TERNARY COMPLEXES OF Ce(Ⅳ)AND Th(Ⅳ)WITH 1,10-PHENANTHROLINE-N-OXIDE AND ACETYLACETONE

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (2): 72-74.

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TERNARY COMPLEXES OF Ce(Ⅳ)AND Th(Ⅳ)WITH 1,10-PHENANTHROLINE-N-OXIDE AND ACETYLACETONE

Liu Weisheng, Tan Minyu, Wang Liufang

Department of Chemistry, Lanzhou University, Lanzhou 730000

Received:1990-04-28 Revised:1990-07-23 Published:1991-04-10 Online:1991-04-10

Abstract

Abstract: Three ternary coordination compounds of Ce (Ⅳ) and Th (Ⅳ) with 1,10-phenanthroline-N-oxide (PhenNO) and acetylacetone (Hacac), were prepared.which have compositions of[Ce(PhenNO)₂ (acac)₂]X₂ (X = NO₃^-, ClO₄^-) and [Th (PbenNO)·(acac)₄], respectively.Thecompounds were characterized by elemental analysis, molar conductance, TG-DSC, IR spec-tra and ¹H NMR measurements.

Key words: Ce(Ⅳ), Th(Ⅳ), phenanthroline-N-oxide, acetylacetone, complex

Liu Weisheng, Tan Minyu, Wang Liufang. TERNARY COMPLEXES OF Ce(Ⅳ)AND Th(Ⅳ)WITH 1,10-PHENANTHROLINE-N-OXIDE AND ACETYLACETONE[J]. Chinese Journal of Applied Chemistry, 1991, 0(2): 72-74.

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TERNARY COMPLEXES OF Ce(Ⅳ)AND Th(Ⅳ)WITH 1,10-PHENANTHROLINE-N-OXIDE AND ACETYLACETONE

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