Synthesis and Characteristics of an Organic Derivative of Phosphomolybdic Acid with Weak Cu-N Bond

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (3): 99-101.

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Synthesis and Characteristics of an Organic Derivative of Phosphomolybdic Acid with Weak Cu-N Bond

Zhang Mingjie, Cui Rong, Nie Yumin, Liu Reixan, Xie Cunyan

Department of Chemistry, Tianjin University, Tianjin 300072

Received:1995-09-11 Revised:1995-12-18 Published:1996-06-10 Online:1996-06-10

Abstract

Abstract: The reaction of E(EDTB)Cu](CH₃COO)₂ with H₃PMo₁₂O₄₀in absolute ethanol produces[(EDTB)Cu](HPMo₁₂O₄₀)(C₂H₅OH)₆,in which EDTB is N,N,N′,N′-tetrakis [(2-benzimidazolyl)methyl]-1,2-ethanediamine.A comparative study of IR spectra、UV-Vis spectra,¹H NMR and elemental analysis for the product and reference molecule[(EDTB) Cu](NO₃)₂ confirms the structure of the title compound.

Key words: organic derivative of phosphomolybdic acid, weak Cu—N bond complex, tetrakis(benzimidazolyl methyl)ethanediamine, synthesis

Zhang Mingjie, Cui Rong, Nie Yumin, Liu Reixan, Xie Cunyan. Synthesis and Characteristics of an Organic Derivative of Phosphomolybdic Acid with Weak Cu-N Bond[J]. Chinese Journal of Applied Chemistry, 1996, 0(3): 99-101.

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Synthesis and Characteristics of an Organic Derivative of Phosphomolybdic Acid with Weak Cu-N Bond

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