Catalytic Oxidation of Cyclohexene to Cyclohexanone by Palladium Compounds

Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (5): 15-19.

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Catalytic Oxidation of Cyclohexene to Cyclohexanone by Palladium Compounds

Li Huaming, Ye Xingkai, Wu Yue

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received:1994-10-24 Revised:1995-03-17 Published:1995-10-10 Online:1995-10-10

Abstract

Abstract: Cyclohexene has been oxidized to cyclohexanone catalytically by catalyst systemsof Pd(OAc)₂/HQ with macrocyclic compounds:metallophthalocyanine(MPc,M=Fe,Cr,Co)and chlorometalloporphyrin(MTPPCI,M=Fe,Cr,Mn)in an acidic aqueous solution ofacetonitrile.The best results were obtained by using Pd(OAc)₂/HQ/FePc system.The vieldof cyclohexanone was 84%with selectivity of 98%on 30min reaction.Some factors influenc-ing the activity of the catalyst have been examined.

Key words: cyclohexene, cyclohexanone, catalytic oxidation, palladium acetate, phthalocya-nine iron, hydroquinone

Li Huaming, Ye Xingkai, Wu Yue. Catalytic Oxidation of Cyclohexene to Cyclohexanone by Palladium Compounds[J]. Chinese Journal of Applied Chemistry, 1995, 0(5): 15-19.

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Catalytic Oxidation of Cyclohexene to Cyclohexanone by Palladium Compounds

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