Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride)

doi:10.11944/j.issn.1000-0518.2018.07.170331

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (7): 776-780.DOI: 10.11944/j.issn.1000-0518.2018.07.170331

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Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride)

Li DONG^a^b,Xiangdong LIU^a,Zhengrong XIONG^a,Yuming YANG^a^*()

^aLaboratory of Polymer Composites Engineering,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
^bUniversity of Science and Technology of China,Hefei 230026,China

Received:2017-09-12 Accepted:2017-11-10 Published:2018-07-06 Online:2018-07-06
Contact: Yuming YANG

Abstract

Abstract:

The macromolecular ultraviolet(UV) absorber P(MMA-co-BPMA) was synthesized by copolymerization of 2-hydroxy-4-(3-methacryloxy-2-hydroxylpropoxy) benzophenone(BPMA) and methylmethacrylate(MMA) through atom transfer radical polymerization(ATRP). The UV-absorbing poly(vinylidene fluoride)(PVDF) composite membranes were made by blend coating. The structure and property of BPMA and P(MMA-co-BPMA) were characterized by nuclear magnetic resonance spectroscopy(NMR), gel permeation chromatography(GPC) and differential scanning calorimeter(DSC). UV absorbing property of the obtained composite membranes was investigated by UV-Vis spectroscopy. The results demonstrate that the relative molecular mass polydispersity index(PDI) of P(MMA-co-BPMA) is 1.11. When the mass fraction of BPMA is 0.68%, the UV transmittance of P(MMA-co-BPMA)/PVDF composite membrane decreases to less than 0.4% in the range of 200~345 nm. In addition, copolymerization of the UV absorber effectively prevents the out-migration as demonstrated in the extraction experiment.

Key words: ultra-violet absorbing, poly(vinylidene fluoride), copolymerization, blends

Li DONG, Xiangdong LIU, Zhengrong XIONG, Yuming YANG. Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride)[J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 776-780.

References

[1]	Ge F J,Huang Y,Luo Y,et al. Macromolecular Chain Structure Design, Synthesis and Analysis of Poly(L-lactide) Linking Ultraviolet Absorbing Groups[J]. RSC Adv,2014,4(108):63118-63127.
[2]	Zhao Y,Dan Y.Preparation and Characterization of a High Molecular Weight UV-Stabilizer Based on a Derivative of 2,4-Dihydroxybenzophenone and Its Application in Polymer Materials[J]. J Appl Polym Sci,2006,102(3):2203-2211.
[3]	Cohen S,Haham H,Pellach M,et al. Design of UV-Absorbing Polypropylene Films with Polymeric Benzotriaziole Based Nano- and Microparticle Coatings[J]. ACS Appl Mater Interfaces,2016,9:868-875.
[4]	Wang X L,Zhou S X,Wu L M.Fabrication of Fe3+ Doped Mg/Al Layered Double Hydroxides and Their Application in UV Light-Shielding Coatings[J]. J Mater Chem A,2014,2(29):5752-5758.
[5]	Fernandes S C M,Alonso-Varona A,Palomares T,et al. Exploiting Mycosporines as Natural Molecular Sunscreens for the Fabrication of UV-Absorbing Green Materials[J]. ACS Appl Mater Interfaces,2015,7(30):16558-16564.
[6]	Xie S Y,Zhao J F,Zhang B W,et al. Graphene Oxide Transparent Hybrid Film and Its Ultraviolet Shielding Property[J]. ACS Appl Mater Interfaces,2015,7(32):17558-17564.
[7]	Zhao G,Chen W N.Enhanced PVDF Membrane Performance via Surface Modification by Functional Polymer Poly(N-isopropylacrylamide) to Control Protein Adsorption and Bacterial Adhesion[J]. React Funct Polym,2015,97:19-29.
[8]	Kang G D,Cao Y M.Application and Modification of Poly(vinylidene fluoride)(PVDF) Pembranes-A Review[J]. J Membr Sci,2014,463:145-165.
[9]	He F,Luo B W,Yuan S J,et al. PVDF Film Tethered with RGD-Click-Poly(glycidyl methacrylate) Brushes by Combination of Direct Surface-Initiated ATRP and Click Chemistry for Improved Cytocompatibility[J]. RSC Adv,2014,4(1):105-117.
[10]	Jiang J H,Zhu L P,Zhu L J,et al. Surface Characteristics of a Self-Polymerized Dopamine Coating Deposited on Hydrophobic Polymer Films[J]. Langmuir,2011,27(23):14180-14187.
[11]	Sun H X,Wang T T,Zhou Y Y,et al. Synthesis of Well-Defined Amphiphilic Block Copolymers via AGET ATRP Used for Hydrophilic Modification of PVDF Membrane[J]. J Appl Polym Sci,2015,132(24).DOI:
[12]	Hua H,Xiong Y,Fu C J,et al. pH-Sensitive Membranes Prepared with Poly(methyl methacrylate) Grafted Poly(vinylidene fluoride) via Ultraviolet Irradiation-Induced Atom Transfer Radical Polymerization[J]. RSC Adv,2014,4(74):39273-39279.
[13]	Kong Z Y,Wei J F,Yang L,et al. Stability of Acrylic Acid Grafted Poly(vinylidene fluoride) Hollow Fiber Membrane Prepared by High-Energy Electron Beam[J]. J Appl Polym Sci,2014,131(23).DOI:
[14]	DONG Li,XIONG Zhengrong,LIU Xiangdong,et al. Study on Pre-Irradiation Grafting Method to Improve Ultraviolet Absorption Property of PVDF[J]. Eng Plast Appl,2017,45(1):23-28(in Chinese). 董莉,熊征蓉,刘向东,等. 预辐照接枝法提高PVDF的紫外线吸收性能[J]. 工程塑料应用,2017,45(1):23-28.
[15]	Dong L,Liu X D,Xiong Z R,et al. Fabrication of Highly Efficient Ultraviolet Absorbing PVDF Membranes via Surface Polydopamine Deposition[J]. J Appl Polym Sci,2018,135(4).DOI:
[16]	Li N,Chen Y H,Bao Y J,et al. Evaluation of UV-Permeability and Photo-Oxidisability of Organic Ultraviolet Radiation-Absorbing Coatings[J]. Appl Surf Sci,2015,332:186-191.

Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride)

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