Synthesis of Lignin-tetraethylenepentamine Palladium Complex and Its Catalytic Properties for Suzuki Reaction

doi:10.3724/SP.J.1095.2010.90577

Chinese Journal of Applied Chemistry ›› 2010, Vol. 27 ›› Issue (07): 787-791.DOI: 10.3724/SP.J.1095.2010.90577

• Full Papers • Previous Articles Next Articles

Synthesis of Lignin-tetraethylenepentamine Palladium Complex and Its Catalytic Properties for Suzuki Reaction

XUE Man^1,2, ZHANG Shi-Zhen³, WU Yu-Feng¹, LIU Jian¹, CUI Yuan-Chen^1*

(1.Key Laboratory for Special Functional Materials,Henan University,Kaifeng 475004;
2.Kaifeng Institute of Education,Kaifeng;
3.Shangqiu Technician School,Shangqiu)

Received:2009-08-31 Revised:2009-11-10 Published:2010-07-10 Online:2010-07-10

Abstract

Abstract:

Lignintetraethylenepentamine was synthesized from Lignin and tetraethylenepentamine(TEPA) with formaldehyde as a crosslinking agent by Mannich reaction. The prepared complex was used as a matrix to support palladium chloride. Lignin-TEPA-Pd complex was characterized by XPS, TG and DTA, which was an efficient catalyst for the Suzuki reaction of iodobenzene with sodium tetraphenylboron. The yield of the product was up to 90.2% when the reaction was carried out at 80 ℃ in air for 8 h with V(DMF)∶V(H₂O)=2∶1 mixture as the solvent and NaHCO₃as the base. The catalyst could be separated easily, but the yield of product decreased to 31.3% after 4 times reusage.

Key words: lignin, palladium, supported catalyst, Suzuki reaction

CLC Number:

O643.3

XUE Man1,2, ZHANG Shi-Zhen3, WU Yu-Feng1, LIU Jian1, CUI Yuan-Chen1*. Synthesis of Lignin-tetraethylenepentamine Palladium Complex and Its Catalytic Properties for Suzuki Reaction[J]. Chinese Journal of Applied Chemistry, 2010, 27(07): 787-791.

[1]	Xing-Quan XIONG, Hui ZHANG, Li-Zhu GAO. Progress in Chemical Modification and Application of Lignin [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 806-819.
[2]	Chen-Chen ZHANG, Yu-Han LIU, Wen-Jie ZHAO, Bai-Jun LIU, Zhao-Yan SUN, Wan-Li LIU, Yan-Miao WANG, Wei HU. Preparation of Oxidized Organosolv Lignin⁃based Hydrophilic Sizing Agent and Its Application in Polypropylene [J]. Chinese Journal of Applied Chemistry, 2022, 39(12): 1854-1861.
[3]	TIAN Shu-Yang, LYU Rong-Wen. Solvent-Free Oxidation of Benzyl Alcohol to Benzaldehyde Catalyzed by Magnesium Oxide Supported Bimetallic Gold-Palladium [J]. Chinese Journal of Applied Chemistry, 2021, 38(7): 789-799.
[4]	WANG Wei, LI Juan, BAI Ru, HAN Zhen, FENG Xuewei, SUN Yue. Preparation of Au/Polyacrylamide@Graphene Oxide/Nano-palladium Electrode via Metal-Free Visible-Light-Induced Atom Transfer Radical Polymerization and Its Detection of Ethanol [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 595-603.
[5]	Lihui ZENG,Yuefeng LI,Haoxiang YAN,Yongkang ZENG,Zhixiang ZHANG,Zhongwen LIU,Zhaotie LIU. Catalytic Hydrogenation Performance of p-tert-Butyl-α-Methyl Cinnamaldehydeover Precious Metal Catalysts [J]. Chinese Journal of Applied Chemistry, 2020, 37(3): 322-331.
[6]	LIU Minghui, LIU Yingcen, Lü Rongwen. Preparation of Carbon-Supported Highly Dispersed Palladium Nanoparticles and Their Performance for Suzuki Reaction [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 61-68.
[7]	XIE Yaqiao, ZHAO Jiaxin, LI Jielan, XU Zidi, QU Jiangying, TIAN Yunqi, GAO Feng. Synthesis of Sodium Chloride Induced Lignin-Based Porous Carbon and Their Supercapacitor Performances [J]. Chinese Journal of Applied Chemistry, 2019, 36(4): 482-488.
[8]	SONG Feiyue, XUE Yongbo, GAO Xin, BAI Ling, LI Jing, DENG Yun, XIE Lijuan, RUAN Wenquan. Palladium(Ⅱ) Extraction Using Different Ionic Liquid-Based Aqueous Biphasic Systems [J]. Chinese Journal of Applied Chemistry, 2019, 36(3): 335-340.
[9]	CHEN Ziting, LIANG Ying. Preparation and Application of Pd Nanomaterials Grown in situ on Non-Through-Hole Porous Alumina [J]. Chinese Journal of Applied Chemistry, 2017, 34(6): 705-711.
[10]	SUN Huiliang, YANG Yike, LI Xiao, WANG Hua, ZHAN Hongmei, CHENG Yanxiang. Polymerization of AB-Type Fluorene Monomer Using Pd(Ⅱ) Complexes Based on Dithieno [2,3-b:2',3'-d]thiophene as Initiators [J]. Chinese Journal of Applied Chemistry, 2017, 34(2): 172-179.
[11]	SUN Huiliang, YANG Yike, LI Xiao, WANG Hua, ZHAN Hongmei, CHENG Yanxiang. Polymerization of AB-Type Fluorene Monomer Using Pd(Ⅱ) Complexes Based on Dithieno [2,3-b:2',3'-d]thiophene as Initiators [J]. Chinese Journal of Applied Chemistry, 2017, 34(2): 0-0.
[12]	ZENG He, SHI Yan, LI Heming, WANG Chen, WANG Haiyan. Effect of Aluminium Oxide and Phosphorus Modification on Structure and Hydrodesulfurization Performance of Unsupported Catalysts [J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 951-959.
[13]	LU Huixia, LI peiying, ZHENG Jianchao, XU Xiujuan, LIU Pu. Preparation, Characterization and Catalytic Performance of Polyamidoamine-2-Pyridine Carbaldehyde Schiff Base Dendrimer Palladium Complexes [J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 161-168.
[14]	LI Haidong,YAO Qichao,FAN Jiangli,DU Jianjun,PENG Xiaojun. Research Advance on the Fluorescent Probe of Palladium Ions [J]. Chinese Journal of Applied Chemistry, 2016, 33(10): 1099-1114.
[15]	YAO Qingxin, XIE Jianjun, LIU Junxia, TANG Liping, LIU Yuan. Effect of Ionic Strength on the Adsorption of Pb²⁺ and Cu²⁺ onto Bentonite/Sodium Lignosulfonate Graft-Polymerized with Acrylamide and Maleic Anhydride [J]. Chinese Journal of Applied Chemistry, 2015, 32(8): 940-947.

Synthesis of Lignin-tetraethylenepentamine Palladium Complex and Its Catalytic Properties for Suzuki Reaction

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments