Chinese Journal of Applied Chemistry ›› 1988, Vol. 0 ›› Issue (6): 86-90.

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SYNTHESIS AND MOLECULAR STRUCTURE OF[Na·6THF] [Cp3Nd(μ-H)NdCp3]·2THF

Sun Yimin, Jin Songchun, Shen Qi, Lin Yonghua   

  1. Changchun Institute of Applied Chemistry, Acodemia Sinica
  • Received:1987-05-11 Revised:1988-06-17 Published:1988-12-10 Online:1988-12-10

Abstract: The title complex crystallizes in space group P-1 with a=16.834(6)Å, b=16.988(7)Å, c=10.696(4)Å,α=91.99°(3), β=96.68°(3),γ=91.42°(3)and Z=2. The crystal is air and X-ray sensitive. Diffraction data had to be collected at low te-mperature (about -110℃) on four circle diffractometer. Least squares refinement led to a final R=0.074. The structure analysis proved that the complex is polymorphic at different temperature.

Key words: Neodymium complex, Crystal structure