Synthesis, Structure Characterization and Magnetic Property of a New Molybdenum-vanadium Polyoxometalate

doi:10.3724/SP.J.1095.2014.30648

Chinese Journal of Applied Chemistry

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Synthesis, Structure Characterization and Magnetic Property of a New Molybdenum-vanadium Polyoxometalate

SUN Yinghua^1,2*, YANG Meiling¹, GUO Qingfang³, CHEN Di¹, JIANG Xiaoyu¹

(1.Department of Chemistry,Baicheng Normal College,Baicheng 137000,China;
2.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130012,China;
3.Group of Chemistry,Baicheng Second Middle School，Baicheng 137000,China)

Received:2013-12-20 Revised:2014-04-08 Published:2014-09-04 Online:2014-09-04

Abstract

Abstract: A new molybdenum-vanadium polyoxometalate [PⅤMoⅥ7MoⅤVⅣ8O44][Ni(Phen)2OH]4·3H2O(1) was prepared under hydrothermal conditions, and characterized by elemental analysis, IR and single crystal X-ray diffraction analysis. The title compound crystallized in a triclinic system, P-1 space group, a=1.51300(11) nm, b=1.74813(15) nm, c=2.58896(18) nm, α=72.842(4)°, β=89.240(5)°, γ=72.627(5)°, V=6.2233(8) nm3, Z=1, R1=0.0962, wR2=0.2572. Compound 1 is composed of a highly reduced tetra-capped pseudo-Keggin polyoxoanion supporting four transition metal complexes. There are many hydrogen bond among polyoxoanion and water molecules, which enable the formation of three dimensional supramolecular array.

Key words: molybvanudates, supramolecular, hydrothermal synthesis, magnetic properties

CLC Number:

O611.4

SUN Yinghua1,2*, YANG Meiling1, GUO Qingfang3, CHEN Di1, JIANG Xiaoyu1. Synthesis, Structure Characterization and Magnetic Property of a New Molybdenum-vanadium Polyoxometalate[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30648.

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Synthesis, Structure Characterization and Magnetic Property of a New Molybdenum-vanadium Polyoxometalate

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