Antibacterial Activities of Six Kinds of Polyoxometalates

doi:10.11944/j.issn.1000-0518.2017.06.160370

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (6): 700-704.DOI: 10.11944/j.issn.1000-0518.2017.06.160370

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Antibacterial Activities of Six Kinds of Polyoxometalates

XIE Lefang^a,XING Rui^a,WANG Fang^b,WANG Li^a^*()

^aCollege of Food and Biological Engineering,Jimei University,Xiamen,Fujian 361021,China
^bCollege of Oceanology and Food Science,Quanzhou Normal University,Quanzhou,Fujian 361000,China

Received:2016-09-18 Accepted:2016-12-05 Published:2017-05-31 Online:2017-05-31
Contact: WANG Li
Supported by:
Supported by the National Natural Science Foundation of China(No.2137107, No.20871054)

Abstract

Abstract:

In this study, we synthesised five kinds of Keggin-type transition metal substituted polyoxometalates(Na₇PMo₁₁M(Ⅱ)O₄₀(M=Mn,Fe,Zn,Co,Ni), abbreviated as PMo₁₁M(Ⅱ)(M=Mn,Fe,Zn,Co,Ni)). The structures of these compounds were characterized by UV-visible absorption spectrum and Fourier transform infrared spectrometer(FTIR). And then the antibacterial activities of the five kinds of Keggin-type transition metal substituted polyoxometalates(PMo₁₁M(Ⅱ)(M=Mn,Fe,Zn,Co,Ni) and their parent H₃PMo₁₂O₄₀(abbreviated PMo₁₂) on Sarcina lutea(S.lutea), Staphylococcus aureus(S.aureus), Bacillus subtilis(B.subtilis) and Escherichia coli(E.coli) were investigated by Oxford plate. Also, the minimum inhibitory concentration(MIC) and the minimum bactericidal concentration(MBC) were tested by broth microdilution methods. The results show that the six kinds of polyoxometalates can inhibit the proliferation of these four different kinds of bacteria to different extents, and the antimicrobial activities of all compounds on S.lutea and S.aureus are more effective than those against B.Subtilis and E.coli. Among these compounds, the antibacterial activities of (PMo₁₁M(Ⅱ)(M=Ni,Mn,Zn)) were superior to the other three compounds. This study will provide more theoretical and experimental supports for polyoxometalates as preservative agents in fruit and vegetables.

Key words: polyoxometalates, antibacterial activities, oxford plate

XIE Lefang, XING Rui, WANG Fang, WANG Li. Antibacterial Activities of Six Kinds of Polyoxometalates[J]. Chinese Journal of Applied Chemistry, 2017, 34(6): 700-704.

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Antibacterial Activities of Six Kinds of Polyoxometalates

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