Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (1): 110-112.

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STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS LV.INVESTIGATION OF SOLID STATE REACTIONS OF PHENANTHROLINE WITH METAL CHLORIDES(M=Fe,Co,Ni,Cu)

Jia Dianzeng, Li Changxiong, Xin Xinquan   

  1. Institute of Coordination Chemistry, Nanjing University, 210008 Nanjing
  • Received:1992-02-24 Revised:1992-10-23 Published:1993-02-10 Online:1993-02-10

Abstract: Solid state reactions of metal chlorides (M=Fe, Co, Ni, Cu) with Phenanthroline at room temperature have been studied. A two-step addition reaction was observed. The intermediates M(Phen)2Cl2·nH2O(M=Co,Ni,Cu) were confirmed by experimental results. Effects of molecular structure of the reactants and the stability of the complexes formed were also discussed.

Key words: solid state reaction, phenanthroline, transition metal chloride