Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H2PO-4

doi:10.11944/j.issn.1000-0518.2020.07.200004

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (7): 839-846.DOI: 10.11944/j.issn.1000-0518.2020.07.200004

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Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO^-₄

DONG Zhiyun, LIU Yang, WANG Yingjin, ZHAO Sanhu, XI Fugui^*

Department of Chemistry,Xinzhou Teachers University,Xinzhou,Shanxi 034000,China

Received:2020-01-02 Published:2020-07-01 Online:2020-07-07
Contact: XI Fugui, lecturer; Tel/Fax:0350-3339205; E-mail:xifuguig@163.com; Research interests:synthesis and design of function materials
Supported by:
Supported by the National Natural Science Foundation of China(No.21701137), and the Shanxi “1331 Project” Key Subjects Construction(2019)

Abstract

Abstract: Two novel naphthalimide-benzimidazolium based receptors 1 and 2 were synthesized. The anion (F^-, Cl^-, Br^-, I^-, CH₃COO^-, HSO^-₄, H₂PO^-₄, ClO^-₄, NO^-₃) binding properties of two receptors were evaluated in CH₃CN by fluorescence spectroscopy. Two receptors display fluorescent quenching effect with H₂PO^-₄ and the quench percentages for receptors 1 and 2 are 98%and 24%, respectively. The results indicate that receptor 1 is more closely matched to H₂PO^-₄ in configuration, and receptor 1 behaves as a “turn-off” fluorescence sensor for H₂PO^-₄. Job-plot shows that receptor 1 and H₂PO^-₄ form a 1∶1 complex, and the binding constant is (1.25±0.11)×10⁵ L/mol, the detection limit is 6.90×10^-6 mol/L.

Key words: benzimidazolium, naphthalimide, H₂PO^-₄, fluorescent sensor

DONG Zhiyun, LIU Yang, WANG Yingjin, ZHAO Sanhu, XI Fugui. Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO^-₄[J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 839-846.

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Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO^-₄

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