SYNTHESIS AND PROPERTIES OF PTHF-MMA BLOCK COPOLYMER

Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (4): 42-46.

• Full Papers • Previous Articles Next Articles

SYNTHESIS AND PROPERTIES OF PTHF-MMA BLOCK COPOLYMER

She Wanneng, Qu Xiuning

Hubei Institute of Chemistry, Wuhan 430074

Received:1989-07-04 Revised:1990-02-12 Published:1990-08-10 Online:1990-08-10

Abstract

Abstract: PTHF-MMA block copolymer was synthesized by using azo-containning polytetrahydro-furan (AZO-PTHF) as macro-initiator in the radical polymerization of methyl methacrylate(MMA).The copolymer has been characterized by GPC, IR, H-NMR and thermal mechanicalanalyses. The physical property indicated that the block copolymer possesses higher creaseresistance and toughness than PMMA without obvious loss of transparence and tensilestrength.

Key words: tetrahydrofuran, methyl methacrlate, block copolymer, polymer initiator, polymerisation

She Wanneng, Qu Xiuning. SYNTHESIS AND PROPERTIES OF PTHF-MMA BLOCK COPOLYMER[J]. Chinese Journal of Applied Chemistry, 1990, 0(4): 42-46.

[1]	HU Xiao-Hua, XIONG Shi-Sheng. Advanced Lithography: Directed Self-Assembly [J]. Chinese Journal of Applied Chemistry, 2021, 38(9): 1029-1078.
[2]	TIAN Xin, LAI Han-Wen, LIU Ya-Dong, JI Sheng-Xiang. Analysis of Defects in Block Copolymer Films by a Convolution Algorithm [J]. Chinese Journal of Applied Chemistry, 2021, 38(9): 1199-1208.
[3]	Long-Fei LUO, Yu-Jie LI, Zhi-Hao SHEN, Shi-Jun ZHENG, Xing-He FAN. Progress in Self⁃assembly and Photo⁃responsiveness of Thin Films of Azobenzene⁃Based Liquid Crystalline Block Copolymers [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1238-1254.
[4]	Ai-Hua CHEN, Cheng-Yun ZHANG, Zi-Chao DENG, Ya-Lan SUN. Structure Control of Liquid Crystalline Block Copolymers in Liquid⁃Phase Self⁃assembly [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1255-1267.
[5]	Zhao-Yong ZHANG, Qian LI, Da-Lin WANG, Jiang-Lin FANG, Dong-Zhong CHEN. Controlled Synthesis and Photophysical Properties of Liquid Crystalline Diblock Copolymers with Side⁃Chain Discotic Triphylene and Calamitic Azobenzene Mesogens [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1340-1352.
[6]	Zhao-Yong ZHANG, Qian LI, Da-Lin WANG, Jiang-Lin FANG, Dong-Zhong CHEN. Controlled Synthesis and Photophysical Properties of Liquid Crystalline Diblock Copolymers with Side⁃Chain Discotic Triphylene and Calamitic Azobenzene Mesogens [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 0-0.
[7]	ZHANG Yanhui, WANG Lin, MUSLIM Arzugul, LAN Haidie. Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 764-771.
[8]	LI Maosheng, CHEN Jinlong, TAO Youhua. Regio- and Stereoselective Ring-Opening Metathesis Polymerization of Amino Acid Functionalized Cyclooctenes [J]. Chinese Journal of Applied Chemistry, 2020, 37(3): 280-292.
[9]	LIU Ning,LIU Shuilin,WU Suyun,TANG Xinde,WU Zhi,LI Aiyang. CTAB-P123-Assisted Synthesis of Orderly Mesoporous KF/Al-Ce-SBA-15 Solid Base and Its Catalytic Application [J]. Chinese Journal of Applied Chemistry, 2019, 36(11): 1294-1300.
[10]	ZHANG Xiaosa, JI Shengxiang. Synthesis and Directed Self-assembly of Cylinder-Forming Poly(styrene-b-lactide) Block Copolymers [J]. Chinese Journal of Applied Chemistry, 2018, 35(12): 1420-1426.
[11]	XU Yuzhong,TONG Yongfen,TAN Licheng,CHEN Yiwang. Block Copolymer Electrolytes for Lithium Batteries [J]. Chinese Journal of Applied Chemistry, 2017, 34(3): 245-261.
[12]	LI Liangui, FU Zhipeng, LI Mingchao, ZHANG Qiang, WANG Rui, WANG Guoqiang, JIANG Min. Synthesis and Characterization of Polyethylene Terephthalate-b-poly(ethylene 2,5-furandicarboxylate) Block Polyester [J]. Chinese Journal of Applied Chemistry, 2017, 34(1): 54-59.
[13]	ZHANG Fan, WANG Lulu, WANG Jilin, FENG Ruijiang, ZHANG Yang. Gemini-type Cationic Molecules-Styrene Block Polymer Anion Conducting Membrane Prepared by in-situ Polymerization [J]. Chinese Journal of Applied Chemistry, 2016, 33(6): 693-700.
[14]	ZHOU Yun,LIU Hui,HE Yan,LI Aitao,TAO Liming. Copper Acetate Catalyzed Oxidative Coupling of Disulfides with Tetrahydrofuran [J]. Chinese Journal of Applied Chemistry, 2015, 32(11): 1253-1258.
[15]	ZHENG Chao, HUANG Haiying, HE Tianbai. Research Progress in Gradient Copolymers [J]. Chinese Journal of Applied Chemistry, 2014, 31(11): 1237-1247.

SYNTHESIS AND PROPERTIES OF PTHF-MMA BLOCK COPOLYMER

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments