Preparation and Application of Pd Nanomaterials Grown in situ on Non-Through-Hole Porous Alumina

doi:10.11944/j.issn.1000-0518.2017.06.160329

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (6): 705-711.DOI: 10.11944/j.issn.1000-0518.2017.06.160329

• Full Papers • Previous Articles Next Articles

Preparation and Application of Pd Nanomaterials Grown in situ on Non-Through-Hole Porous Alumina

CHEN Ziting,LIANG Ying()

School of Chemistry and Chemical Engineering,Guangdong Pharmaceutical University,Guangzhou 510006,China

Received:2016-08-18 Accepted:2017-01-16 Published:2017-05-31 Online:2017-05-31
Contact: LIANG Ying
Supported by:
Supported by the National Natural Science Foundation of China(No.21201043)

Abstract

Abstract:

Using non-through-hole anodic aluminum oxide(AAO) as templates, with Al substrate as support body, Pd nanomaterials were prepared in situ in the channels of AAO with Al substrate as reducing agent. The removal of barrier layer and acid corrosion post-treatment of synthesized Pd/AAO were studied. The Pd morphologies under different situations were observed by scanning electronic microscopy. A plausible mechanism of Pd formation was proposed. The catalytic activity for Suzuki reaction of 4-bromobenzene carboxylic acid and phenylboronic acid was investigated with Pd/AAO as heterogeneous catalysts. It is found that Pd/AAO catalysts exhibit excellent catalytic activity, and the yield is up to 99.8% with 0.06% molar fraction of Pd. The catalysts with sheet structure are easily separated for recovery by just taking out of the solution and can be reused in the next time. This research gives a practical method for the design of heterogeneous catalysts in organic reactions.

Key words: porous alumina, barrier layer, Pd, Suzuki reaction

CHEN Ziting, LIANG Ying. Preparation and Application of Pd Nanomaterials Grown in situ on Non-Through-Hole Porous Alumina[J]. Chinese Journal of Applied Chemistry, 2017, 34(6): 705-711.

References

[1]	Masuda H,Fukud K. Ordered Metal Nanohole Arrays Made by a Two-step Replication of Honeycomb Structures of Anodic Alumina[J]. Science,1995,268(5216):1466-1468.
[2]	Yang Y,Gao Q M. Influence of Sulfosalicylic Acid in the Electrolyte on the Optical Properties of Porous Anodic Alumina Membranes[J]. Phys Lett,2004,333(3/4):328-333.
[3]	Liu L C,Yoo S H. Electrochemical Growth of Silver Nanobelts in Cylindrical Aluminum Nanochannels[J]. Cryst Growth Des,2011,11(9):3731-3734.
[4]	Wei W,Miao T,Aziz A,et al. Three-Dimensional Ni/TiO2 Nanowire Network for High Areal Capacity Lithium Ion Microbattery Applications[J]. Nano Lett,2012,12(2):655-660.
[5]	Wu G S,Zhang L,Cheng B C,et al. Synthesis of Eu2O3 Nanotubes Arrays Through a Facile Sol-Gel Template Approach[J]. J Am Chem Soc,2004,126(19):5976-5977.
[6]	Laksbmi B B,Dorhout P K,Martin C R. Sol-Gel Template Synthesis of Semiconductor Nanostructures[J]. Chem Mater,1997,9(3):857-861.
[7]	Ergen O,Ruebusch D J,Fang H,et al. Shape-Controlled Synthesis of Single-Crystalline Nanopillar Arrays by Template-assisted Vapor-Liquid-Solid Process[J]. J Am Chem Soc,2010,132(132):13972-13974.
[8]	Yang F,Li Y F,Liu T,et al. Plasma Synthesis of Pd Nanoparticles Decorated-Carbon Nanotubes and Its Application in Suzuki Reaction[J]. Chem Eng J,2013,226((24):52-58.
[9]	Tan L K,Chong M A S,Gao H. Free-Standing Porous Anodic Alumina Templates for Atomic Layer Deposition of Highly Ordered TiO2 Nanotube Arrays on Various Substrates[J]. J Phys Chem C,2008,112(1):69-73.
[10]	Cheng D F,Yagihashi M,Hozumi A. Lamination of Alumina Membranes to Polymer Surfaces:Thick, Hard, Transparent, Crack-free Alumina Films on Polymers with Excellent Adhesion[J]. Appl Mater Interfaces,2011,3(7):2224-2227.
[11]	Liang Y,Wang X D,Liu N,et al. A Facile Method to Synthesise Unique Si Nanostructure Materials by Non-Through-Hole Anodic Alumina Templating[J]. Surf Interface Anal,2013,45(6):1067-1070.
[12]	Cui J,Zhang M,Zhan Y. Synthesis and Characterization Amino-salicylaldimine Palladium-based Complexes and Their Suzuki Coupling Reaction Study[J]. Inorg Chem Commun,2009,12(9):839-841.
[13]	Liu F S,Huang Y T,Lu C,et al. Efficient Salicylaldimine Ligands for a Palladium-catalyzed Suzuki-Miyaura Cross-Coupling Reactions[J]. Appl Organomet Chem,2012,26(8):425-429.
[14]	Brayton D F,Larkin T M,Vicic D A. Synthesis of a Bi(phenoxyketimine) Palladium(Ⅱ) Complex and Its Activity in the Suzuki-Miyaura Reaction[J]. J Organomet Chem,2009,694(18):3008-3011.
[15]	Siamaki A R,Lin Y,Woodberry K,et al. Palladium Nanoparticles Supported on Carbon Nanotubes from Solventless Preparations:Versatile Catalysts for Ligand-free Suzuki Cross Coupling Reactions[J]. J Mater Chem A,2013,1(41):12909-12918.
[16]	Navidi M,Rezadi N,Movassagh B. Palladium(Ⅱ) Schiff Base Complex Supported on Multi-walled Carbon Nanotubes:A Heterogeneous and Reusable Catalyst in the Suzukie Miyaura and Copper-free Sonogashira Hagihara Reactions[J]. J Organometal Chem,2013,743(3):63-69.
[17]	FENG Cuilan,LIU Jianping,GUI Jianzhou,et al. Application of Magnetic Nanoparticles Supported Pd Catalysts in C—C Bond Formation Reactions[J]. Chinese J Appl Chem,2015,32(1):19-26(in Chinese). 冯翠兰,刘建平,桂建舟,等. 磁性纳米粒子负载钯催化剂在C—C键偶联反应中的应用[J]. 应用化学,2015,32(1):19-26.
[18]	Karakhanov E,Maximova,Kardasheva Y,et al. Pd Nanoparticles in Dendrimers Immobilized on Silica-Polyamine Composites as Catalysts for Selective Hydrogenation[J]. ACS Appl Mater Interfaces,2014,6(11):8807-8816.
[19]	Li R,Zhang P,Huang Y M,et al. Facile Approach to Prepare Pd Nanoarray Catalysts within Porous Alumina Templates on Macroscopic Scales[J]. ACS Appl Mater Interfaces,2013,5(23):12695-12700.
[20]	Chee C C,Houy Q,Wamg H,et al. Facile Deposition of Pd Nanoparticles on Carbon Nanotube Microparticles and Their Catalytic Activity for Suzuki Coupling Reactions[J]. J Phys Chem C,2008,112(22):8172-8176.
[21]	XU Guorong,REN Fenglian,SI Shihui,et al. Study on Removal of the Barrier Between Al Substrate and Porous Anodic Alumina by Electrochemical Approach[J]. Acta Phys Chim Sin,2006,22(3):341-344(in Chinese). 徐国荣,任凤莲,司士辉,等. 多孔阳极氧化铝模板电化学法去阻挡层的研究[J]. 物理化学学报,2006,22(3):341-344.
[22]	Tang K J,Yu J H,Zhao Y Y,et al. Fabrication of Super-hydrophobic and Super-oleophilic Boehmite Membranes from Anodic Oxide Film via a Two-phase Thermal Approach[J]. J Mater Chem,2006,16(18):1741-1745.
[23]	Naghipour A,Fakhri A. Heterogeneous Fe3O4@chitosan-Schiff Base Pd Nanocatalyst:Fabrication Characterization and Application as Highly Efficient and Magnetically Recoverable Catalyst for Suzuki-Miyaura and Heck-Mizoroki C—C Coupling Reactions[J]. Catal Commun,2016,73:39-45.
[24]	Veisi H,Khazaei A,Safaei M,et al. Synthesis of Biguanide-functionalized Single-walled Carbon Nanotubes(SWCNTs) Hybrid Materials to Immobilized Palladium as New Recyclable Heterogeneous Nanocatalyst for Suzuki-Miyaura Coupling Reaction[J]. J Mol Catal A:Chem,2014,382(4):106-113.

Preparation and Application of Pd Nanomaterials Grown in situ on Non-Through-Hole Porous Alumina

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Hui-Hui LI, Kai-Sheng YAO, Ya-Nan ZHAO, Li-Na FAN, Yu-Lin TIAN, Wei-Wei LU. Ionic Liquid-Modulated Synthesis of Pt-Pd Bimetallic Nanomaterials and Their Catalytic Performance for Ammonia Borane Hydrolysis to Generate Hydrogen [J]. Chinese Journal of Applied Chemistry, 2023, 40(4): 597-609.
[2]	Ya-Li FENG, Lie-Jin ZHOU, Zhong-Yan CAO. Transition Metal⁃Catalyzed Cross⁃Coupling Reactions of Alkenyl Fluorides： Advances and Perspectives [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 749-759.
[3]	SUN Zhicong, MENG Qinglei, MA Rongpeng, GE Junjie, LIU Changpeng, XING Wei. Promotion Effect of Functionalized Carbon Nitride on Pd-Based Catalyst for Hydrogen Generation from Formic Acid [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 1187-1194.
[4]	LIU Minghui, LIU Yingcen, Lü Rongwen. Preparation of Carbon-Supported Highly Dispersed Palladium Nanoparticles and Their Performance for Suzuki Reaction [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 61-68.
[5]	YU Yancun,WANG Xian,GE Junjie,LIU Changpeng,XING Wei. Polypyrrole Modified Carbon-Supported Pd Catalyst for Formic Acid Electrooxidation [J]. Chinese Journal of Applied Chemistry, 2019, 36(11): 1317-1322.
[6]	ZHU Yiming, ZHANG Hao, ZHANG Jun, MI Gang, SONG Bangcai, DU Xigang. Preparation and Catalytic Performance Evaluation of Multi-metal Catalysts for Conversion of Tetrachloromethaneto Trichloromethane by Liquid Phase Hydrogenation [J]. Chinese Journal of Applied Chemistry, 2017, 34(2): 242-244.
[7]	MENG Shuaiqi, ZHOU Jinsong, WANG Xiaolong, GAO Xiang, LUO Zhongyang. Adsorption and Removal of Hg on Pd Doped CeO₂ Surfaces [J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 960-967.
[8]	HE Xiaoyan, LIU Zhirong, FAN Fuhong, QIANG Shenglu, CHENG Li. Preparation of Palladium/Polyelectrolyte Hollow Nanospheres and Their Catalytic Activity in 4-Nitrophenol Reduction [J]. Chinese Journal of Applied Chemistry, 2015, 32(3): 310-316.
[9]	ZHOU Yu, HE Yuan, ZHOU Wenjun. Adsorption of Palladium by Pectin and Its Application in Organic Synthesis [J]. Chinese Journal of Applied Chemistry, 2015, 32(12): 1402-1409.
[10]	FENG Cuilan, LIU Jianping, GUI Jianzhou, LIU Lantao. Application of Magnetic Nanoparticles Supported Pd Catalysts in C—C Bond Formation Reactions [J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 19-26.
[11]	FENG Xiao juan*, ZHANG Weina, AN Honggang. Electrocatalytic Performance of Pd-modified Polyaniline/Polysulfone Composite Film Electrodes for Formic Acid Oxidation [J]. Chinese Journal of Applied Chemistry, 2014, 31(03): 336-341.
[12]	PAN Xiqiang1,2, YANG Xiangguang1*. Effect of Different Zirconia Phase on Methane Combustion Activity and Stability over Pd/ZrO₂ [J]. Chinese Journal of Applied Chemistry, 2014, 31(02): 177-181.
[13]	WANG Xiuyan1, ZHAO Xueping2, MA Shuhua2*. Preparation of Silicotungstic Acid Modified Carbon Supported Pd Catalyst by Impregnation Method and Its Electrocatalytic Performance for Formic Acid Oxidation [J]. Chinese Journal of Applied Chemistry, 2013, 30(12): 1470-1475.
[14]	QYANG Qiuming1, WU Bing1,2, GAO Ying1,2*. Effect of Surfactants on Microwave-assisted Reduction Prepared Carbon-supported PdAu Catalysts and Electrooxidation of Formic Acid [J]. Chinese Journal of Applied Chemistry, 2012, 29(10): 1189-1193.
[15]	FAN Jiangli*, LU Jing, LI Honglin, LIU Xiaojian, ZHU Hao, PENG Xiaojun. An Improved Fluorescence-enhanced Pd²⁺ Probe Derived from Rhodamine Fluorophore [J]. Chinese Journal of Applied Chemistry, 2011, 28(11): 1292-1297.