Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (1): 21-24.

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OPTICAL PROPERTIES OF 2,2-BIS(4-METHACRYLOYLOXYPHENYL)PROPANESTYRENE COPOLYMER

Yang Bai, Yang Fan, Lin Dehou, Li Yingjun, Shen Jiacong   

  1. Department of Chemistry, Jilin Uuiversity, 130023 Changchun
  • Received:1991-07-12 Revised:1992-10-05 Published:1993-02-10 Online:1993-02-10

Abstract: Transparent resins were synthesized from title methacryloyloxyphenyl propane (abbr. bisvinyl-A) homopolymer and its copolymer with styrene. The homopolymer of bisvinyl-A is light(d4201.19),has high surface hardness (pencil hardness 6H),heat resistance (T8 155℃) and superior optical properties (nD201.578,transparency 90~91%). But it is too fragile. The property of bisvinyl-A and styrene copolyrner was dependent on the content of bisvinyl-A. Copolymer containing 70% bisvinyl-A has the most absorption of UV-light (with complete absorbtion at<370nm). The copolymer with 5%~10% bisvinyl-A shows an excellent water absorbing resistance,acid and alkali resistance,impact resistance and high refractive index (nD 1.588).

Key words: bismethacryloyloxyphenyl propane, styrene, copolymer, optical resin, synthesis, property