Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (5): 10-13.

• Full Papers • Previous Articles Next Articles

Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups

Pan Yan, Huang Yuhui, Cong Guangmin

Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650

Received:1995-11-22 Revised:1996-03-18 Published:1996-10-10 Online:1996-10-10

Abstract

Abstract: The chemical modification of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) has been carried out by incorporating nitro or amino groups in the PPO backbone. The obtained maximum monosubstitution value is 95% or 65% respectively. The effects of reaction conditions on the functional group contents in PPO were discussed. The modified PPO obtained was characterized by FT-IR、¹H NMR spectroscopy, nitrogen analysis, solubility test and X-ray diffraction study.

Key words: poly(phenylene oxide), amination, nitration, substitution value

Pan Yan, Huang Yuhui, Cong Guangmin. Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups[J]. Chinese Journal of Applied Chemistry, 1996, 0(5): 10-13.

[1]	NIU He-Qiang, WU Fa-Si, WANG Li-Qin, FAN Zai-Xuan. Research Progress of Gel Materials for the Removal of Stains on Cultural Relics Surface [J]. Chinese Journal of Applied Chemistry, 2021, 38(11): 1441-1453.
[2]	ZHANG Hualiang,YANG Shi,XU Chao,HONG Chao,YUAN Hua. Synthesis of Ethylenediamine by Catalytic Ammoniation of Ethylene Glycol [J]. Chinese Journal of Applied Chemistry, 2017, 34(5): 557-562.
[3]	BI Haoyu, LIANG Yaqin, LI Yan. Adsorption of p-Cresol on X-Type Gemini Surfactant-modified Hydrotalcite-like Nanocomposite [J]. Chinese Journal of Applied Chemistry, 2017, 34(11): 1329-1335.
[4]	XIA Ran, SUN Liping, QU Guirong, CHEN Leishan. Synthesis of Anti-leukemia Drug Cladribine [J]. Chinese Journal of Applied Chemistry, 2016, 33(11): 1274-1278.
[5]	LIU Lijun, CI Yingqian, WANG Qiliao, GONG Shuwen*, CUI Qingxin. Selective Catalytic Nitration of Phenol to o-Nitrophenol by Silica Supported Cesium Salts of Molybdovanadophosphoric Acid [J]. Chinese Journal of Applied Chemistry, 2014, 31(07): 817-822.
[6]	WU Jinming1, SHI Lei1, SHEN Aibao1, TANG Yanfeng1, LU Tianhong2,3. Selective Nitration of Phenols via* H₆PMo₉V₃O₄₀/SiO₂ catalysts [J]. Chinese Journal of Applied Chemistry, 2014, 31(04): 437-443.
[7]	WU Jinming, TANG Yanfeng, SHEN Aibao*. Synthesis of 5-Nitrosalicylaldehyde Catalyzed by H₆PMo₉V₃O₄₀ Supported on Silica Gel [J]. Chinese Journal of Applied Chemistry, 2012, 29(05): 545-550.
[8]	ZHAO Xiaofeng, LIU Zuliang*. Amination of Aminonitropyridine and Its N-Oxide via Vicarious Nucleophilic Substitution of Hydrogen [J]. Chinese Journal of Applied Chemistry, 2011, 28(04): 376-381.
[9]	WANG Peng-Cheng, CHEN Jing, LU Ming*. Nitration of Single-substituted Benzenes [J]. Chinese Journal of Applied Chemistry, 2010, 27(07): 783-786.
[10]	HU Yu-Feng, LUO Jun, LV Chun-Xu*. Synthesis of Fluoroaromatics via Fluorodenitrations with Tetramethylammonium Fluoride [J]. Chinese Journal of Applied Chemistry, 2010, 27(06): 669-672.
[11]	GONG Shu-Wen1*, WANG Xiang-Yu2, LI Kao-Zhen1, CUI Qing-Xin1, DENG Xiu-Juan1. Nitration of benzene catalyzed by supported ammonium molybdophosphat catalyst [J]. Chinese Journal of Applied Chemistry, 2010, 27(04): 428-431.
[12]	LIU Yan-Zhu*, LI Yong-Xiu, LI Xia, ZHANG Ling. Nitration Reaction betweem Methyl Salicylate and Iron(Ⅲ) Nitrate and its Regioselectivity [J]. Chinese Journal of Applied Chemistry, 2010, 27(04): 432-436.
[13]	LI Meng-Long, CHENG Jian, CAO Shao-Ting, LIU JZu-Liang*. Improved process for the synthesis of 2-mercapto-5-methoxyimidazo[4,5-b]pyridine [J]. Chinese Journal of Applied Chemistry, 2010, 27(01): 122-124.
[14]	. Investigation on Supported Heteropoly Acids Assisted Selective Nitration of Chlorobenzene with N2O5 [J]. Chinese Journal of Applied Chemistry, 2009, 26(6): 676-680.
[15]	ZHAO Xin*, SHU Hui-Li, GE Ji-Yun. Regioselective Nitration of Toluene in Caprolactam-trifluoromethanesulfonic Acid Ionic Liquid [J]. Chinese Journal of Applied Chemistry, 2009, 26(08): 905-908.

Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments