Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrin Ⅱ.

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (5): 27-30.

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Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrin Ⅱ.

Zheng Guodong¹, Yan Yan¹, Gao Sai¹, Tong Shanling², Gao De³

1. Department of Chemistry and Department of Environment Science, Jilin University, Changchun 130023;
2. Changchun School of Light Industry, Changchun;
3. Department of Chemical Engineering, Hunan University, Changsha

Received:1993-10-27 Revised:1994-05-03 Published:1994-10-10 Online:1994-10-10

Abstract

Abstract: The CoTPP showed an effective catalytic activity in electrocarboxylation of benzyl chloride,acetophnone,benzophenone and naphthalene with CO₂.The products of electrocarboxvlation were characterized by UV,IR and GC-MS measurements,The mechanisms of the catalvtic electrocarboxylation have been discussed.

Key words: cobaltoporphyrin, benzyl chloride, acetophenone, benzophenone, naphthalene, catalvtic electrocarboxylation

Zheng Guodong, Yan Yan, Gao Sai, Tong Shanling, Gao De. Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrin Ⅱ.[J]. Chinese Journal of Applied Chemistry, 1994, 0(5): 27-30.

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Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrin Ⅱ.

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