Determination of the Reactivity Ratios of Copolymerization between Vinyl-containing Polysiloxane and Vinyl Monomers and the Influence on the Morphology of Composite Particles

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (6): 15-18.

• Full Papers • Previous Articles Next Articles

Determination of the Reactivity Ratios of Copolymerization between Vinyl-containing Polysiloxane and Vinyl Monomers and the Influence on the Morphology of Composite Particles

He Weidong¹, Cao Chuntao¹, Pan Caiyuan¹, Feng Jianping²

1. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026;
2. Centre of Stucture and Component Analysis, University of Science and Technology of China, Hefei

Received:1996-01-31 Revised:1996-07-10 Published:1996-12-10 Online:1996-12-10

Abstract

Abstract: The copolymerization reactivity ratios of vinyl-containing polysiloxane(SV) with styrene(ST),methyl methacrylate(MMA) or n-butyl methacrylate(BMA) were measured using Fineman-Ross method,and the results were:r_st =1.45 and r_sv =1.08 for ST-SV,r_MMA =0.78 and r_sv=2.01 for MMA-SV,r_n-BMA =0.46 and r_sv =3.49 for BMA-SV,respectively.The reactivity ratios between vinyl-containing polysiloxane and vinyl monomers had a strong effect on the morphology of the particles prepared by the seeded emulsion polymerization.

Key words: vinyl-containing polysiloxane, vinyl monomer, copolymerization, reactivity ratio, seeded emulsion polymerization

He Weidong, Cao Chuntao, Pan Caiyuan, Feng Jianping. Determination of the Reactivity Ratios of Copolymerization between Vinyl-containing Polysiloxane and Vinyl Monomers and the Influence on the Morphology of Composite Particles[J]. Chinese Journal of Applied Chemistry, 1996, 0(6): 15-18.

[1]	Li DONG, Xiangdong LIU, Zhengrong XIONG, Yuming YANG. Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride) [J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 776-780.
[2]	WANG Jiabao, MU Hongliang, LI Yuesheng. Vanadium Complexes Containing Pyridylimine(amine) Ancillary Ligands for Olefin Polymerization [J]. Chinese Journal of Applied Chemistry, 2015, 32(5): 510-518.
[3]	ZHENG Chao, HUANG Haiying, HE Tianbai. Research Progress in Gradient Copolymers [J]. Chinese Journal of Applied Chemistry, 2014, 31(11): 1237-1247.
[4]	LI Zheng1, ZHU Haie1, ZHOUYingjie1, YAN Kai1, YI Changfeng1,2, XU Zushun2*. Preparation and Characterization of Rare Earth Europium Containing Bifunctional Fluorescent Magnetic Nanoparticles [J]. Chinese Journal of Applied Chemistry, 2014, 31(07): 828-834.
[5]	LI Aiyuan1*, SHI Liqin1, SUN Xiangdong1,2, WANG Bin2, ZHANG Huibo1. Copolymerization Technology of α-Pinene and 1,3-Pentadiene [J]. Chinese Journal of Applied Chemistry, 2014, 31(06): 661-666.
[6]	JIA Yi1,2*, ZHU Chunjiang1, QIN Zheng3, SUN Yongfei3. Preparation and Performance of Hydroxyl-Terminated Oligomeric Polysiloxane Grafted Toughened Phenolic Resins [J]. Chinese Journal of Applied Chemistry, 2014, 31(05): 566-569.
[7]	DING Wei*, LIU Kang, LUAN Huoxin, YU Tao, QU Guangmiao. Synthesis of Novel Cationic Copolymer Acrylamide/Acrylic Acid Ester by Single Electron Transfer Living Radical Polymerization in Aqueous Solution [J]. Chinese Journal of Applied Chemistry, 2013, 30(06): 648-654.
[8]	ZHU Deqin, SHENG Yu*, ZOU Yinjiang, FANG Zhen, SU Xiaofen. Effect of Modifiers on the Performance of Polypropylene/Calcium Carbonate Composites [J]. Chinese Journal of Applied Chemistry, 2013, 30(06): 655-660.
[9]	DING Wei*, WANG Ling, YU Tao, QU Guangmiao, GAO Xiang, LI Ming. Atom Transfer Radical Copolymerization of Acrylamide Under Microwave Irradiation [J]. Chinese Journal of Applied Chemistry, 2013, 30(04): 398-402.
[10]	PAN Yupeng1,2, XIE Hongyan1,2, CUI Dongmei1*. Novel Constrained-geometry-configuration Rare-earth Metal Precursors to Obtain Styrene-Styrene Copolymers [J]. Chinese Journal of Applied Chemistry, 2012, 29(12): 1389-1393.
[11]	ZHANG Kai1*, HUANG Chunbao1, SHEN Huifang2, CHEN Huanqin2. Structure and Morphology of Polychloroprene-Polymethylmethacrylate Composite Latex Particles [J]. Chinese Journal of Applied Chemistry, 2012, 29(10): 1111-1116.
[12]	LI Zhifeng1,2, QIN Yusheng1, ZHAO Xiaojiang1, WANG Xianhong1*, WANG Fosong1. Copolymerization Between Propylene Oxide and Carbon Dioxide under Rare Earth Metal Complex/Double Metal Cyanide Complex Catalyst [J]. Chinese Journal of Applied Chemistry, 2012, 29(09): 985-989.
[13]	YUAN Donghai1, TANG Anbin1,2*, HUANG Jie2, MA Hanbing1. Synthesis of Hexaphenoxycyclotriphosphazene with Allyl Group and Application in Flame Retardant Acrylate Resin [J]. Chinese Journal of Applied Chemistry, 2012, 29(09): 1090-1092.
[14]	WANG Qingling, HU Yingmo*, BIAN Jing. Synthesis and Characterization of Starch/Lactic Acid Graft Copolymer Catalyzed with Zinc Oxide [J]. Chinese Journal of Applied Chemistry, 2012, 29(03): 256-259.
[15]	BI Kezhen, ZHANG Yuejun*. Kinetics Study on Polymerization of Acrylamide and Dimethyldiallylammonium Chloride [J]. Chinese Journal of Applied Chemistry, 2011, 28(12): 1354-1359.

Determination of the Reactivity Ratios of Copolymerization between Vinyl-containing Polysiloxane and Vinyl Monomers and the Influence on the Morphology of Composite Particles

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments