Effects of Ethyl Orthosilicate on the Electrochemical Performance of High-Voltage Lithium Nickel Manganese Oxide-Based Full-Cell

doi:10.11944/j.issn.1000-0518.2020.11.200099

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (11): 1301-1308.DOI: 10.11944/j.issn.1000-0518.2020.11.200099

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Effects of Ethyl Orthosilicate on the Electrochemical Performance of High-Voltage Lithium Nickel Manganese Oxide-Based Full-Cell

CAI Min^a, WU Chunyan^a*, XIE Yishun^b, BAN Gui^b, LAI Feiyan^b*, HUANG Xiaoying^b, ZHANG Xiaohui^b

^aCollege of Chemistry and Engineering, Guangxi Normal University for Nationalities,Chongzuo,Guangxi 532200,China;
^bCollege of Materials and Chemical Engineering,Hezhou University,Hezhou,Guangxi 542899,China

Received:2020-04-06 Revised:2020-05-25 Accepted:2020-06-29 Published:2020-11-01 Online:2020-11-04
Contact: LAI Feiyan, lecturer; E-mail:fylai112@163.com; Research interests:new energy materials and devices
Co-corresponding author:WU Chunyan, associate professor; E-mail:wuchunyan117@163.com; Research interests:synthesis of electrochemical new energy materials
Supported by:
Supported by the National Natural Science Foundation of China (No.51964013, No. 51762006), the Guangxi University Middle-aged and Young Teachers' Basic Research Ability Improvement Project (No.2019KY0709), the Hezhou Innovation-Driven Development Project (No.Hekechuang ZX1907001) and the Guangxi University Student Innovation and Entrepreneurship Training Program (No.201911838065)

Abstract

Abstract: In order to improve the electrochemical performance of LiNi_0.5Mn_1.5O₄ lithium ion batteries, a physical mixing method was used to add ethyl orthosilicate (TEOS) to the negative electrode slurry with the mass ratios of TEOS to graphite of 0∶100, 5∶100, 10∶100, 16∶100 and 20∶100. A 502030-type flexible packaging lithium-ion battery was assembled by using LiNi_0.5Mn_1.5O₄ as the positive electrode and graphite as the negative electrode. The battery was tested for constant current charge and discharge and internal resistance. The test results show that the internal resistance of the 0TEOS(m(TEOS)∶m(graphite)=0∶100) and 16TEOS(m(TEOS)∶m(graphite)=16∶100) batteries are 159 mΩ and 105 mΩ, respectively. After 200 cycles, the capacity retention rates are 52.6% and 65.7%, and the specific discharge capacities are 46 mA·h/g and 62.9 mA·h/g, respectively. The addition of TEOS to the negative electrode slurry through a physical mixing method is beneficial to the formation of a structurally stable artificial solid electrolyte interface(SEI) film on the surface of the negative electrode, and improves the cycling and rate performance of LiNi_0.5Mn_1.5O₄.

Key words: lithium ion battery, lithium nickel manganese oxide, tetraethyl orthosilicate, full battery, electrochemical properties

CLC Number:

O643

CAI Min, WU Chunyan, XIE Yishun, BAN Gui, LAI Feiyan, HUANG Xiaoying, ZHANG Xiaohui. Effects of Ethyl Orthosilicate on the Electrochemical Performance of High-Voltage Lithium Nickel Manganese Oxide-Based Full-Cell[J]. Chinese Journal of Applied Chemistry, 2020, 37(11): 1301-1308.

References

[1] Lu Y,Hou X,Miao L,et al. Cyclohexanehexone with Ultrahigh Capacity as Cathode Materials for Lithium-Ion Batteries[J]. Angew Chem Int Ed,2019,58(21):7020-7024.
[2] Xu C,Xiang W,Wu Z,et al. Highly Stabilized Ni-Rich Cathode Material with Mo Induced Epitaxially Grown Nanostructured Hybrid Surface for High-Performance Lithium-Ion Batteries[J]. ACS Appl Mater Interfaces,2019,11(18):16629-16638.
[3] Zhao H J,Deng N P,Yan J,et al. Effect of Octaphenyl Polyhedral Oligomeric Silsesquioxane on the Electrospun Poly-m-phenylene Isophthalamid Separators for Lithium-Ion Batteries with High Safety and Excellent Electrochemical Performance[J]. Chem Eng J,2019,356:11-21.
[4] Yin Y H,Gao M X,Pan H G,et al. High-Rate Capability of LiFePO₄ Cathode Materials Containing Fe₂P and Trace Carbon[J]. J Power Sources,2012,199(2):256-262.
[5] Gao M X,Lin Y,Yin Y H,et al. Structure Optimization and the Structural Factors for the Ischarge Rate Performance of LiFePO₄/C Cathode Materials[J]. Electrochim Acta,2010,55:8043-8050.
[6] Manthiram A,Chemelewski K,Lee E S. A Perspective on the High-Voltage LiMn_1.5Ni_0.5O₄ Spinel Cathode for Lithium-Ion Batteries[J]. Energy Environ Sci,2014,7(4):1339-1350.
[7] Gao H,Maglia F,Lamp P,et al. Mechanistic Study of Electrolyte Additives to Stabilize High-Voltage Cathode-Electrolyte Interface in Lithium-Ion Batteries[J]. ACS Appl Mater Interfaces,2017,9(51):44542-44549.
[8] Zeng H N,He J,Fang D Y,et al. Nano-Sized AlPO₄ Coating Layer on Graphite Powder to Improve the Electrochemical Properties of High-Voltage Graphite/LiNi_0.5Mn_1.5O₄ Li-Ion Cells[J]. Energy Technol,2019,7(9):1801078.
[9] Takahiro K. Lattice Deformation of LiNi_0.5Mn_1.5O₄ Spinel Cathode for Li-Ion Batteries by Ball Milling[J]. J Power Sources,2019,419:52-57.
[10] Cui X L,Geng T T,Zhang F L,et al. The Influence of the Voltage Plateau on the Coulombic Efficiency and Capacity Degradation in LiNi_0.5Mn_1.5O₄ Materials[J]. J Alloy Compd,2020,820:153443.
[11] Hanf L,Henschel J,Diehl M,et al. Mn²⁺ or Mn³⁺ Investigating Transition Metal Dissolution of Manganese Species in Lithium Ion Battery Electrolytes by Capillary Electrophoresis[J]. Electrophoresis,2020,41:697-704.
[12] Chen G R,An J,Meng Y M,et al. Cation and Anion Co-doping Synergy to Improve Structural Stability of Li- and Mn-Rich Layered Cathode Materials for Lithium Ion Batteries[J]. Nano Energ,2019,57:157-165.
[13] Li S Y,Wei Y,Wang P,et al. Synergism of Cu and Al Co-doping on Improvements of Structural Integrity and Electrochemical Performance for LiNi_0.5Mn_1.5O₄[J]. J Alloy Compd,2020,820:153140.
[14] Liu J,Cheng Y F,Fan Q L,et al. Tri-functional Coating to Enhance the Capacity Retention of LiNi_0.5Mn_1.5O₄ for High Power Lithium ion Battery[J]. Mater Lett,2018,214(1):68-71.
[15] Fang X,Shen C F,Ge M Y,et al. High-Power Lithium Ion Batteries Based on Flexible and Light-Weight Cathode of LiNi_0.5Mn_1.5O₄/Carbon Nanotube Film[J]. Nano Energy,2015,12:43-51.
[16] Liu H P,Liang G M,Gao C,et al. Insight into the Improved Cycling Stability of Spere-Nanorod-Like Micro-nanostructured High Voltage Spinel Cathode for Lithium-Ion Batteries[J]. Nano Energy,2019,66:104100.
[17] Ma F,Geng F S,Yuan A B,et al. Facile Synthesis and Characterization of a SnO₂-modified LiNi_0.5Mn_1.5O₄ High-Voltage Cathode Material with Superior Electrochemical Performance for Lithium Ion Batteries[J]. Phys Chem Chem Phys,2017,19(15):9983-9991.
[18] Sun X G,Angell C A. New Sulfone Electrolytes for Rechargeable Lithium Batteries[J]. Electrochem Commun,2005,7(3):261-266.
[19] Wang H Q,Xie X S,Wei X L,et al. A New Strategy to Stabilize Capacity and Insight into the Interface Behavior in Electrochemical Reaction of LiNi_0.₅Mn_1.5O₄/Graphite System for High-Voltage Lithium-Ion Batteries[J]. ACS Appl Mater Interfaces,2017,9(38):33274-33287.
[20] Wang K,Xing L D,Zhu Y M,et al. A Comparative Study of Si-Containing Electrolyte Additives for Lithium Ion Battery:Which One is Better and Why is It Better[J]. J Power Sources,2017,342:677-684.
[21] MENG Qi,ZHOU Siyuan,LI Kun,et al. Research on Preparation and Electrochemical Properties of Silicon/Carbon Compsites by Spray Drying Method[J]. Guangzhou Chem Ind,2019,47(12):32-36(in Chinese).
孟奇,周思源,李坤,等. 喷雾干燥法构建硅/碳复合材料及其电化学性能研究[J]. 广州化工,2019,47(12):32-36.
[22] FENG Xuejiao,CUI Hongmin,XIAO Zhengqiang,et al. Synthesis of Porous Silicon Oxide/Silicon/Carbon Composite Material from Micro-SiO for Lithium Storage[J]. Chinese J Appl Chem,2017,34(1):76-82 (in Chinese).
冯雪娇,崔红敏,肖正强,等. 纳米级SiO合成多空氧化硅/硅/碳储锂复合材料[J]. 应用化学,2017,34(1):76-82.
[23] Pang W K,Lin H F,Peterson V K,et al. Enhanced Rate-Capability and Cycling-Stability of 5 V SiO₂- and Polyimide-Coated Cation Ordered LiNi_0.5Mn_1.5O₄ Lithium-Ion Battery Positive Electrodes[J]. J Phys Chem C,2017,121(7):3680-3689.

Effects of Ethyl Orthosilicate on the Electrochemical Performance of High-Voltage Lithium Nickel Manganese Oxide-Based Full-Cell

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