Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (5): 20-24.

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Mechanism of Oxidation of Cyclohexene to Cyclohexanone Catalyzed by Pd(OAc)2/HO/FePc

Li Huaming, Ye Xingkai, Wu Yue   

  1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1994-10-15 Revised:1995-03-27 Published:1995-10-10 Online:1995-10-10

Abstract: The oxidation of cyclohexene to cyclohexanone catalyzed by Pd(OAc)2/HQ/FePcwas investigated in an acidic aqueous solution of acetonitrile.The role of each component incatalyst system during the oxidation of cyclohexene was examined by UV-Vis,IR,XPSspectroscopy and cyclic voltammetry, respectively.Based on the experimental results,themechanism of oxidation of cyclohexene catalyzed by Pd(OAc)2/HQ/FePc was discussed.

Key words: cyclohexene oxidation, cyclohexanone, Pd(OAc)2, hydroquinone, phthalocyanineiron, reaction mechanism