Preparation and Luminescence Property of Ba5-3x/2B4O11∶xEu3+ Phosphor

doi:10.11944/j.issn.1000-0518.2019.05.180276

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (5): 548-553.DOI: 10.11944/j.issn.1000-0518.2019.05.180276

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Preparation and Luminescence Property of Ba_5-3_x_/2B₄O₁₁∶xEu³⁺ Phosphor

HAO Bin^a^b,ZHAO Wenwu^b^c,YU Jianyuan^b^c,LIU Jinqiang^b^c,LIU Jian^b^c^*(),DONG Xiuzhen^b^c,WANG Xiuwen^b^c

^aScientific Technology Service
^bKey Laboratory of Micro-nano Materials Preparation and Application of Tangshan City
^cDepartment of Environmental and Chemical Engineering,Tangshan College,Tangshan,Hebei 063000,China

Received:2018-08-27 Accepted:2018-11-29 Published:2019-05-01 Online:2019-05-06
Contact: LIU Jian
Supported by:
Supported by the Youth Top Talent Program of Hebei Education Department (No.BJ2018203), Tangshan Science and Technology Research and Development Program(No.17130259a)

Abstract

Abstract:

The phosphors, Ba_5-3_x_/2B₄O₁₁∶xEu³⁺(x=0.02~0.22), were synthesized by high-temperature solid-state reaction method. The luminescence property of Ba_5-3_x_/2B₄O₁₁∶xEu³⁺ was studied in this paper. The phase and surface topographies of as-prepared samples were characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM). This phosphor can be effectively excited at 393 nm and the emission peaks are located at 596 nm, 621 nm, 657 nm and 706 nm corresponding to the ⁵D₀-⁷F_J(J=1,2,3,4) transition of Eu³⁺ ions, respectively. Therein the ⁵D₀-⁷F₂ electric dipole transition of Eu³⁺ ions, which locates at 621 nm, is the strongest wave crest. Investigation of Eu³⁺ content-dependent emission spectra indicates that x=0.16 is the optimum doping content of Eu³⁺ ions in the Ba₅B₄O₁₁ host.

Key words: high-temperature solid-state reaction method, luminescence property, borate, Ba_5-3_x_/2B₄O₁₁∶xEu³⁺, rare earth doping

HAO Bin,ZHAO Wenwu,YU Jianyuan,LIU Jinqiang,LIU Jian,DONG Xiuzhen,WANG Xiuwen. Preparation and Luminescence Property of Ba_5-3_x_/2B₄O₁₁∶xEu³⁺ Phosphor[J]. Chinese Journal of Applied Chemistry, 2019, 36(5): 548-553.

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Preparation and Luminescence Property of Ba_5-3_x_/2B₄O₁₁∶xEu³⁺ Phosphor

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