Synthesis and Luminescence Properties of Ba3Y(PO4)3:Dy3+,Eu3+ Single Phase White-emitting Phosphor

doi:10.11944/j.issn.1000-0518.2017.10.160495

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (10): 1186-1194.DOI: 10.11944/j.issn.1000-0518.2017.10.160495

• Orginal Article • Previous Articles Next Articles

Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺,Eu³⁺ Single Phase White-emitting Phosphor

LI Shuailong,LIU Xiaoming(),TANG Xinghua,FENG Jingchun,XIE Weijie

Environmental and Chemical Engineering,Nanchang Hangkong University,Nanchang 330063,China

Received:2016-12-05 Accepted:2017-03-29 Published:2017-09-29 Online:2017-09-29
Contact: LIU Xiaoming
Supported by:
Supported by the Natural Science Foundation of the Jiangxi Province of China(No.20152ACB20011), the Postgraduate Innovation Foundation of Nanchang Hangkong University(No.YC2015009)

Abstract

Abstract:

A series of Dy³⁺ and/or Eu³⁺ doped Ba₃Y(PO₄)₃ phosphors was prepared via a traditional high temperature solid state reaction to investigate how the luminescent properties of Dy³⁺ doped Ba₃Y(PO₄)₃ phosphor can be tuned by co-doping Eu³⁺ ions into the host lattice. X-ray diffraction(XRD), photoluminescence and fluorescence lifetime were used to characterize the as-prepared samples. The results show that all the samples have Ba₃Y(PO₄)₃ eulytite cubic structure. Under the excitation of near-UV light, the Ba₃Y(PO₄)₃:Dy³⁺ phosphor shows cool-white emission and the Ba₃Y(PO₄)₃:Eu³⁺ phosphor presents an orange-red emission. For Ba₃Y(PO₄)₃:Dy³⁺,Eu³⁺ phosphor, warm-white emission with high color rendering index and appropriate correlated color temperature has been obtained by combining red emission of Eu³⁺with cool-white emission of Dy³⁺. The luminescence mechanism of Ba₃Y(PO₄)₃:Dy³⁺,Eu³⁺ phosphor has been tentatively proposed and the prepared Ba₃Y(PO₄)₃:Dy³⁺,Eu³⁺ phosphor has potential application in white-light-emitting-diodes(WLEDs) filed.

Key words: Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺, white-emitting phosphor, energy transfer

LI Shuailong, LIU Xiaoming, TANG Xinghua, FENG Jingchun, XIE Weijie. Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺,Eu³⁺ Single Phase White-emitting Phosphor[J]. Chinese Journal of Applied Chemistry, 2017, 34(10): 1186-1194.

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Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺,Eu³⁺ Single Phase White-emitting Phosphor

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