Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (2): 41-44.

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Synthesis of Halogenated Toluenes and Its Liquid Phase Oxidation with Co (OAc)2-Mn (OAc)2-NaBr

Wang Shuliang, Dai Guiyuan, Shi Daqing   

  1. Department of Chemistry, Xuzhou Teachers College, Xuzhou 221009
  • Received:1995-07-10 Revised:1995-11-06 Published:1996-04-10 Online:1996-04-10

Abstract: Fluorotoluene and halogenated 3-fluorotoluenes have been synthesized and oxidized by Co(OAc)2-Mn(OAc)2-NaBr system to the corresponding carboxylic acids in liquid phase with good yields. All the compounds are characterized by UV, IR, 1H NMR, MS spectrometry and elemental analysis.

Key words: halogenated toluene, halogenated benzoic acid, synthesis, liquid phase oxidation