Synthesis and Antibacterial Activity of Its Metal Complexes of Salicyhydrazide and 3,5-Diiodo-salicylalidehyde Schiff Base

doi:10.3724/SP.J.1095.2011.00618

Chinese Journal of Applied Chemistry ›› 2011, Vol. 28 ›› Issue (10): 1167-1172.DOI: 10.3724/SP.J.1095.2011.00618

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Synthesis and Antibacterial Activity of Its Metal Complexes of Salicyhydrazide and 3,5-Diiodo-salicylalidehyde Schiff Base

GAO Min, YANG Tianlin^*, MA Zhiqiang, ZHANG Jingjing

(Key Laboratory of Energy Sources and Chemical Engineering,College of Chemistry and
Chemical Engineering,Ningxia University,Yinchuan 750021)

Received:2010-10-18 Revised:2010-12-13 Published:2011-10-10 Online:2011-10-10
Contact: Min GAO

Abstract

Abstract:

Four coordination compounds of transition metal with 3,5-diiodo-salicylalidehyde and salicyhydrazide Schiff base have been synthesized in pyridine and DMF solvents. These ligand and complexes were characterized by UV and IR spectra, TG-DTG, elemental analysis, and molar conductance analysis. The interactions of the complexes with DNA were investigated by UV and fluorescence spectroscopies, which show that the binding mode of the complexes with ct-DNA was intercalation. In addition, the biological activity test reveals that the complexes have potentially catalytic and antibacterial activity towards superoxide anion radical O-·2 and Micrococcus luteus.

Key words: iodine-containing Schiff base, transition metal complexes, spectrum character, antibacterial activity

CLC Number:

O611.6

GAO Min, YANG Tianlin*, MA Zhiqiang, ZHANG Jingjing. Synthesis and Antibacterial Activity of Its Metal Complexes of Salicyhydrazide and 3,5-Diiodo-salicylalidehyde Schiff Base[J]. Chinese Journal of Applied Chemistry, 2011, 28(10): 1167-1172.

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Synthesis and Antibacterial Activity of Its Metal Complexes of Salicyhydrazide and 3,5-Diiodo-salicylalidehyde Schiff Base

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