Third‑Order Nonlinear Optical Properties of Molybdenum Diselenide/Graphene Composite

doi:10.19894/j.issn.1000-0518.230283

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (5): 659-667.DOI: 10.19894/j.issn.1000-0518.230283

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Third‑Order Nonlinear Optical Properties of Molybdenum Diselenide/Graphene Composite

Yan-Li ZU¹, Wan-Lu LI², Jia LIU¹, Shan LIN¹, Sen LI¹(), Chun-Ying HE²()

^1.Department of Pharmaceutics，Daqing Branch，Harbin Medical University，Daqing 163319，China
^2.Key Laboratory of Functional Inorganic Material Chemistry，Ministry of Education，School of Chemistry and Materials Science，Heilongjiang University，Harbin 150080，China

Received:2023-09-19 Accepted:2024-03-13 Published:2024-05-01 Online:2024-06-03
Contact: Sen LI,Chun-Ying HE
About author:chunyinghe_hlju@163.com
lisen_116@163.com；
Supported by:
the National Natural Science Foundation of China(61841504)

1. .pdf(296KB)

Abstract

Abstract:

Molybdenum diselenide/graphene （MoSe₂/rGO） composite was synthesized by a facile solvothermal reaction， and the molybdenum diselenide/graphene/polyvinyl alcohol（MoSe₂/rGO/PVA） film was further prepared by simple drop casting technique. The structure， morphology， component and absorption characteristics of MoSe₂/rGO composite were analyzed by X-ray diffraction， raman spectra， fourier transform infrared spectrometry， transmission electron microscope， X-ray photoelectron spectrometer and ultraviolet visible spectrophotometer. The third order nonlinear optical （NLO） properties of MoSe₂/rGO solution and film were investigated using the Z-scan technique at 1064 and 532 nm with 4 ns laser pulses. The results demonstrate that the third order NLO properties of MoSe₂/rGO/PVA film was larger than that of the MoSe₂solution， MoSe₂/rGO solution and MoSe₂film. The MoSe₂/rGO/PVA film exhibits much larger nonlinear absorption coefficient with incident energy of 25 μJ at 532 nm. The results pave the way for the application of transition metal dichalcogenides/graphene composite in the optical limiting and laser mode-locking.

Key words: Nonlinear optical properties, Molybdenum diselenide/graphene composite, Film, Z-scan

CLC Number:

O611.6

Yan-Li ZU, Wan-Lu LI, Jia LIU, Shan LIN, Sen LI, Chun-Ying HE. Third‑Order Nonlinear Optical Properties of Molybdenum Diselenide/Graphene Composite[J]. Chinese Journal of Applied Chemistry, 2024, 41(5): 659-667.

Figures/Tables 9

Fig.1 Schematic illustration of the MoSe2/rGO/PVA film

Fig.2 TEM images of （A， B） MoSe2 and （C， D） MoSe2/rGO composite

Fig.3 XRD patterns of GO， MoSe2 and MoSe2/rGO composite

Fig.4 Raman spectra of GO， MoSe2 and MoSe2/rGO composite

Fig.5 FT-IR spectra of GO， MoSe2/rGO， MoSe2/PVA and MoSe2/rGO/PVA

Fig.6 XPS spectra of （A） survey spectrum，（B） Se3d and （C） Mo3d in MoSe2/rGO composite；（D） The high-resolution C1s XPS spectra of GO and MoSe2/rGO composite

Fig.7 UV-Vis spectra of MoSe2， MoSe2/rGO， GO， MoSe2/PVA and MoSe2/rGO/PVA

Fig.8 Open aperture Z-scan curves of MoSe2 and MoSe2/rGO composite excited by the different input energies at 532 and 1064 nm

Fig.9 Open aperture Z-scan curves of MoSe2/PVA and MoSe2/rGO/PVA films excited by the different input energies at 532 and 1064 nm

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Third‑Order Nonlinear Optical Properties of Molybdenum Diselenide/Graphene Composite

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