Synthesis,Magnetism and Antibacterial Activity of Cu(Ⅱ)-Ln(Ⅲ)Binuclear Complexes

Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (5): 37-41.

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Synthesis,Magnetism and Antibacterial Activity of Cu(Ⅱ)-Ln(Ⅲ)Binuclear Complexes

Yan Cuiwei¹, Li Yantuan¹, Liao Daizheng², Jiang Zonghui², Wang Genglin²

1. Department of Chemistry, Qufu Normal University, Qufu 273165;
2. Department of Chemistry, Nankai University, Tianjin

Received:1994-12-12 Revised:1995-04-13 Published:1995-10-10 Online:1995-10-10

Abstract

Abstract: Six μ-oxamido heterobinuclear complexes,namely Cu(oxen)Ln(phen)₂(ClO₄)₃,(oxen:N,N'-bis(2-aminoethyl)oxamido dianion;phen:1,10-phenanthroline and Ln:Y,La,Ce,Nd,Gd,Yb)have been synthesized and characterized.The variable-temperature mag-netic susceptibility of Cu(oxen)Gd(phen)₂(ClO₄)₃· H₂O was measured over 4～300K andthe susceptibility data were least-squares fit to the susceptibility equation derived from thespin HamiItonian operator The exchange integral J was found to be2.3cm^-1,indicating that a very weak ferromagnetic spin-exchange interaction operates be-tween Cu(Ⅱ)and Gd(Ⅲ)ions.The antibacterial activity of the complexes were also exam-ined.

Key words: copper-rare earth binuclear complex, synthesis, magnetism, antibacterial activity

Yan Cuiwei, Li Yantuan, Liao Daizheng, Jiang Zonghui, Wang Genglin. Synthesis,Magnetism and Antibacterial Activity of Cu(Ⅱ)-Ln(Ⅲ)Binuclear Complexes[J]. Chinese Journal of Applied Chemistry, 1995, 0(5): 37-41.

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Synthesis,Magnetism and Antibacterial Activity of Cu(Ⅱ)-Ln(Ⅲ)Binuclear Complexes

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