Synthesis and Application Progress of Organic Phosphorus-Containing Flame Retardants

doi:10.11944/j.issn.1000-0518.2016.06.150299

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (6): 611-623.DOI: 10.11944/j.issn.1000-0518.2016.06.150299

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Synthesis and Application Progress of Organic Phosphorus-Containing Flame Retardants

LI Nana^a^b,JIANG Guowei^a,ZHOU Guangyuan^a^*(),JIANG Zhenhua^c,WANG Huawei^d

^a Key Laboratory of Polymer Ecomaterials,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
^b University of Chinese Academy of Sciences,Beijing 100049,China
^c College of Chemistry,Jilin University,Changchun 130012,China
^d Tianjin Dagu Chemical Co.,LTD,Tianjin 300450,China

Received:2015-08-17 Accepted:2015-12-17 Published:2016-06-01 Online:2016-06-01
Contact: ZHOU Guangyuan

Abstract

Abstract:

Organic phosphorus-containing flame retardants have good characteristics, such as high efficiency, low toxicity, no pollution and smokeless. To date, research of synthesis and application in this field attracts a lot of attention. This paper reviewed recent developments, current status and potential future trends of organic phosphorus-containing flame retardants. The classification and mechanism of organic phosphorus-containing flame retardants were also introduced. The development and problems in the application were outlined considering the aspects of organic phosphorus-containing fire retardants.

Key words: phosphorus-containing, flame-retardant mechanism, classification, development

LI Nana,JIANG Guowei,ZHOU Guangyuan,JIANG Zhenhua,WANG Huawei. Synthesis and Application Progress of Organic Phosphorus-Containing Flame Retardants[J]. Chinese Journal of Applied Chemistry, 2016, 33(6): 611-623.

References

[1]	Cho C S,Fu S C,Chen L W,et al.Aryl Phosphinate Anhydride Curing for Flame Retardant Epoxy Networks[J]. Polym Int,1998,47(2):203-209.
[2]	Ravey M,Weil E D,Keidar I,et al.Flexible Polyurethane Foam.Ⅱ.Fire Retardation by Tris (1,3-Dichloro-2-Propyl) Phosphate. Part B.Examination of the Condensed Phase(the Pyrolysis Zone)[J]. J Appl Polym Sci,1998,68(2):231-254.
[3]	Nisshihara H,Taun S,Kanatani R. Interactions Between Phosphorus and Nitrogen-Containing Flame Retardants[J]. Polym J,1998,30(3):163-167.
[4]	Antony R, Pillai C K S. Synthesis and Thermal Characterization of Chemically Modified Cardanol Polymers[J]. J Appl Polym Sci,1993,49(12):2129-2135.
[5]	Davies D,Horrocks A R. Nitrogen Phosphorous Antagonism in Flame-retardant Cotton[J]. J Appl Polym Sci,1986,31(6):1655-1662.
[6]	Mandal H,Hay A S. Polycyclic Phosphonate Resins:Thermally Cross-linkable Intermediates for Flame-retardant Materials[J]. J Polym Sci,Part A:Polym Chem,1998,36(11):1911-1918.
[7]	Horold S. Phosphorus Flame Retardants in Thermoset Resins[J]. Polym Degrad Stab,1999,64(3):427-431.
[8]	Stackman R W. Phosphorus based Additives for Flame Retardant Polyester.1.Low Molecular Weight Wdditives[J]. Ind Eng Chem Prod Res Dev,1982,21(2):328-331.
[9]	Stackman R W. Phosphorus Based Additives for Flame Retardant Polyester.2.Polymeric Phosphorus Esters[J]. Ind Eng Chem Prod Res Dev,1982,21(2):332-336.
[10]	Liu Y L,Hsiue G H,Lan C W,et al.Flame-retardant Polyurethanes From Phosphorus-containing Isocyanates[J]. J Polym Sci,Part A:Polym Chem,1996,35(9):1769-1780.
[11]	Banerjee S,Palit S K,Malti S. Phosphorus Containing Polymers.3.Polyimidophosphonates[J]. J Polym Sci,Part A:Polym Chem,1994,32(2):219-227.
[12]	Green J. Phosphorus-bromine Flame Retardant Synergy in Polycarbonate/ABS Blends[J]. Polym Degrad Stab,1996,54(2/3):189-193.
[13]	Liu Y L,Hsiue C H,Chiu Y S,et al.Synthesis and Flame-retardant Properties of Phosphorus-containing Polymers Based on Poly(4-hydroxystyrene)[J]. J Appl Polym Sci,1996,59(10):1619-1625.
[14]	Ma Z L,Zhao W G,Liu Y F,et al.Synthesis and Properties of Intumescent, Phosphorus-containing, Flame-retardant Polyesters[J]. J Appl Polym Sci,1997,63(12):1511-1515.
[15]	Antony R,Pillai C K S. Synthesis and Thermal Characterization of Chemically Modified Phenolic Resins[J]. J Appl Polym Sci,1994,54(4):429-438.
[16]	Liu Y L,Hsiue G H,Lan C W,et al.Synthesis, Thermal Properties, and Flame Retardancy of Phosphorus Containing Polyimides[J]. J Appl Polym Sci,1997,63(7):875-882.
[17]	Tang H I,Lin R K,Way T F,et al.A Study of Thermal Stability of Polyester Containing Phenyl Phosphonate Unit for Flame Retardant Fiber[J]. Polym Degrad Stab,1996,54(2/3):313-377.
[18]	Annakutty K S,Kishore K. Pyrolysis Gas Chromatographic Studies on Polyphosphate Esters of Bisphenol A[J]. Macromol Chem Phys,1991,192(1):11-20.
[19]	Duquesne S,Lefebvre J,Seeley G,et al.Vinyl Acetate/butyl Acrylate Copolymers Part 2:Fire Retardancy Using Phosphorus-containing Additives and Monomers[J]. Polym Degrad Stab,2004,85(2):883-892.
[20]	Laoutid F,Ferry L,Lopez J M,et al.Red Phosphorus/aluminium Oxide Compositions as Flame Retardants in Recycled Poly(ethylene terephthalate)[J]. Polym Degrad Stab,2003,82(2):357-363.
[21]	ZHANG Jun. Polymer Combustion and Flame Retardant Technology[M]. Beijing:Chemical Industry Press,2005,268-275(in Chinese). 张军. 聚合物燃烧与阻燃技术[M]. 北京:化学工业出版社,2005,268-275.
[22]	Sponton M,Ronda J C,Galia M,et al.Cone Calorimetry Studies of Benzoxazine-epoxy Systems Flame Retarded by Chemically Bonded Phosphorus or Silicon[J]. Polym Degrad Stab,2009,94(1):102-106.
[23]	Sun D C,Yao Y W. Synthesis of Three Novel Phosphorus-containing Flame Retardants and Their Application in Epoxy Resins[J]. Polym Degrad Stab,2011,96(10):1720-1724.
[24]	Guo Y N,Qiu J J,Tang H Q,et al.High Transmittance and Environment-friendly Flame-resistant Opticalr Resins Based on Poly(methyl methacrylate) and Cyclotriphosphazene Derivatives[J]. J Appl Polym Sci,2011,121(2):727-734.
[25]	Wu C S,Liu Y L,Chiu Y S,et al.Thermal Stability of Epoxy Resins Containing Flame Retardant Components:An Evaluation with Thermogravimetric Analysis[J]. Polym Degrad Stab,2002,78(1):41-48.
[26]	Wu C S,Liu Y L,Chiu Y S. Epoxy Resins Possessing Flame Retardant Elements from Silicon Incorporated Epoxy Compounds Cured with Phosphorus or Nitrogen Containing Curing Agents[J]. Polymer,2002,43(15):4277-4284.
[27]	Liu Y,Wang Q. Reactive Extrusion to Synthesize Intumescent Flame Retardant with a Solid Acid as Catalyst and the Flame Retardancy of the Products in Polypropylene[J]. J Appl Polym Sci,2008,107(1):14-20.
[28]	Shankwalkar S G,Placck D G. Oxidation and Weight loss Characteristics of Commercial Phosphate Esters[J]. Ind Eng Chem Res,1992,31(7):1810-1813.
[29]	Matuschek G. Thermal-degradation of Different Fire Retardant Polyurethane Foams[J]. Thermochim Acta,1995,263:59-71.
[30]	Reshetnikov I,Anonov A,Rudakova T,et al.Some Aspects of Intumescent Fire Rctardant Systems[J]. Polym Degrad Stab,1996,54(2/3):137-141.
[31]	Kpura A A. Chemistry of Flame Retardants:3.Aging of n-Methylol-3-dimethoxyphosphoryl Propionamide and Commercial Flame Retardant for Fabrics Containing This Substance[J]. J Fire Sci,1996,14(3):169-183.
[32]	XIN Fei. Preparation and Characterization of Resorcinol Bis(diphenyl phosphate) Oligomer[J]. New Chem Mater,2011,39(7):123-125(in Chinese). 辛菲. 无卤阻燃剂间苯二酚双(二苯基)磷酸酯的合成及表征[J]. 化工新型材料,2011,39(7):123-125.
[33]	FU Quanjun,WANG Xinlong,ZHANG Zhiye,et al.Synehesis and Application of Phosphorus Flame Retardant HDP/ABS Composites[J]. Acta Polym Sin,2013,2(2):166-173(in Chinese). 付全军,王辛龙,张志业,等. 磷酸酯阻燃剂HDP的合成工艺及其在ABS中的阻燃作用[J]. 高分子学报,2013,2(2):166-173.
[34]	FANG Keyi,LI Juan,KE Chenhao,et al.Promotion Effect of a Hyperbranched Polyphosphnate Ester Flame Retardant on Char Formation of Polyamide 6[J]. Acta Polym Sin,2011,1(1):55-62(in Chinese). 方科益,李娟,柯晨皓,等. 超支化聚磷酸酯阻燃剂对尼龙6的成炭促进作用[J]. 高分子学报,2011,1(1):55-62.
[35]	WU Denghui,ZHAO Peihua,ZHANG Mei,et al.Synthesis and Flame Retardant Properties of a Novel Monomolecular P-N Intumescent Flame Retardant[J]. Chinese J Synth Chem,2013,21(5):530-533(in Chinese). 毋登辉,赵培华,张美,等. 新型单组分磷-氮膨胀型阻燃剂的合成及其阻燃性能[J]. 合成化学,2013,21(5):530-533.
[36]	Enescu D,Frache A,Lavaselli M,et al.Novel Phosphorous-nitrogen Intumescent Flame Retardant System. Its Effects on Flame Retardancy and Thermal Properties of Polypropylene[J]. Polym Degrad Stab,2013,98(1):297-305.
[37]	Shariatinia Z,Javeri N,Shekarriz S,et al.Flame Retardant Cotton Fibers Produced Using Novel Synthesized Halogen-free Phosphoramide Nanoparticles[J]. Carbohydr Polym,2015,118:183-198.
[38]	Yuan H X,Xing W Y,Zhang P,et al.Functionalization of Cotton with UV-cured Flame Retardant Coatings[J]. Ind Eng Chem Res,2012,51(15):5394-5401.
[39]	ZHONG Liu,LIU Zhiguo,OU Yuxiang. Synthesis and Identification of Novel Halogen-contained Phosphate Ester and Its Application in PU Foam[J]. Plastics,2008,37(5):27-30(in Chinese). 钟柳,刘治国,欧育湘. 新型含卤磷酸酯阻燃剂的合成、表征和应用[J]. 塑料,2008,37(5):27-30.
[40]	LU Lingang,ZHOU Xia,ZHAO Min,et al.Synthesis of Flame Retardant Bis(5,5-dibromomethyl-1,3,2-dioxanephosphoryl) Bisphenol A[J]. Chem Res Appl,2009,21(12):1667-1670(in Chinese). 卢林刚,周霞,赵敏,等. 阻燃剂二(5,5-二溴甲基-1,3,2-二氧六环磷酰)双酚A的合成[J]. 化学研究与应用,2009,21(12):1667-1670.
[41]	WANG Huiya,ZHOU Xia,WANG Yongming,et al.Synthesis of Novel Mono-component P-Br Synergistic Flame Retardant 1,3-Bis(5,5-dibromomethyl-1,3-dioxaphosphori-nanyl-2-oxy) Benzene[J]. Chem Reag,2010,32(1):52-54(in Chinese). 王会娅,周霞,王永明,等. 新型单组分磷溴协效阻燃剂1,3-二(5,5-二溴甲基-1,3-二氧杂己内磷酰氧基)苯的合成[J]. 化学试剂,2010,32(1):52-54.
[42]	MA Zhiling,CUI Haixiang,ZHANG Jiaojiao,et al.Synthesis and Applications of Intumescent Flame Retardant Dibromoneopentyl Glycol-phosphate Ester-melamine Salt[J]. J Hebei Univ(Nat Sci Ed),2008,28(3):258-262(in Chinese). 马志领,崔海香,张娇娇,等. 膨胀型阻燃剂二溴新戊二醇磷酸酯三聚氰胺盐的合成及应用[J]. 河北大学学报(自然科学版),2008,28(3):258-262.
[43]	Nguyen C,Kim A. Synthesis of a Novel Nitrogen-phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS[J]. Macromol Res,2008,16(7):620-625.
[44]	WANG Dan,ZHOU Hao,ZHI Huizhen,et al.Synthesis of Halogen-free Flame Retardant 1,2-Ethylene Bis(dimethyl phosphonate)[J]. Fine Chem,2011,4(28):389-392(in Chinese). 王丹,周浩,职慧珍,等. 无卤阻燃剂1,2-亚乙基双麟酸四甲酯的合成[J]. 精细化工,2011,4(28):389-392.
[45]	Peng H Q,Zhou Q,Wang D Y. A Novel Charring Agent Containing Caged Bicyclic Phosphate and Its Application in Intumescent Flame Retardant Polypropylene Systems[J]. J Ind Eng Chem,2008,14(5):589-595.
[46]	Dumitrascu A,Howell B A. Flame-retarding Vinyl Polymers Using Phosphorus Functionalized Styrene Monomers[J]. Polym Degrad Stab,2011,96(3):342-349.
[47]	Jiang D W,Sun C Y,Zhou Y N,et al.Enhanced Flame Retardancy of Cotton Fabrics with a Novel Intumescent Flame-retardant Finishing System[J]. Fire Mater,2015,16(2):388-396.
[48]	Wyman P,Crook V,Ebdon J,et al.Flame-retarding Effects of Dialkyl-p-vinylbenzyl Phosphonates in Copolymers with Acrylonitrile[J]. Polym Int,2006,55(7):764-771.
[49]	Fan R L,Guo L,Wang P Z,et al.Synthesis and Solubilities of 3,9-Dipyrolidino-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane-3,9-dioxide in Selected Solvents[J]. Chem Eng Sci,2015,202(1):96-101.
[50]	Lin H T,Lin C H,Hu Y M,et al.An Approach to Develop High-Tg Epoxy Resins for Halogen-free Copper Clad Laminates[J]. Polymer,2009,50(24):5685-5692.
[51]	Hoang D,Kim J,Jang B N. Synthesis and Performance of Cyclic Phosphorus-containing Flame Retardants[J]. Polym Degrad Stab,2008,93(11):2042-2047.
[52]	Karatas S,Hosgor Z,Kayaman-Apohan N,et al.Preparation and Characterization of Phosphine Oxide Containing Organosilica Hybrid Coatings by Photopolymerization and Sol-gel Process[J]. Prog Org Coat,2009,65(1):49-55.
[53]	Meenakshi K S, Sudhan E P J, Kumar S A. Development and Characterization of New Phosphorus Based Flame Retardant Tetraglycidyl Epoxy Nanocomposites for Aerospace Application[J]. Bull Mater Sci,2012,35(2):129-136.
[54]	Yang X F,Li Q L,Chen Z P,et al.Study on Crystallization Behaviour of Co-polyamide 66 Containing Triaryl Phosphine Oxide[J]. Bull Mater Sci,2012,35(2): 233-242.
[55]	Rajasekaran R,Karikalchozhan C,Alagar M. Preparation and Characterization of 3,3'-Bis(maleimidophenyl)phenylphosphine Oxide(BMI)/polysulfone Modified Epoxy Intercrosslinked Matrices[J]. Polym Compos,2008,29(7):773-781.
[56]	Sponton M,Ronda J C,Galia M,et al.Studies on Thermal and Flame Retardant Behaviour of Mixtures of Bis(m-aminophenyl)methylphosphine Oxide based Benzoxazine and Flycidylether or Benzoxazine of Bisphenol A[J]. Polym Degrad Stab,2008,93(12):2158-2165.
[57]	Hua R,Sun J Z,Wu B J,et al.Synthesis and Properties of a Phosphorus-containing Flame Retardant Epoxy Resin Based on Bis-phenoxy(3-hydroxy) phenyl Phosphine Oxide[J]. Polym Degrad Stab,2007,92(6):956-961.
[58]	Peng C,Wu Z J,Li J L,et al. Synthesis, Thermal and Mechanical Behavior of a Silicon/phosphorus Containing Epoxy Resin[J]. J Appl Polym Sci, 2015, 132(46):DOI:
[59]	Schafer A,Seibold S,Lohstroh W,et al.Synthesis and Properties of Flame-retardant Epoxy Resins Based on DOPO and One of Its Analog DPPO[J]. J Appl Polym Sci,2007,105(2):685-696.
[60]	Vasiljevic J,Jerman I,Jaksa G,et al.Functionalization of Cellulose Fibres with DOPO-polysilsesquioxane Flame Retardant Nanocoating[J]. Cellulose,2015,22(3):1893-1910.
[61]	Sablong R,Duchateau R,Koning C E,et al.Incorporation of a Flame Retardancy Enhancing Phosphorus-containing Diol into Poly(butylene terephthalate) via Solid State Polycondensation:A Comparative Study[J]. Polym Degrad Stab,2011,96(3):334-341.
[62]	Pospiech D,Hauler L,Korwitz A,et al.The Miscibility of Poly(butylene terephthalate)(PBT) with Phosphorus Polyester Flame Retardants[J]. High Perform Polym,2012,24(1):64-73.
[63]	Fischer O,Pospiech D,Korwitz A,et al.Synthesis and Properties of Phosphorus Polyesters with Systematically Altered Phosphorus Environment[J]. Polym Degrad Stab,2011,96(12):2198-2208.
[64]	Lu L G,Wang X,Yang S S,et al.Synthesis and Application of Novel Arborescent Monomolecular P-N Intumescent Flameretardant[J]. Acta Chim Sin,2012,70(2):190-194.
[65]	Lu L G,Wang X,Yang S S,et al.Synthesis and Charring of Arborescent Monomolecular P-N Intumescent Flameretardant[J]. Polym Mater Sci Eng,2012,28(7):10-13.
[66]	Qian L,Feng F,Tang S. Bi-phase Flame-retardant Effect of Hexa-phenoxy-cyclotriphosphazeneon Rigid Polyurethane Foams Containing Expandable Graphite[J]. Polymer,2014,55(1):95-101.
[67]	Qian L J,Ye L J,Xu G Z,et al.The Non-halogen Flame Retardant Epoxy Resin Based on a Novel Compound with Phosphaphenanthrene and Cyclotriphosphazene Double Functional Groups[J]. Polym Degrad Stab,2011,96(6):1118-1124.
[68]	Balabanovich A I,Pospiech D. Pyrolysis Behavior of Phosphorus Polyesters[J]. J Anal Appl Pyrolysis,2009,86(1):99-107.
[69]	Perret B,Schartel B. Novel DOPO-based Flame Retardants in High-performance Carbon Fibre Epoxy Composites for Aviation[J]. Eur Polym J,2011,47(5):1081-1089.
[70]	Zhao C S,Huang F L,Xiong W C,et al.A Novel Halogen-free Flame Retardant for Glass-fiber-reinforced Poly(ethylene terephthalate)[J]. Polym Degrad Stab,2008,93(6):1188-1193.
[71]	Ciesielski M,Schafer A,Doring M. Novel Efficient DOPO-based Flame-retardants for PWB Relevant Epoxy Resins with High Glass Transition Temperatures[J]. Polym Adv Technol,2008,19(6):507-515.
[72]	Zhang X,Zhong Y,Mao Z P. The Flame Retardancy and Thermal Stability Properties of Poly(ethylene terephthalate)/hexakis(4-nitrophenoxy) cyclotriphosphazene Systems[J]. Polym Degrad Stab,2012,97(8):1504-1510.
[73]	Despinasse M,Schartel B. Influence of the Structure of Aryl Phosphates on the Flame Retardancy of Polycarbonate/acrylonitrile-butadiene-styrene[J]. Polym Degrad Stab,2012,97(12):2571-2580.
[74]	BAN Daming,LIU Jiping. Synthesis, Characterization and Thermal Stability of Poly(resorcine phenyl phosphate)[J]. Chem J Chinese Univ,2013,24(5):1284-1287(in Chinese). 班大明,刘吉平. 聚苯基磷酸间苯二酚酯的合成、表征及热性能[J]. 高等学校化学学报,2013,24(5):1284-1287.
[75]	Li N N,Jiang G W,Zhou G Y. Synthesis and Characterization of a Cyclic 9,9-Bis(4-hydroxyphenyl)fluorine(phenylene phosphonate) oligomer and Its Flame Retardancy Application[J]. RSC Adv,2015,5(96):78815-78822.
[76]	Wang X,Song L,Xing W Y,et al.A Effective Flame Retardant for Epoxy Resins Based on Poly(DOPO Substituted Dihydroxyl Phenyl Pentaerythritol Diphosphonate)[J]. Mater Chem Phys,2011,125(3):536-541.
[77]	Wang X,Hu Y,Song L,et al.Synthesis and Characterization of a DOPO-substitued Organophosphorus Oligomer and Its Application in Flame Retardant Epoxy Resins[J]. Prog Org Coat,2011,71(1):72-82.
[78]	Wang X,Hu Y,Song L,et al.Thermal Degradation Mechanism of Flame Retarded Epoxy Resins with a DOPO-substitued Organophosphorus Oligomer by TG-FTIR and DP-MS[J]. J Anal Appl Pyrolysis,2011,92(1):1641-1670.
[79]	Ma H Y,Tong L F,Xu Z B,et al.A Novel Intumescent Flame Retardant:Synthesis and Application in ABS Copolymer[J]. Polym Degrad Stab,2007,92(4):720-726.
[80]	Zhou C,Wei Z Y,Yu Y,et al.Synthesis and Crystallization Behavior of Novel Poly(butylene succinate) copolyesters Containing Phosphorus Pendent Groups[J]. J Therm Anal Calorim,2015,120(3):1799-1810.
[81]	Zhang J B,Wang X L,He Q X,et al.A Novel Phosphorus-containing Poly(1,4-cyclohexylenedimethylene terephthalate) copolyester: Synthesis, Thermal Stability, Flammability and Pyrolysis Behavior[J]. Polym Degrad Stab,2014,108(SI):12-22.
[82]	Chen L,Ruan C,Yang R,et al.Phosphorus-containing Thermotropic Liquid Crystalline Polymers:A Class of Efficient Polymeric Flame Retardants[J]. Polym Chem,2014,5(12):3737-3749.
[83]	Lin C H,Huang C M,Wang M W,et al.Synthesis of a Phosphinated Acetoxybenzoic Acid and Its Application in Enhancing Tg and Flame Retardancy of Poly(ethylene terephthalate)[J]. J Polym Sci,Part A:Polym Chem,2014,52(3):424-434.
[84]	Lai X J,Tang S, Li H Q,et al.Flame-retardant Mechanism of a Novel Polymeric Intumescent Flame Retardant Containing Caged Bicyclic Phosphate for Polypropylene[J]. Polym Degrad Stab,2015,113:22-31.
[85]	DU Dajiang,CAO Fangli,CHEN Jia,et al.Synthesis of P-N Synergistic Alkyl Phosphinate Flame Retardants and Its Application on PBT[J]. J Jianghan Univ(Nat Sci Ed),2015,43(1):19-23(in Chinese). 杜大江,曹芳利,陈佳,等. 磷-氮协效型烷基次膦酸盐阻燃剂的合成及其在PBT中的应用[J]. 江汉大学学报(自然科学版),2015,43(1):19-23.
[86]	XU Jianzhong,LIU Xin,QU Hongqiang,et al.Application of Hypophosphite Flame Retardant in PBT and Its Synthesis[J]. Plast Sci Technol,2013,41(11):90-95(in Chinese). 徐建中,刘欣,屈红强,等. 次磷酸盐阻燃剂的合成及其在PBT中的应用[J]. 塑料科技,2013,41(11):90-95.
[87]	Chen L,Luo Y,Hu Z,et al.An Efficient Halogen-free Flame Retardant for Glass-fibre-reinforced Poly(butylene terephthalate)[J]. Polym Degrad Stab,2012,97(2):158-165.
[88]	Yan H W, Wei J L,Yin B, et al. Effect of the Surface Modification of Ammonium Polyphosphate on the Structure and Property of Melamine-formaldehyde Resin Microencapsulated Ammonium Polyphosphate and Polypropylene Flame Retardant Composites[J]. Polym Bull,2015,72(11):2725-2737.

Synthesis and Application Progress of Organic Phosphorus-Containing Flame Retardants

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[8]	JIN Rongrong1,2, MA Liqun1, YIN Dongming2, WANG Limin2,3*. Research Development of Cerium-Zinc Flow Battery [J]. Chinese Journal of Applied Chemistry, 2013, 30(08): 855-860.
[9]	YU Xuejiao, LIU Jianjun*, YU Yingchun, ZUO Shengli. Application of Fluorescent Quantum Dots Synthesized via Chemical Routes in Fingerprints Development [J]. Chinese Journal of Applied Chemistry, 2012, 29(08): 855-862.
[10]	CHEN Yan1,2, ZHANG Chunjing2, GAO Dongmei2, YANG Fan2, HAN Dongxue2* , NIU Li2*. Development of Visualization of Latent Fingerprints [J]. Chinese Journal of Applied Chemistry, 2011, 28(10): 1099-1107.