Synthesis of Pyridine and 3-Picoline from Acrolein Diethyl Acetal and Ammonia over La- and KF-modified Y Type Zeolite Catalysts

doi:10.11944/j.issn.1000-0518.2018.05.170154

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (5): 559-563.DOI: 10.11944/j.issn.1000-0518.2018.05.170154

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Synthesis of Pyridine and 3-Picoline from Acrolein Diethyl Acetal and Ammonia over La- and KF-modified Y Type Zeolite Catalysts

LUO Caiwu^a^b^*(),ZHAO Yong^a^b,JIANG Fuliang^a^b,LI Xiangyang^a^b,CHAO Zisheng^c^*()

^aSchool of Environmental and Safety Engineering,University of South China,Hengyang,Hunan 421001,China
^bHunan Engineering Research Center for Uranium Tailings Decommission and Treatment,Hengyang,Hunan 421001,China
^cCollege of Materials Science and Engineering, Changsha University of Science & Technology, Changsha 410114, China;

Received:2017-05-12 Accepted:2017-08-25 Published:2018-04-23 Online:2018-04-23
Contact: LUO Caiwu,CHAO Zisheng
Supported by:
Supported by the National Natural Science Foundation of China(No.21376068), the Educational Commission of Hunan Province(No.17C1361), the Doctoral Scientific Research Foundation of University of South China(No.2016XQD36)

Abstract

Abstract:

The synthesis of pyridine and 3-picoline from the reaction of acrolein diethyl acetal, water and ammonia was conducted in a fixed-bed reactor. The catalytic activities of La- and KF-modified Y zeolites were compared. Various influencing parameters, including the loadings and modified ways of La species, the loadings of KF and the calcination temperature of KF/Y, were systematically investigated. Compared to pure Y zeolite, La- and KF-modifications can enhance the catalytic activities. The catalytic activity of La-modified Y through ion exchange is better than that of the sample through wet impregnation. The total yield of pyridine and 3-picoline reaches the maximum while the loading of La via the wet-impregnation method is 1% mass fraction and the calcination temperature of KF/Y is 700 ℃.

Key words: acetal, picoline, pyridine, La-Y, KF/Y zeolite

LUO Caiwu, ZHAO Yong, JIANG Fuliang, LI Xiangyang, CHAO Zisheng. Synthesis of Pyridine and 3-Picoline from Acrolein Diethyl Acetal and Ammonia over La- and KF-modified Y Type Zeolite Catalysts[J]. Chinese Journal of Applied Chemistry, 2018, 35(5): 559-563.

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Synthesis of Pyridine and 3-Picoline from Acrolein Diethyl Acetal and Ammonia over La- and KF-modified Y Type Zeolite Catalysts

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