Preparation and Characterization of Rare Earth Europium Containing Bifunctional Fluorescent Magnetic Nanoparticles

doi:10.3724/SP.J.1095.2014.30607

Chinese Journal of Applied Chemistry

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Preparation and Characterization of Rare Earth Europium Containing Bifunctional Fluorescent Magnetic Nanoparticles

LI Zheng¹, ZHU Haie¹, ZHOUYingjie¹, YAN Kai¹, YI Changfeng^1,2, XU Zushun^2*

(1.College of Materials Science and Engineering;2.Ministry-of-Education Key Laboratory for the
Green Preparation and Application of Functional Materials, Hubei University,Wuhan 430062,China)

Received:2013-12-02 Revised:2013-12-24 Published:2014-07-10 Online:2014-07-10

Abstract

Abstract: Firstly oleic acid and sodium undecylenate modified water-soluble magnetic fluid was prepared. Then in the presence of water-based magnetic fluid, fluorescent magnetic nanoparticles were successfully synthesized by soap-free and seeded emulsion polymerization of rare earth complex monomer Eu(AA)3Phen(AA=acrylic acid, phen=1,10-phenanthroline) polymerized with styrene(St) and glycidyl methacrylate(GMA) using potassium persulfate(KPS) as the initiator. The morphology and size of the products were characterized by transmission electron microscopy(TEM) and dynamic light scattering(DLS) granulometer. Experimental results show that the fluorescent magnetic nanoparticles have obvious core-shell structures. Their particle sizes are smaller than 100 nm and have narrow size distribution. The chemical and crystalline structures of the particles were analyzed by Fourier transform infrared spectroscopy(FTIR) and X-ray diffraction(XRD). The magnetic and fluorescent properties of the particles were characterized by vibrating sample magnetometer(VSM) and fluorescence spectrophotometer. These results show that the fluorescent nanoparticles exhibit the superparamagnetic property. Their fluorescence emission spectra show characteristic emission peaks of Eu3+ at 594 and 619 nm, respectively.

Key words: water-based magnetic fluid, soap-free and seeded emulsion polymerization, rare earth, europium, fluorescent magnetic nanoparticles

CLC Number:

O631

LI Zheng1, ZHU Haie1, ZHOUYingjie1, YAN Kai1, YI Changfeng1,2, XU Zushun2*. Preparation and Characterization of Rare Earth Europium Containing Bifunctional Fluorescent Magnetic Nanoparticles[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30607.

References

[1] LIU Chunli,HAN Zhaorang,CUI Linlin,et al. Synthesis and Characterization of Fe3O4/Polystyrene Microspheres[J]. Polym Mater Sci Eng,2008,24(3):137-140(in Chinese).

刘春丽,韩兆让,崔琳琳,等. Fe3O4/聚苯乙烯磁性微球的合成与表征[J]. 高分子材料科学与工程,2008,24(3):137-140.

[2] Shi D,Cho H S,Chen Y,et al. Fluorescent Polystyrene-Fe3O4 Composite Nanospheres for in Vivo Imaging and Hyperthermia[J]. Adv Mater,2009,21(21):2170-2173.

[3] Kang X,Cheng Z,Yang D,et al. Design and Synthesis of Multifunctional Drug Carriers Based on Luminescent Rattle-Type Mesoporous Silica Microspheres with a Thermosensitive Hydrogel as a Controlled Switch[J]. Adv Funct Mater,2012,22(7):1470-1481.

[4] Murdan S. Electro-responsive Drug Delivery from Hydrogels[J]. J Control Release,2003,92(1):1-17.

[5] Zhang R,Liu J,Wang S,et al. Magnetic CuFe2O4 Nanoparticles as an Efficient Catalyst for CO Cross-Coupling of Phenols with Aryl Halides[J]. Chem Cat Chem,2011,3(1):146-149.

[6] Foy S P,Manthe R L,Foy S T,et al. Optical Imaging and Magnetic Field Targeting of Magnetic Nanoparticles in Tumors[J]. ACS Nano,2010,4(9):5217-5224.

[7] Guo J,Yang W,Wang C,et al. Poly(N-isopropylacrylamide)-coated Luminescent/Magnetic Silica Microspheres:Preparation, Characterization, and Biomedical Applications[J]. Chem Mater,2006,18(23):5554-5562.

[8] Xu H,Cheng L,Wang C,et al. Polymer Encapsulated Upconversion Nanoparticle/iron Oxide Nanocomposites for Multimodal Imaging and Magnetic Targeted Drug Delivery[J]. Biomaterials,2011,32(35):9364-9373.

[9] GU Yinjun,WANG Xiuling,ZHAO Qin,et al. Preparation and Characterization of Bifunctional Fluorescent Magnetic Dendrimer Microspheres[J]. Chem J Chinese Univ,2012,33(5):885-891(in Chinese).

顾银君,王秀玲,赵勤,等. 荧光磁性双功能树状分子微球的制备与表征[J]. 高等学校化学学报,2012,33(5):885-891.

[10] Guo J,Yang W,Deng Y,et al. Organic-dye-coupled Magnetic Nanoparticles Encaged Inside Thermoresponsive PNIPAM Microcapsules[J]. Small,2005,1(7):737-743.

[11] JIANG Feirong,JIA Wenting,ZHANG Xingshen,et al. Fluorescent Quantum Dots Probes and Their Biological Labeling[J]. Chinese Bull Life Sci,2010,22(4):391-395(in Chinese).

蒋飞荣,贾文婷,张兴燊,等. 荧光量子点探针及其标记技术[J]. 生命科学,2010,22(4):391-395.

[12] Selvan S T,Tan T T,Ying J Y. Robust, Non-Cytotoxic, Silica-Coated CdSe Quantum Dots with Efficient Photoluminescence[J]. Adv Mater,2005,17(13):1620-1625.

[13] Sun Ruixue,CHEN Liping,CHEN Kezheng. Research Progress in the Preparation of Magnetic Fluorescent Nanoparticles[J]. Mater Rev,2011,25(5):20-23(in Chinese).

孙瑞雪,陈丽平,陈克正. 磁性荧光纳米复合微粒的制备方法及研究进展[J]. 材料导报,2011,25(5):20-23.

[14] WU Boyue,YAN Xiuping. Lanthanide Luminescence for Bioimaging[J]. Acta Biophys Sin,2011,27(4):289-300(in Chinese).

吴伯岳,严秀平. 稀土发光材料在荧光成像中的应用[J]. 生物物理学报,2011,27(4):289-300.

[15] Gai S,Yang P,Li C,et al. Synthesis of Magnetic, Up-Conversion Luminescent, and Mesoporous Core-Shell-Structured Nanocomposites as Drug Carriers[J]. Adv Funct Mater,2010,20(7):1166-1172.

[16] Ma Z Y,Dosev D,Nichkova M,et al. Synthesis and Bio-functionalization of Multifunctional Magnetic Fe3O4@ Y2O3∶Eu Nanocomposites[J]. J Mater Chem,2009,19(27):4695-4700.

[17] Zhang Y,Pan S,Teng X,et al. Bifunctional Magnetic-Luminescent Nanocomposites:Y2O3/Tb Nanorods on the Surface of Iron Oxide/Silica Core-Shell Nanostructures[J]. J Phys Chem C,2008,112(26):9623-9626.

[18] Tong L,Shi J,Liu D,et al. Luminescent and Magnetic Properties of Fe3O4@SiO2@Y2O3∶Eu3+ Composites with Core Shell Structure[J]. J Phys Chem C,2012,116(12):7153-7157.

[19] Yang P,Quan Z,Hou Z,et al. A Magnetic, Luminescent and Mesoporous Core shell Structured Composite Material as drug Carrier[J]. Biomaterials,2009,30(27):4786-4795.

[20] WANG Julan,XUE Ping. Synthesis of Hydrophilic Polymer Magnetic Microspheres and Its Application[J]. Appl Chem Ind,2008,37(8):934-938(in Chinese).

王居兰,薛屏. 亲水性高分子磁性微球的合成和应用研究[J]. 应用化工,2008,37(8):934-938.

[21] ZHOU Yingjie,ZHU Haie,ZHANG Jun,et al. Preparation and Characterization of Fluorescent Copolymer Emulsion Containg Europium by Soap-Free Emulsion Polymerazation[J]. Acta Polym Sin,2012,(9):923-928(in Chinese).

周英杰,朱海娥,张俊,等. 无皂乳液聚合制备含铕荧光共聚物乳液的研究及其表征[J]. 高分子学报,2012,(9):923-928.

[22] Pan Y,Zheng A,Hu F,et al. Copolymers of Styrene with a Quaternary Europium Complex[J]. J Appl Polym Sci,2006,100(2):1506-1510.

[23] AN Lijuan,LI Zhaoqiang,XU Wei,et al. Preparation and Characterization of Superparamagnetic Polymer Microspheres[J]. Chem J Chinese Univ,2005,26(2):366-369(in Chinese).

安丽娟,李兆强,徐娓,等. 超顺磁性高分子微球的制备与表征[J]. 高等学校化学学报,2005,26(2):366-369.

[24] Pan Y,Zheng A,Hu F,et al. Copolymers of Styrene with a Quaternary Europium Complex[J]. J Appl Polym Sci,2006,100(2):1506-1510.

[25] Hu X X,Li P H,Yeung K W K,et al. Synthesis and Characterization of Fluorescent Copolymer Containing Rare Earth Metal Complex and Its Interaction with DNA[J]. J Polym Sci,Part A:Polym Chem,2010,48(24):5961-5967.

Preparation and Characterization of Rare Earth Europium Containing Bifunctional Fluorescent Magnetic Nanoparticles

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