Microwave Assisted Synthesis of Ethylene Glycol Intercalated Nickel-aluminum Layered Double Hydroxides

doi:10.11944/j.issn.1000-0518.2016.01.150149

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (1): 84-91.DOI: 10.11944/j.issn.1000-0518.2016.01.150149

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Microwave Assisted Synthesis of Ethylene Glycol Intercalated Nickel-aluminum Layered Double Hydroxides

GUO Ke,DUAN Weizhuo,WANG Xiaodong,WU Yan,WANG Hao()

College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu 610500,China

Received:2015-04-27 Accepted:2015-10-21 Published:2016-01-05 Online:2016-01-05
Contact: WANG Hao
Supported by:
Supported by the National Natural Science Foundation of China(No.201506156), the National Undergraduate Training Programs for Innovation and Entrepreneurship(No.201410615005)

Abstract

Abstract:

Ethylene glycol(EG) intercalated layered double hydroxide(LDH) can be used as an interlayer catalytic reactor for the esterification of naphthenic acids with EG in oil. However, long synthesis time for EG intercalated LDH limits its further application. In the present investigation, EG intercalated NiAl-LDH was synthesized via a microwave-assisted ion exchange method by the aid of KOH and with nitrate LDH as precursor. The effects of microwave irradiating time and power, and the reaction temperature on the structure of EG intercalated LDH were investigated. XRD, FT-IR and TG-DSC were used to characterize EG intercalated LDHs prepared. Microwave irradiation was found to provide sufficient energy to accelerate the diffusion of exchanging anions into the interlayer and weaken the interaction between the layers and original interlayer anions. As a result, well-crystallized EG intercalated LDH can be synthesized under 550 W microwave irradiation at 120 ℃ for 10 min. The EG intercalated LDH prepared shows similar structure and properties and higher crystallinity as that prepared by conventional method, while the preparation time can be significantly reduced from 12 h to 10 min.

Key words: microwave, ethylene glycol intercalated, layered double hydroxide

GUO Ke, DUAN Weizhuo, WANG Xiaodong, WU Yan, WANG Hao. Microwave Assisted Synthesis of Ethylene Glycol Intercalated Nickel-aluminum Layered Double Hydroxides[J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 84-91.

References

[1]	Schutz A,Biloen P. Interlamellar Chemistry of Hydrotalcites:I.Polymerization of Silicate Anions[J]. J Solid State Chem,1987,68(2):360-368.
[2]	LIU Yu,YANG Xiangguang,ZHANG Zhongliang,et al.Synthesis and Characterization of Composite Oxide Mg-Al-M from Hydrotalcite and Its Catalytic Activity for NOx Removal[J]. Chinese J Catal,1999,20(4):450-454(in Chinese). 刘钰,杨向光,张忠良,等. 以水滑石为前体的Mg-Al-M复合氧化物对催化消除NOx的活性[J]. 催化学报,1999,20(4):450-454.
[3]	Benito P,Labajos F M,Rocha J,et al.Influence of Microwave Radiation on the Textural Properties of Layered Double Hydroxides[J]. Micropor Mesopor Mater,2006,94(1):148-158.
[4]	DU Yibo,HE Jing,LI Feng,et al.Preparation of Hydrotalcite and Hydrotalcite-Like Compounds by Microwave Techniques[J]. J Appl Sci,1998,16(3):100-105(in Chinese). 杜以波,何静,李峰,等. 微波技术在制备水滑石和柱撑水滑石中的应用[J]. 应用科学学报,1998,16(3):100-105.
[5]	ZHONG Qiong,LI Huan. Mg/Al Layered Double Hydroxides Prepared by Microwave-assisted Coprecipitation Method for the Removal of Bromate[J]. Environ Sci,2014,35(4):1566-1575(in Chinese). 钟琼,李欢. Mg/Al水滑石微波共沉淀法合成及其对BrO3-吸附性能的研究[J]. 环境科学,2014,35(4):1566-1575.
[6]	CHEN Chunxia,XU Chenghua,FENG Liangrong,et al.Catalytic Hydroxylation of Phenol over Pentatomic Hydrotalcite Prepared by Microwave Irradiation[J]. Chem Bull,2005,(2):123-127(in Chinese). 陈春霞,徐成华,冯良荣,等. 五元水滑石的微波晶化法合成及催化苯酚羟基化反应[J]. 化学通报,2005,(2):123-127.
[7]	CHEN Youmei. Study of Microwave-assisted Preparation and Properties of Inorganic Layered Mineral-drug Composites[D]. Xi'an:Xi'an University of Science and Technology,2010(in Chinese). 陈有梅. 微波辅助无机层状矿物-药物复合物的制备及特性研究[D]. 西安:西安科技大学,2010.
[8]	HE Heming,JIANG Dazhen,SUN Tie. Preparation and Synthesis of Hydrotalc in Microwave Field[J]. Chem J Chinese Univ,1992,13(11):1462-1463(in Chinese). 贺鹤鸣,蒋大振,孙铁. 微波场下水滑石的快速合成及制备[J]. 高等学校化学学报,1992,13(11):1462-1463.
[9]	HUANG Yanzhao,ZHU Jianhua,WU Bencheng,et al.Catalytic Esterification Deacidification of the Crude Oil with High Naphthenic Acid Content by ZnMgAl-HTlc[J]. Acta Pet Sin(Pet Process Sect),2009,25(5):731-735(in Chinese). 黄延召,朱建华,武本成,等. ZnMgAl-HTlc催化酯化高酸原油脱酸[J]. 石油学报(石油加工),2009,25(5):731-735.
[10]	Huang Y,Zhu J,Wu B,et al.Esterification Kinetics of Cyclohexanecarboxylic Acid and Ethylene Glycol in Diesel Oil with or without a ZnAl-HTlc Catalyst[J]. Pet Sci Technol,2011,29(21):2209-2219.
[11]	Guimaraes JL,Marangoni R, RamosLP, et al. Covalent Grafting of Ethylene Glycol into the Zn-Al-CO3 Layered Double Hydroxide[J]. J. Colloid Interface Sci,2000,227(2):445-451.
[12]	Stanimirova T,Hibino T. Ethylene Glycol Intercalation in MgAlCO3 Hydrotalcite and Its Low-temperature Intermediate Phases[J]. Appl Clay Sci,2006,31(1):65-75.
[13]	Wang H,Duan W,Wu Y,et al.Synthesis of Magnesium aluminum Layered Double Hydroxide Intercalated with Ethylene Glycol by the Aid of Alkoxides[J]. Inorg Chim Acta,2014,418:163-170.
[14]	Wang H,Duan W,Lei Y,et al.An Intracrystalline Catalytic Esterification Reaction between Ethylene Glycol Intercalated Layered Double Hydroxide and Cyclohexanecarboxylic Acid[J]. Catal Commun,2015,62:44-47.
[15]	XIE Xianmei,YAN Kai,HU Qiuxia,et al.Preparation and Catalytic Application of Copper-containing Hydrotalcite-like Compounds[J]. Chinese J Inorg Chem,2008,24(1):32-36(in Chinese). 谢鲜梅,严凯,胡秋霞,等. 铜铁二元类水滑石化合物的制备及催化性质研究[J]. 无机化学学报,2008,24(1):32-36.
[16]	LI Qiao,ZENG Hongyan,ZHANG Zhiqing,et al.Surface Chemical Performances and Electrochemical Behavior of Mg-Fe Hydrotalcite[J]. Chinese J Nonferrous Met,2014,24(6):1671-1677(in Chinese). 李巧,曾虹燕,张治青,等. 镁铁水滑石的表面化学性质及电化学行为[J]. 中国有色金属学报,2014,24(6):1671-1677.
[17]	SUN Yousong. Preparation andStudy on the Structure and Properties of Organic Anion-pillared Hydrotalcites[D]. Beijing:Beijing University of Chemical Technology,2010(in Chinese). 孙幼松. 有机阴离子柱撑水滑石的制备及结构和性能研究[D]. 北京:北京化工大学,2001.
[18]	Gabriel C,Gabriel S,Grant E H,et al.Dielectric Parameters Relevant to Microwave Dielectric Heating[J]. Chem Soc Rev,1998,27(3):213-224.
[19]	Lakraimi M,Legrouri A,Barroug A,et al.Preparation of a New Stable Hybrid Material by Chloride-2,4-dichlorophenoxyacetate Ion Exchange into the Zinc-aluminium-chloride Layered Double Hydroxide[J]. J Mater Chem,2000,10(4):1007-1011.
[20]	SUN Yousong,JIAO Qingze,ZHAO Yun,et al.Assembly and Structural Characterization of Terephthalate-pillared Hydrotalcites[J]. Chinese J Appl Chem,2001,18(10):781-784(in Chinese). 孙幼松,矫庆泽,赵芸,等. 对苯二甲酸柱撑水滑石的组装及其结构特征[J]. 应用化学,2001,18(10):781-784.
[21]	XING Ying,LI Dianqing,REN Lingling,et al.Assembly and Structural Characteristics of Supramolecular Salicylate-pillared Hydrotalcites[J]. Acta Chim Sin,2003,61(2):267-272(in Chinese). 邢颖,李殿卿,任玲玲,等. 超分子结构水杨酸根插层水滑石的组装及结构与性能研究[J]. 化学学报,2003,61(2):267-272.
[22]	Li Z,Xiang X,Bai L,et al. A Nanocomposite Precursor Strategy to Mixed-metal Oxides with Excellent Catalytic Activity for Thermal Decomposition of Ammonium Perchlorate[J]. Appl Clay Sci, 2012,65/66:14-20.
[23]	YANG Zhengwen,JIANG Yinshan,WANG Anping,et al.Preparation of Thermally Stable Nanohydroxyapatite by Microwave Process[J]. J Inorg Mater,2004,19(4):839-844(in Chinese). 杨正文,蒋引珊,王安平,等. 微波法快速制备高稳定性纳米羟基磷灰石[J]. 无机材料学报,2004,19(4):839-844.
[24]	ZHANG Maisheng,YAO Yunfeng,YANG Yansheng. Studies on Synthesis of MCM-41 Mesoporous Molecular Sieve by Microwave Radiation Method by Means of X-Ray Diffraction[J]. Chinese J Inorg Chem,2000,16(1):119-122(in Chinese). 张迈生,姚云峰,杨燕生. XRD粉末衍射法研究全微波合成的MCM-41介孔分子筛[J]. 无机化学学报,2000,16(1):119-122.
[25]	Fetter G,Botello A,Lara V H,et al.Detrital Mg(OH)2 and Al(OH)3 in Microwaved Hydrotalcites[J]. J Porous Mater,2001,8(3):227-232.
[26]	Meyn M,Beneke K,Lagaly G. Anion-exchange Reactions of Layered Double Hydroxides[J]. Inorg Chem,1990,29(26):5201-5207.
[27]	Huwe A,Kremer F,Behrens P,et al.Molecular Dynamics in Confining Space:From theSingle Molecule to the Liquid State[J]. Phys Rev Lett,1999,82(11):2338-2341.

Microwave Assisted Synthesis of Ethylene Glycol Intercalated Nickel-aluminum Layered Double Hydroxides

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