Catalytic Properties of Carbon Supported Pd/Ce Bimetallic Catalyst on Heck Reaction

doi:10.11944/j.issn.1000-0518.2015.04.140298

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (4): 428-432.DOI: 10.11944/j.issn.1000-0518.2015.04.140298

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Catalytic Properties of Carbon Supported Pd/Ce Bimetallic Catalyst on Heck Reaction

XU Qijie, SHI Wenzhong^*, ZUO Chunshan, LIU Dayong, YANG Chun, ZHAO Xiang, LIU Pengcheng

Department of Chemistry & Chemical Engineering,Huanghuai University,Zhumadian,He'nan 463000,China

Received:2014-08-27 Revised:2014-11-20 Published:2015-04-10 Online:2015-04-10
Contact: Corresponding author:SHIWenzhong, professor; Tel/Fax:0396-2853156; E-mail:shiwz64@163.com; Research interests: preparation and properties of rare earth compounds
Supported by:
Supported by He’nan Province Natural Science Fund project (No.0624270040, No.092300410121, No.112300410184)

Abstract

Abstract:

Carbon supported Pd/Ce bimetallic catalyst was prepared readily for Heck reaction. The effect of reaction conditions on the catalytic properties of carbon supported Pd/Ce bimetallic catalyst was studied in details with the model Heck reaction of iodobenzene and acrylic acid. The results show that carbon supported Pd/Ce bimetallic catalyst can effectively catalyze the Heck reactions under the conditions of 130 ℃, 5 h, DMF as the solvent, and Bu₃N as the base to afford the product with a yield of over 70%. Additionally, the heterogeneous carbon supported Pd/Ce bimetallic catalyst can be easily separated from the reaction solution. Furthermore, the catalyst can be reused for 3 times with a yield of 69% and without the significant loss of catalytic efficiency.

Key words: Heck reaction, bimetallic catalyst, catalytic

CLC Number:

O643

XU Qijie, SHI Wenzhong , ZUO Chunshan, LIU Dayong, YANG Chun, ZHAO Xiang, LIU Pengcheng. Catalytic Properties of Carbon Supported Pd/Ce Bimetallic Catalyst on Heck Reaction[J]. Chinese Journal of Applied Chemistry, 2015, 32(4): 428-432.

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Catalytic Properties of Carbon Supported Pd/Ce Bimetallic Catalyst on Heck Reaction

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