Copolymerization of Propylene and α-Olefin by Titanium-Based Ziegler-Natta Catalysts

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (5): 5-9.

• Full Papers • Previous Articles Next Articles

Copolymerization of Propylene and α-Olefin by Titanium-Based Ziegler-Natta Catalysts

Chen Hui, Wang Jianguo, Zhang Xuequan, Pang Deren, Huang Baotong

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received:1994-03-24 Revised:1994-06-17 Published:1994-10-10 Online:1994-10-10

Abstract

Abstract: The synthesis of propylene/decene-1 copolymer by TiCl₄/MgCl₂ catalyst and propylene/octene-1 copolymer by δ-TiCl₃ catalyst has been investigated.The effects of [Al]/[Ti] ratio,temperature,and concentration of monomers on the copolymerization have been studied.The higher catalysis efficiency,the larger particle size and more porous surface of polymer were observed in copolymerization in comparison with that in homopolymerization of propylene.The results are discussed in terms of the unsteady diffusion kinetics of the heterogeneous Ziegler-Natta polymerization.

Key words: propylene, octene, decene, copolymerization, Ziegler-Natta catalyst

Chen Hui, Wang Jianguo, Zhang Xuequan, Pang Deren, Huang Baotong. Copolymerization of Propylene and α-Olefin by Titanium-Based Ziegler-Natta Catalysts[J]. Chinese Journal of Applied Chemistry, 1994, 0(5): 5-9.

[1]	Jia-Cheng ZHOU, Dong-Dong WANG, Yun-Bao GAO, Jing JIN, Wei JIANG. Rheological Properties and Bonding Properties of Modified Poly（Propylene Carbonate） Pressure-sensitive Adhesive [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 871-878.
[2]	Di XU, Li DAI, Wen-Zhi YAO, Guang-Rui YANG, Hai-Rong WANG, Peng-Fei SONG, Yan-Song ZHU. Research Progress of Olefin Polymerization Catalysts [J]. Chinese Journal of Applied Chemistry, 2022, 39(3): 355-373.
[3]	Chen-Chen ZHANG, Yu-Han LIU, Wen-Jie ZHAO, Bai-Jun LIU, Zhao-Yan SUN, Wan-Li LIU, Yan-Miao WANG, Wei HU. Preparation of Oxidized Organosolv Lignin⁃based Hydrophilic Sizing Agent and Its Application in Polypropylene [J]. Chinese Journal of Applied Chemistry, 2022, 39(12): 1854-1861.
[4]	Jiu-Geng CHENG, Zhao-Hui SU. Quantitative Analysis of Phase Composition of Poly (1-butene) /Polypropylene Blends by Atomic Force Microscopy-Infrared [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 266-271.
[5]	QIU Jian, JIANG Zhiwei, XING Haiping, LI Minggang, LIU Jie, TANG Tao. Preparation and Electromagnetic Shielding Properties of Polypropylene/Carbon Nanotubes Composites with Segregated Structure [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 904-911.
[6]	QIU Jian, JIANG Zhiwei, XING Haiping, LI Minggang, LIU Jie, TANG Tao. Preparation and Electromagnetic Shielding Properties of Polypropylene/Carbon Nanotubes Composites with Segregated Structure [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 0-0.
[7]	YANG Zhengjun, LIU Bo, HUANG Pai, NIE Heran, ZHOU Guangyuan, ZHANG Jianfu. Effect of Pore Structures of Porous Polymer Microspheres on Catalytic Propylene Polymerization [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 746-755.
[8]	QI Yanxin, HUANG Yubin, JIN Ningyi. Preparation and Release Behavior of Progesterone Nano Micelles in Vitro [J]. Chinese Journal of Applied Chemistry, 2020, 37(11): 1340-1342.
[9]	ZHANG Yudong,GAO Yun,ZHANG Lei,LI Qinghua. Effect of Poly(4-ethylphenol) Antioxidant on Non-isothermal Crystallization Behavior of Polypropylene [J]. Chinese Journal of Applied Chemistry, 2019, 36(5): 539-547.
[10]	GUO Hongchen, QIN Yusheng, WANG Xianhong, WANG Fosong. Copolymerization of Carbon Dioxide and Propylene Oxide under Aluminum Porphyrin Catalyst [J]. Chinese Journal of Applied Chemistry, 2019, 36(10): 1118-1127.
[11]	LIU Yide, CHEN Jialian, LI Hongzhou, YANG Songwei, LUO Fubin, CHEN Qinghua. Flame Retardant Properties of Synergistic Flame Retardant Polypropylene [J]. Chinese Journal of Applied Chemistry, 2019, 36(10): 1165-1171.
[12]	Li DONG, Xiangdong LIU, Zhengrong XIONG, Yuming YANG. Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride) [J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 776-780.
[13]	ZHANG Deguang, LI Yanguo, CUI Lei, LI Yuesheng. Controlled Preparation of Crosslinked Isotactic Polypropylene via Diels-Alder Reaction [J]. Chinese Journal of Applied Chemistry, 2018, 35(2): 174-180.
[14]	BIAN Junjia, XU Mingzhi, HAN Changyu, WU Dandan, HAN Lijing, DONG Lisong. Poly(propylene carbonate)/Starch Blends Prepared by Water-assisted Processing [J]. Chinese Journal of Applied Chemistry, 2017, 34(8): 885-890.
[15]	LICHEN Haoyang, CUI Xihua, JIANG Wei, CHEN Bin. Preparation and Properties of the Poly(propylene carbonate)/Straw Flour Composites Compatibilized with Chlorided Poly(propylene carbonate) [J]. Chinese Journal of Applied Chemistry, 2017, 34(7): 744-748.

Copolymerization of Propylene and α-Olefin by Titanium-Based Ziegler-Natta Catalysts

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments