BIS(1-CARBONYLAMINO-3-AROYLTHIOUREA):SYNTHESIS AND CYCLIZATION

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (2): 28-32.

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BIS(1-CARBONYLAMINO-3-AROYLTHIOUREA):SYNTHESIS AND CYCLIZATION

Feng Xiaoming¹, Chen Rong¹, Liu Xiaochen¹, Zhang Ziyi²

1. Department of Chemistry, Southwest Teacher's University, Chongqing 630715;
2. Department of Chemistry, Lanzhou University, Lanzhou

Received:1989-12-25 Revised:1990-08-07 Published:1991-04-10 Online:1991-04-10

Abstract

Abstract: A series of new bis(1-carbonylamino-3-aroylthiourea)1 were synthesized by condensationof aroylisothiocyanate with oxalylhydrazine in anhydrous acetonitrile.Some of bis(3-yl-4-aroyl-1, 2,4 -triazoline- 5-thione) 2 were obtamed in good yields (32.3～91.7%) by cycliztaionof compounds 1 in alkaline solution.The structures of all the synthesized compounds werecharacterized by elemental analysis, IR, ¹H NMR and MS.Preliminary plant physiological tests indicated that some of compounds 1 possess strongpromoting activity on the growth of plumule of corn at concentration of ppm.

Key words: aroylthniosemicarbazide, triazo inothione, biological activity, plant growth regulator

Feng Xiaoming, Chen Rong, Liu Xiaochen, Zhang Ziyi. BIS(1-CARBONYLAMINO-3-AROYLTHIOUREA):SYNTHESIS AND CYCLIZATION[J]. Chinese Journal of Applied Chemistry, 1991, 0(2): 28-32.

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BIS(1-CARBONYLAMINO-3-AROYLTHIOUREA):SYNTHESIS AND CYCLIZATION

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