Synthesis and Application of Water-Soluble Fe3O4 Magnetic Nano-catalyst

doi:10.11944/j.issn.1000-0518.2019.02.180089

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (2): 188-194.DOI: 10.11944/j.issn.1000-0518.2019.02.180089

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Synthesis and Application of Water-Soluble Fe₃O₄ Magnetic Nano-catalyst

CHEN Hongyun^a,YANG Fanghong^a,LI Yupeng^a,HE Jiayu^a,CHE Mengqin^a,WANG Meichen^b,CHENG Chuanjie^a^*()

^aSchool of Chemistry and Chemical Engineering,Jiangxi Science & Technology Normal University,Nanchang 330013,China;
^bSchool of Information Engineering,Nanchang University,Nanchang 330031,China

Received:2018-03-29 Published:2019-02-01 Online:2019-01-31
Contact: CHENG Chuanjie
Supported by:
Supported by the National Natural Science Foundation of China(No.21564004, No.21264008)

Abstract

Abstract:

Fe₃O₄ magnetic nano particles(MNPs) with sulfonic acid groups on the surface were readily prepared via coupling reaction between 4-amino phenylsulfonic acid diazonium tetrafluoroborate and Fe₃O₄ nano particles. Transmission electron microscopy(TEM) images reveal that the average size of these acidic particles is about 20 nm. These acidic particles show good solubility in water, but they are insoluble in most of common organic solvents, allowing easy isolation and recycling of the particles by their magnetic property in catalytic reactions. In terms of application, when the acidic magnetic particles were used to catalyze esterification reactions between carboxylic acids and alcohols, moderate to high isolated yields(71%86%) of ester products were obtained. The optimized catalyst loading is 1.5%(mass fraction). Furthermore, 5-hydroxymethyl furfural(HMF) was also synthesized in a 32% yield from fructose utilizing the acidic magnetic particles as a catalyst.

Key words: magnetic nanoparticles, nano Fe₃O₄, nano catalyst, esterification, water-solubility

CHEN Hongyun,YANG Fanghong,LI Yupeng,HE Jiayu,CHE Mengqin,WANG Meichen,CHENG Chuanjie. Synthesis and Application of Water-Soluble Fe₃O₄ Magnetic Nano-catalyst[J]. Chinese Journal of Applied Chemistry, 2019, 36(2): 188-194.

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Synthesis and Application of Water-Soluble Fe₃O₄ Magnetic Nano-catalyst

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