Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc

doi:10.3724/SP.J.1095.2012.00271

Chinese Journal of Applied Chemistry

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Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc

BAI Qinglong^1,2, ZHANG Chunhua¹, CHENG Chuanhui^2*, LI Wancheng³, DU Guotong^2,3

(1.College of Chemistry and Chemical Engineering,Inner Mongglia University for Nationalities,Tongliao 028043,China;
2.School of Physics and Optoelectronic Technology,Dalian University of Technology,Dalian 116024,China;
3.College of Electronic Science and Engineering,Jilin University,Changchun 130012,China)

Received:2011-06-22 Revised:2011-09-24 Published:2012-06-10 Online:2012-06-10

Abstract

Abstract: α(β)-tetra-phenoxy phthalocyaninato zinc complexes have been synthesized via a two-step process using 3(4)-nitrobenzene-1,2-dicarbonitrile and phenol as precursors. The products were characterized by means of IR spectrum, UV-Vis spectrum, 1H NMR spectrum, mass spectrum and elemental analysis. The UV-Vis spectra, photoluminescence spectra of spin-coated film and pressed solid pellet were compared. The fluorescences of both compressed and spin-coated samples had red-shifts larger than 161 nm compared to that obtained from solution. In addition, their fluorescence peaks are broader than that in solution. The fluorescence of β-substituted phthalocyanines has a greater red-shift than that of α-substituted phthalocyanines. The two kinds of fabricated devices showed similar electroluminescent spectra around 880 nm.

Key words: phenoxyphthalocyanines, Synthesis, Photoluminescence, Electroluminescence, red-shift

CLC Number:

O644

BAI Qinglong1,2, ZHANG Chunhua1, CHENG Chuanhui2*, LI Wancheng3, DU Guotong2,3. Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2012.00271.

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Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc

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