Synthesis and Catalytic Performance of Zinc Porphyrin Modified Binuclear Carbene Olefin Metathesis Catalysts

doi:10.11944/j.issn.1000-0518.2018.12.180015

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (12): 1457-1461.DOI: 10.11944/j.issn.1000-0518.2018.12.180015

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Synthesis and Catalytic Performance of Zinc Porphyrin Modified Binuclear Carbene Olefin Metathesis Catalysts

ZHANG Huizhu^a,HOU Yurong^a,WANG Xinyuan^b,LIU Guiyan^b^*()

^aCollege of Pharmacy,Jiamusi University,Jiamusi,Heilongjiang 154007,China
^bCollege of Chemistry,Tianjin Normal University,Tianjin 300387,China

Received:2018-01-18 Accepted:2018-04-28 Published:2018-12-05 Online:2018-12-05
Contact: LIU Guiyan
Supported by:
Supported by the General Program of Jiamusi University(No.JMSUJCMS2016-018)

Abstract

Abstract:

A zinc-containing porphyrin-modified Grubbs-Hoveyda type binuclear ruthenium carbene olefin metathesis catalyst was synthesized. The structure of the product was confirmed by nuclear magnetic resonance(NMR). The yield of the ring-closing metathesis(RCM) reaction of several representative substrates could reach 95% by using 0.1% steriochemic catalyst. For a specific cross-olefin metathesis reaction(CM), a higher yield(93%) could be obtained with extended reaction time. This study provides a new method and a theoretical basis for the modification of Grubbs-Hoveyda catalyst.

Key words: binuclear, olefin metathesis, ruthenium carbene, zinc porphyrin

ZHANG Huizhu, HOU Yurong, WANG Xinyuan, LIU Guiyan. Synthesis and Catalytic Performance of Zinc Porphyrin Modified Binuclear Carbene Olefin Metathesis Catalysts[J]. Chinese Journal of Applied Chemistry, 2018, 35(12): 1457-1461.

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Synthesis and Catalytic Performance of Zinc Porphyrin Modified Binuclear Carbene Olefin Metathesis Catalysts

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