Polystyrene-Supported Selenoether Platinum Complex as Hydrosilylation Catalyst

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (1): 107-109.

• Full Papers • Previous Articles Next Articles

Polystyrene-Supported Selenoether Platinum Complex as Hydrosilylation Catalyst

Meng Lingzhi, Ke Aiqing, Chen Yuanyin

Department of Chemistry, Wuhan University, Wuhan 430072

Received:1996-04-18 Revised:1996-10-18 Published:1997-02-10 Online:1997-02-10

Abstract

Abstract: Polystyrene-supported selenoethers were synthesized from chloromethylated crosslinked polystyrene and(HOCH₂CH₂)₂Se or EtOCH₂CH₂SeCH₂CH₂OH via Williamson reaction. They were reacted with potassium chloroplatinite in acetone under nitrogen atmosphere to give title complexes. It was found that the platinum complexes exhibited high catalytic activity in the hydrosilylation of olefins with triethoxysilane.

Key words: polystyrene, supported selenoether, platinum coodination, hydrosilylation catalyst, platinum complex

Meng Lingzhi, Ke Aiqing, Chen Yuanyin. Polystyrene-Supported Selenoether Platinum Complex as Hydrosilylation Catalyst[J]. Chinese Journal of Applied Chemistry, 1997, 0(1): 107-109.

[1]	Fu-Lin WANG, Zhong-Fu ZHAO, Yi-Ming LIANG, Jian-En HUANG, Chun-Qing ZHANG. Preparation， Structure and Properties of Crystalline Homo-Polystyrene/Hydrogenated Poly（styrene-b-butadiene-b-styrene） Anion Exchange Membrane [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 833-844.
[2]	ZHANG Yanhui, WANG Lin, MUSLIM Arzugul, LAN Haidie. Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 764-771.
[3]	YE Lin, ZHANG Shaofeng, MIN Jiakang, MA Li, TANG Tao. Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide [J]. Chinese Journal of Applied Chemistry, 2019, 36(4): 451-458.
[4]	ZHANG Guangchun, QIU Jian, XING Haiping, TANG Tao. Influence of Polyethylene-g-polystyrene on the Mechanical Properties and Foaming Behavior of Linear Low Density Polyethylene/Polystyrene Blends [J]. Chinese Journal of Applied Chemistry, 2016, 33(7): 756-765.
[5]	ZHANG Guangchun, QIU Jian, XING Haiping, TANG Tao. Influence of Polyethylene-g-polystyrene on the Mechanical Properties and Foaming Behavior of Linear Low Density Polyethylene/Polystyrene Blends [J]. Chinese Journal of Applied Chemistry, 2016, 33(7): 0-0.
[6]	HU Zhengyong, LI Shanjia, DONG Xinrong. Synthesis and Photoelectric Properties of a Cyclometalated Iridium-Platinum Binuclear Complex [J]. Chinese Journal of Applied Chemistry, 2016, 33(12): 1428-1434.
[7]	XU Di,GAO Baojiao ,CHEN Pinghong. Preparation and Characterization of Polystyrene Containing Bidentate Schiff Base Ligand on Side Chain and Preliminary Exploration of Fluorescence Emission Property of Its Eu(Ⅲ) Complexes [J]. Chinese Journal of Applied Chemistry, 2015, 32(2): 183-191.
[8]	XIAO Liwei*, KONG jie, ZHOU Qiuxiang, HU Yueli. One Pot Synthesis of β-Amino Ketone Derivatives Catalyzed by Polystyrene-supported Ferric Chloride [J]. Chinese Journal of Applied Chemistry, 2014, 31(06): 715-720.
[9]	JIA Ruokun*, LI Tingting, ZHOU Shiyu. Shrinking and Light Diffraction of the Self-Organized Polystyrene-block-Polybutadiene Microporous Film Deposited on a Stretched Polymer Film by Thermal Contraction [J]. Chinese Journal of Applied Chemistry, 2014, 31(05): 560-565.
[10]	XU Zeqing, GAO Baojiao*, HOU Xiaodong. Synthesis of Benzoic Acid Derivative-Bonded Polystyrene Ligand and Photoluminescence Properties of Its Complex with Eu(Ⅲ) Ion [J]. Chinese Journal of Applied Chemistry, 2014, 31(02): 133-139.
[11]	DING Hao, GAO Baojiao*, CHENG Wei. Synthesis, Immobilization and Characterization of Chiral Metal-Salen Complex on Chloromethylated Crosslinked Polystyrene Microspheres [J]. Chinese Journal of Applied Chemistry, 2013, 30(03): 276-282.
[12]	SONG Changping, LIU Junkang, NI Zhongbin, CHEN Mingqing, LIU Shirong*. Preparation of Self-Assembly Polystyrene Sphere Colloid Crystal by a Solvent Evaporation Method [J]. Chinese Journal of Applied Chemistry, 2012, 29(06): 639-642.
[13]	DAI Xin, GAO Baojiao*, DING Hao, FANG Xiaolin. Aminomethyl Group-Modification of Chloromethylated Polystyrene Microspheres and Preparation of Schiff Base-Type Chelating Resin Microspheres [J]. Chinese Journal of Applied Chemistry, 2012, 29(04): 383-391.
[14]	WEI Xiaopeng, GAO Baojiao*, SHI Xuejun. Preparation of Aryl Carboxylic Acid-functionalized Polystyrene and Preliminary Exploration of Florescence Emission of Formed Polymer-Rare Earth(Tb(Ⅲ)) Complexes [J]. Chinese Journal of Applied Chemistry, 2012, 29(03): 260-265.
[15]	XU Songxiu, WANG Yinning, CONG Yuanhua, JIANG Shiping, LI Liangbin. Construction of Polydimethylsiloxane Nanochannel Using Electrospinning [J]. Chinese Journal of Applied Chemistry, 2012, 29(01): 23-28.

Polystyrene-Supported Selenoether Platinum Complex as Hydrosilylation Catalyst

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments