Polymer Nanocomposites[J]. Nature,2015,523(7562):576-579.
[12] Yang L,Qiu J,Ji H,et al. Enhanced Electrical Properties of Multiwalled Carbon Nanotube/Poly(vinylidenefluoride) Films Through a Rolling Process[J]. J Mater Sci-Mater El,2014,25(5):2126-2137.
[13] Yan Z,Zhao A,Liu X,et al. A pH-switched Mesoporous Nanoreactor for Synergetic Therapy[J]. Nano Res,2017,10(5):1651-1661.
[14] Liu Z,Zhou H,Lim Y S,et al. Synthesis of Silver Nanoplates by Two-Dimensional Oriented Attachment[J]. Langmuir,2012,28(25):9244-9249.
[15] Pandey R,Khandelwal G,Palani I A,et al. A La-Doped ZnO Ultra-flexible Flutter-Piezoelectric Nanogenerator for Energy Harvesting and Sensing Applications: A Novel Renewable Source of Energy[J]. Nanoscale,2019,11(29):14032-14041.
[16] Paik H,Choi Y Y,Hong S,et al. Effect of Ag Nanoparticle Concentration on the Electrical and Ferroelectric Properties of Ag/P(VDF-TrFE) Composite Films[J]. Sci Rep,2015,5:13209.
[17] Cai X,Lei T,Sun D,et al. A Critical Analysis of the α, β and γ Phases in Poly(vinylidene fluoride) Using FTIR[J]. RSC Adv,2017,7(25):15382-15389.
[18] Cui Z,Hassankiadeh N T,Zhuang Y,et al. Crystalline Polymorphism in Poly(vinylidenefluoride) Membranes[J]. Prog Polym Sci,2015,51:94-126.
[19] Wang Z L. Zinc Oxide Nanostructures: Growth, Properties and Applications[J]. J Phys:Condens Mat,2004,16(25):R829.
[20] Mandal D,Henkel K,Schmeiβer D. Improved Performance of a Polymer Nanogenerator Based on Silver Nanoparticles Doped Electrospun P(VDF-HFP) Nanofibers[J]. Phys Chem Chem Phys,2014,16(22):10403-10407.
[21] Chu H,Fu C,Xu J,et al. Carbon-doped Inorganic Nanoassemblies as Fillers to Tailor the Dielectric and Energy Storage Properties in Polymer-Based Nanocomposites[J]. Mater Des,2020:108486.

Fabrication and Piezoelectric Properties of Polyvinylidene Fluoride Composites with High β Phase

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yu-Wen YANG, Jing-Yao QI, Lin LI, Guo-Ning CHU, Sai WANG, Yu ZHANG, Shuang ZHANG. Selective Oxidation of 5-Hydroxymethylfurfural to 2，5-Furandicarboxylic Acid over Ru Supported on Magnetic NiFe₂O₄ [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 879-887.
[2]	Ye LIU, Shao-Bo GUO, Yan-Li LIANG, Hong-Guang GE, Jian-Qi MA, Zhi-Feng LIU, Bo LIU. Preparation and Catalytic Performance of Core‑Shell CuFe₂O₄@NH₂@Pt Nanocomposites [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1237-1245.
[3]	Wen-Dong WANG, Zai-Jun LI. Synthesis of Ruthenium‑Graphene Quantum Dots Artificial Oxidase and Its Application in Colorimetric Detection of Phoxim in Carrots [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1285-1293.
[4]	Feng-Zhou XU, Hua-Ying TANG, Wu-Hui LIU, Yi-Feng JIANG, Wen-Kai LI, Xian-Hai LU. A Visual Semi⁃quantitative Method for Rapid Detection of Copper Ion in Water [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1303-1311.
[5]	Tao GONG, Chao-Chao WEN, Kai-Li QIN, Ying-Zhu ZAHO, Yu-Qi ZHANG, Wen-Ting LIANG, Chuan DONG. Preparation of Formyl Deoxycholic Acid Modified Fe₃O₄ Nanoparticles and Their Application for Oxytetracycline Loading [J]. Chinese Journal of Applied Chemistry, 2022, 39(12): 1920-1926.
[6]	NIU Zhan-Ning, TANG Hao-Qing, ZHENG Chao, TIAN Tian, ZHENG Li-Yun. Study on [RESA]Br@-COOH@Fe₃O₄ with Density Functional Theory [J]. Chinese Journal of Applied Chemistry, 2021, 38(7): 825-835.
[7]	Yuan DENG, Yao-Jian FAN, Lei TAO, Zhi-Wang LUO, He-Lou XIE. Liquid Crystal Nanoparticles Containing Azobenzene：Synthesis， Supramolecular Structure and Their Applications in Light⁃Controlled Orientation [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1353-1361.
[8]	GAO Ming, ZHAO Kaidong, LIU Xiangyong, JIN Yuanzhe. Preparation of Molybdenum Disulfide Nanoparticles and the Cytoprotection on Cardiac Myocytes [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1010-1021.
[9]	DUAN Jinchi, QI Yunxia, SHI Chengying, ZHAO Qi, LIU Baijun, SUN Zhaoyan, XU Yiquan, HU Wei, ZHANG Niaona. Electron Beam Radiation Modification of Polyethylene Thermal Conductive Composites [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 896-903.
[10]	ZHANG Jingjing, XIAO Xin, SHI Dongjian, CHEN Mingqing. Morphology Regulation of Polydopamine Self-polymerization on the Surface of Strongly Electronegative Microspheres [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 756-763.
[11]	QIAN Jin, HAO Yanzhong, LI Jingqi, PEI Juan, LI Yingpin. Preparation of TiO₂ Branched Nanorod Array to Improve the Performance of Polymer Hybrid Solar Cell [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 695-702.
[12]	SUN Li'na,LI Yan,GUO Hantao,HUANG Tingting,YAO Bixia,WENG Wen. Preparation of Nitrogen and Iron Co-doped Carbon Nanoparticles and Their Applications in Detection of Hydrogen Peroxide and Glucose [J]. Chinese Journal of Applied Chemistry, 2020, 37(3): 350-358.
[13]	HUANG Xuewen, XU Sheng, ZHAO Wei, WEI Wei, LI Xiaojie, LIU Xiaoya. Hydrogen Peroxide Sensor Based on a Polymeric Self-assembled Nanoparticles-Modified Screen-Printed Electrode [J]. Chinese Journal of Applied Chemistry, 2020, 37(2): 235-241.
[14]	ZHANG Liang, HE Xinhai, REN Yanwei, CHEN Tongshan, CHEN Dongzhen. Electrospinning Composite Nanofibers for the Application of Flexible Substrate of Surface-Enhanced Raman Scattering Sensing [J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1364-1373.
[15]	LIU Lixin, DONG Jianhong, ZHANG Guanghui, ZHU Luyi, WANG Xinqiang, XU Dong, CHOW Yuktak. Preparation and Properties of Polyvinylidene Fluoride@Diatomite Fiber Membranes by Eletrospinning as Separator of Lithium-Ion Batteries [J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1441-1446.