Preparation of Chromium(Ⅲ) Phenanthroline and 8-Hydroxyquinoline Complexes/Y-Zeolite and Catalytic Hydroxylation of Phenol

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (1): 30-33.

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Preparation of Chromium(Ⅲ) Phenanthroline and 8-Hydroxyquinoline Complexes/Y-Zeolite and Catalytic Hydroxylation of Phenol

Qi Xingyi¹, Wang Guojia¹, Ye Xingkai², Wu Yue²

1. Department of Chemistry, Jilin University, Changchun;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received:1995-05-20 Revised:1995-10-06 Published:1996-02-10 Online:1996-02-10

Abstract

Abstract: Chromium(Ⅲ) phenanthroline and 8-hydroxyqinoline complexes/Y-zeolite were prepared respectively.The formation of the metal complexes within the cages of Y-zeolite and their crystal structure were determined by elemental analysis,diffuse reflectance UV-Vis,SEM,BET,and XRD methods.The influence of experimental parameters upon phenol conversion and product selectivity were investigated as well.

Key words: chromium(Ⅲ), phenanthroline, hydroxyqinoline, zeolite, phenol hydroxylation

Qi Xingyi, Wang Guojia, Ye Xingkai, Wu Yue. Preparation of Chromium(Ⅲ) Phenanthroline and 8-Hydroxyquinoline Complexes/Y-Zeolite and Catalytic Hydroxylation of Phenol[J]. Chinese Journal of Applied Chemistry, 1996, 0(1): 30-33.

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Preparation of Chromium(Ⅲ) Phenanthroline and 8-Hydroxyquinoline Complexes/Y-Zeolite and Catalytic Hydroxylation of Phenol

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